朱从青 - 南京大学 - 配位化学国家重点实验室

个人简介

Biography 2016.11 — Professor, Nanjing University 2015.10 — 2016.10 Postdoctoral Associate, MIT (Prof. Richard Schrock) 2014.06 — 2015.09 Postdoctoral Fellow, iChEM, China (Prof. Haiping Xia) 2008.09 — 2014.05 Ph.D. Xiamen University, Xiamen, China (Prof. Haiping Xia) 2004.09 — 2008.07 B.S., Anqing Normal University, Anhui, China Honours and Awards 中国化学会首届 “黄耀曾金属有机化学青年奖”（2021）国家自然科学奖二等奖（4/5，2021）中国化学会 “菁青化学新锐奖”（2021）国家青年拔尖人才（2020）福建省自然科学奖一等奖（4/5，2019）江苏省双创人才（2018）中国科协青年人才托举工程（2017）江苏教授（2017）福建省优秀博士学位论文（2016）卢嘉锡优秀研究生奖（2014）第九届中国青少年科技创新奖（2014）厦门大学嘉庚奖章（2014） IUPAC最佳墙报奖（2013）

研究领域

We are committed to the development of efficient strategy to construct novel organometallic molecules with unusual structures and chemical reactivity. Our research interests span a wide range of coordination chemistry, organometallic chemistry, organic synthesis, and small molecule activation. Current projects mainly focus on: i) the chemistry of f-block metal (such as Ce, Nd, and U) complexes with metal-ligand multiple bond; ii) d-f heterometallic molecular clusters with direct metal-metal bond; iii) the main group elements (P, B, and Al) imitate metal catalysts in organic synthesis; and iv) small molecule activation promoted by organometallics.

