祝艳 - 南京大学 - 化学化工学院

个人简介

南京大学化学化工学院教授、博士生导师。主要从事金属团簇催化研究，在构筑精确团簇催化剂、建立明确构效关系、精准调控催化反应过程等方面开展深入探索和系统性研究，为理性设计新催化剂和催化反应过程提供新思路和科学基础，促进多相催化研究精准化发展。在J. Am. Chem. Soc.、Angew. Chem.、Nature Commun.等期刊发表通讯作者论文70余篇。获授权发明专利11项。主编出版专著1部。主持基金委、中石化、Shell等项目。担任物理化学学报、Nano Research、Green Energy & Environment等期刊青年编委，Current Opinion in Green and Sustainable Chemistry期刊编委。

研究领域

催化研究领域一百多年的发展过程中，对多相催化剂活性中心的认识在尺度上越来越小，以单核配合物为主要代表的均相催化剂，在保持结构精确的基础上向尺度更大的多核配合物发展，多相-均相融合是催化研究发展的重要趋势。原子精确金属团簇恰好处于二者的结合地带，它们是由确定数目的金属原子内核与外围配体组成的集合体，可看作是连接多相-均相催化剂的桥梁；团簇结构高度均一，种类丰富多样，为在原子层次上深入理解催化作用机制提供了新的材料体系，对发展结构高度精确的催化剂具有重要的科学意义。

近期论文

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Guangjun Li, Xin Sui, Xiao Cai, Weigang Hu, Xu Liu, Mingyang Chen, Yan Zhu*. Precisely Constructed Silver Active Sites in Gold Nanoclusters for Chemical Fixation of CO2. Angewandte Chemie International Edition 2021,60,10573-10576. Xu Liu, Wen Wu Xu, Xinyu Huang, Endong Wang, Xiao Cai, Yue Zhao, Jin Li, Min Xiao, Chunfeng Zhang*, Yi Gao*, Weiping Ding, Yan Zhu*. De novo design of Au36(SR)24 nanoclusters. Nature Communications 2020,11,3349. Guangjun Li, Weigang Hu, Yongnan Sun, Jiayu Xu, Xiao Cai, Xinglian Cheng, Yuying Zhang, Ancheng Tang, Xu Liu, Mingyang Chen*, Weiping Ding, Yan Zhu*. Reactivity and Lability Modulated by a Valence Electron Moving in and out of 25-Atom Gold Nanoclusters. Angewandte Chemie International Edition 2020,59,21135-21142. Xu Liu, Govindarajan Saranya, Xinyu Huang, Xinglian Cheng, Rui Wang, Mingyang Chen*, Chunfeng Zhang, Tao Li, Yan Zhu*. Ag2Au50(PET)36 Nanocluster: Dimeric Assembly of Au25(PET)18 Enabled by Silver Atoms. Angewandte Chemie International Edition 2020,59,13941-13946. Xiao Cai, Weigang Hu, Shun Xu, Dan Yang, Mingyang Chen*, Miao Shu, Rui Si*, Weiping Ding, Yan Zhu*. Structural Relaxation Enabled by Internal Vacancy Available in a 24-atom Gold Cluster Reinforces Catalytic Reactivity. Journal of the American Chemical Society 2020,142,4141-4153. Dan Yang, Wei Pei, Si Zhou*, Jijun Zhao, Weiping Ding, Yan Zhu*. Controllable Conversion of CO2 on Non-Metallic Gold Clusters. Angewandte Chemie International Edition 2020,59,1919-1924. Xiao Cai, Govindarajan Saranya,Kangqi Shen, Mingyang Chen,* Rui Si,* Weiping Ding, Yan Zhu*.Reversible Switching of Catalytic Activity by Shuttling an Atom into and out of Au Nanoclusters. Angewandte Chemie International Edition 2019,58,9964-9968. Yuanyuan Liu, Xiaoqi Chai, Xiao Cai, Mingyang Chen*, Rongchao Jin, Weiping Ding, Yan Zhu*. Central Doping of a Foreign Atom into the Silver Cluster for Catalytic Conversion of CO2 toward C-C Bond Formation. Angewandte Chemie International Edition 2018,57,9775-9779. Qi Li, Jack C. Russell, Tian-Yi Luo, Xavier Roy, Nathaniel L. Rosi, Yan Zhu*, Rongchao Jin*. Modulating the Hierarchical Fibrous Assembly of Au Nanoparticles with Atomic Precision. Nature Communications 2018,9,3871.