近期论文

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X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex. Natl. Sci. Rev. 2023, 10, nwac144. J. Shen, T. Rajeshkumar, G. Feng, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Complexes featuring a cis-[M⇉U⇇M] core (M = Rh, Ir): A new route to uranium-metal multiple bonds. Angew. Chem. Int. Ed. 2023, 62, e202303379 (Hot Paper). W. Fang, L. Maron*, C. Zhu*, Recent advances in f-block metal-metal bonds. Handbook on the Physics and Chemistry of Rare Earths. 2023, 63, 1-54. X. Sun, J. Shen, T. Rajeshkumar, L. Maron*, C. Zhu*, Heterometallic cluster with cerium-transition-metal bonding supported by nitrogen-phosphorus ligands. Inorg. Chem. 2023, 62, 16077-16083. K. Li, J. He, Y. Zhao, C. Zhu*, Synthesis and reactivity of uranium(IV) complex supported by monoanionic nitrogen-phosphorus ligand. Inorg. Chem. Front. 2023, 10, 5622-5633. Y. Li, P. Chen, Q. Zhu*, C. Zhu*, Magnesium complexes supported by dianionic double layer nitrogen-phosphorus ligand: Synthesis and reactivity study. Dalton Trans. 2023, 52, 15467-15474. K. Li, G. Feng, S. Christodolou, Y. Zhao, L. Maron*, C. Zhu*, Heterotrimetallic cluster with U-Ni-Ge and U-Ni-Sn units. Polyhedron, 2023, 243, 116548. Q. Zhu†, W. Fang†, L. Maron, C. Zhu*, Heterometallic clusters with uranium–metal bonds supported by double-layer nitrogen–phosphorus ligands. Acc. Chem. Res.2022, 55, 1718-1730. W. Fang, Q. Zhu*, C. Zhu*, Recent advances in heterometallic clusters with f-block metal-metal bonds: synthesis, reactivity and applications. Chem. Soc. Rev. 2022, 51, 8434-8449. P. Wang, I. Douair, Y. Zhao, R. Ge, J. Wang, S. Wang, L. Maron*, C. Zhu*, Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium–metal triple bonds. Chem.2022, 8, 1361–1375. X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex. Natl. Sci. Rev. 2022, DOI: 10.1093/nsr/nwac144. X. Xin, I. Douair, T. Rajeshkumar, Y. Zhao, S. Wang, L. Maron*, C. Zhu*, Photochemical synthesis of transition metal-stabilized uranium(VI) nitride complexes. Nat. Commun. 2022, 13, 3809. X. Sun†, X. Gong†, Z. Xie, C. Zhu*, A uranium(IV) alkyl complex: Synthesis and catalytic property in carbonyl hydroboration. Chin. J. Chem. 2022, 40, 2047–2053. P. Wang, Y. Zhao, C. Zhu*, Photolysis, thermolysis, and reduction of a uranium azide complex supported by a double-layer N-P ligand. Organometallics 2022, 41, 2448-2454. K. Li, W. Liu, H. Zhang, L. Cheng, Y. Zhang, Y. Wang*, N. Chen*, C. Zhu*, Z. Chai, S. Wang*, Progress in solid state and coordination chemistry of actinides in China. Radiochim. Acta 2022, DOI: 10.1515/ract-2022-0024. K. Shi, I. Douair, G. Feng, P. Wang, Y. Zhao, L. Maron*, C. Zhu*, Heterometallic clusters with multiple rare earth metal−transition metal bonding. J. Am. Chem. Soc. 2021,143, 5998–6005. P. Wang, I. Douair, Y. Zhao, S. Wang, J. Zhu, L. Maron*, C. Zhu*, Facile dinitrogen and dioxygen cleavage by a uranium(III) complex: Cooperativity between the non-innocent ligand and the uranium center. Angew. Chem. Int. Ed. 2021, 60, 473-479. W. Fang, I. Douair, A. Hauser, K. Li, Y. Zhao, P. W. Roesky, S. Wang, L. Maron*, C. Zhu*, Uranium(III)-phosphorus(III) synergistic activation of white phosphorus and arsenic. CCS Chem. 2021, 3, 3268–3276. W. Fang, S. Pan, W. Su, S. Wang, L. Zhao*, G. Frenking*, C. Zhu*, Complex featuring two double dative bonds between carbon(0) and uranium. CCS Chem. 2021, 3, 2324-2332. W. Fang, A. Carpentier, X. Sun, Y. Zhao, L. Maron,* C. Zhu*, Redox-induced reversible P-P coupling in a uranium complex. Chem. Commun. 2021, 57, 12175-12178. X. Sun, C. Zhu*, Synthesis, characterization and reactivity of a neutral antimony(III) complex. Chin. Chem. Lett. 2021, 32, 717–720. P. Wang#, Q. Zhu#, Y. Wang, G. Zeng*, J. Zhu*, C. Zhu*, Carbon-halogen bond activation by a structurally constrained phosphorus(III) platform. Chin. Chem. Lett. 2021, 32, 1432–1436. 施开赢，方蔚，朱从青* 稀土金属－金属键的构筑策略. 中国稀土学报, 2021, 39, 143-152 X. Xin, I. Douair, Y. Zhao, S. Wang, L. Maron*, C. Zhu*,Dinitrogen cleavage by a heterometallic cluster featuring multiple uranium–rhodium bonds. J. Am. Chem. Soc. 2020, 142, 15004-15011. G. Feng, K. N. McCabe, S. Wang, L. Maron*, C. Zhu*, Construction of heterometallic clusters with multiple uranium-metal bonds by dianionic nitrogen-phosphorus ligands. Chem. Sci. 2020, 11, 7585-7592. Q. Zhu,# P. Wang,# J. Zhu*, C. Zhu*, G. Zeng*, Chemoselectivity for B-O and B-H bond cleavage by pincer-type phosphorus compounds: Theoretical and experimental studies. Inorg. Chem., 2020, 59, 15636-15645. [IC-2020.pdf] (# co-first author) P. Wang, M. Zhang, C. Zhu*, Synthesis, characterization, and reactivity of a pincer-type aluminum(III) complex. Organometallics, 2020, 39, 2732−273. X. Sun, W. Su, K. Shi, Z. Xie (本科生), C. Zhu*, Triple frustrated Lewis pair-type reactivity on a single rare earth metal center. Chem.-Eur. J. 2020, 26, 5354-5359. X. Xin, C. Zhu*, Isolation of heterometallic cerium(iii) complexes with a multidentate nitrogen–phosphorus ligand. Dalton Trans. 2020, 49, 603-607. G. Feng, M. Zhang, D. Shao, X. Wang, S. Wang, L. Maron*, C. Zhu*, Transition-metal-bridged bimetallic clusters with multiple uranium–metal bonds. Nature Chem. 2019, 11, 248-253. G. Feng, M. Zhang, P. Wang, S. Wang, L. Maron*, C. Zhu*, Identification of a uranium–rhodium triple bond in a heterometallic cluster. Proc. Natl. Acad. Sci. U. S. A. 2019, 116, 17654-17658. X. Sun, Q. Zhu, Z. Xie (本科生), W. Su, J. Zhu*, C. Zhu*, An unprecedented Ga/P frustrated Lewis pair: Synthesis, characterization, and reactivity. Chem.-Eur. J.2019, 25, 14295-14299. W. Su, S. Pan, X. Sun, L. Zhao*, G. Frenking*, C. Zhu*, Cerium-carbon dative interactions supported by carbodiphosphorane. Dalton Trans. 2019, 48, 16108-16114. W. Su, S. Pan, X. Sun, S. Wang, L. Zhao*, G. Frenking*, C. Zhu*, Double dative bond between divalent carbon(0) and uranium. Nature Commun., 2018, 9, 4997. Featured in a Nat. Commun. Editors' Highlights Webpage Q. Zhu, J. Zhu*, C. Zhu*, Recent progress in the chemistry of lanthanide-ligand multiple bonds. Tetrahedron Lett., 2018, 59, 514-520. [TL-2018.pdf] C. Zhu, H. Xia,* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metal. Acc. Chem. Res., 2018, 51, 1691–1700. C. Zhu, J. Zhu, X. Zhou, Q. Zhu, Y. Yang, T. Wen, H. Xia,* Isolation of an Eleven-Atom Polydentate Carbon-Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem. Int. Ed., 2018, 57, 3154-3157. (VIP) C. Zhu, J. Wu, S. Li, Y. Yang, J. Zhu, X. Lu, H. Xia,* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings. Angew.Chem. Int. Ed., 2017, 56, 9067-9071. C. Zhu,+ C. Yang,+ Y. Wang, G. Lin, Y. Yang, X. Wang, J. Zhu, X. Chen, X. Lu,* G. Liu,* H. Xia,* CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties.Sci. Adv., 2016, 2, e1601031. C. Zhu, Y. Yang, J. Wu, M. Luo, J. Fan, J. Zhu,* H. Xia,* Five-membered cyclic metal carbyne: Synthesis of osmapentalynes by the reactions of osmapentalene with allene, alkyne, and alkene. Angew. Chem.Int. Ed., 2015, 54, 7189-7192. C. Zhu, Y. Yang, M. Luo, C. Yang, J. Wu, L. Chen, G. Liu, T. Wen, J. Zhu,* H. Xia,* Stabilizing two classical anti-aromatic frameworks: Demonstration of photoacoustic imaging and photothermal effect in metalla-aromatics.Angew. Chem. Int. Ed., 2015, 54, 6181-6185. C. Zhu, X. Zhou, H. Xing, K. An, J. Zhu,* H. Xia,* σ-Aromaticity in an unsaturated ring: Osmapentalene derivatives containing a metallacyclopropene unit.Angew. Chem. Int. Ed., 2015, 54, 3102-3106. C. Zhu, M. Luo, Q. Zhu, J. Zhu,* P. v. R. Schleyer, J. I.-C. Wu, X. Lu, H. Xia,* Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums. Nature Commun., 2014, 5, 3265-3271. C. Zhu, Q. Zhu, J. Fan, J. Zhu, X. He, X.-Y. Cao,* H. Xia,* A metal-bridged tricyclic aromatic system: synthesis of osmium polycyclic aromatic complexes.Angew. Chem. Int. Ed., 2014, 53, 6232-6236. C. Zhu, S. Li, M. Luo, X. Zhou, Y. Niu, M. Lin, J. Zhu,* Z. Cao, X. Lu, T. Wen, Z. Xie, P. v. R. Schleyer, H. Xia,* Stabilization of anti-aromatic and strained five-membered rings with a transition metal.Nature Chem., 2013, 5, 698-703. C. Zhu, X. Cao,* H. Xia,* Double stabilization of highly strained six-membered rings by phosphonium and transition metal. Chin. J. Org. Chem., 2013, 33, 657-662. M. Luo, Y. Sui, X. Lin, C. Zhu, Z. Yan, Y. Ruan, H. Zhang,* H. Xia,* [3+2] Cycloaddition Reaction of Metallacyclopropene with Nitrosonium Ion: Isolation of Aromatic Metallaisoxazole. Chem. Commun. 2020, 56, 6806-6809. Z. Deng, C. Zhu, Y. Hua, G. He, Y. Guo, R. Lu, X. Cao, J. Chen,* H. Xia,* Synthesis and Characterization of Metallapentalenoxazetes from the [2+2] Cycloaddition of Metallapentalynes with Nitrosoarenes. Chem. Commun.2019, 55, 6237-6240. X. Zhou, X. Pang, L. Nie, C. Zhu, K. Zhuo, Q. Zhuo, Z. Chen, G. Liu, H. Zhang,* Z. Lin, H. Xia,Successive Modification of Polydentate Complexes Gives Access to Planar Carbon- and Nitrogen-based Ligands. Nat. Commun.2019, 10, 1488. G. Lin, Y. Zhang, C. Zhu, C. Chu, Y. Shi, X. Pang, E. Ren, Y. Wu, P. Mi, H. Xia, X. Chen, G. Liu,* Photo-excitable hybrid nanocomposites for image-guided photo/TRAIL synergistic cancer therapy. Biomaterials, 2018, 176, 60-70. X. Zhou, J. Wu, Y. Hao, C. Zhu, Q. Zhuo, H. Xia,* J. Zhu,* Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity.Chem. Eur. J., 2018, 24, 2389-2395. C. Yang+, G. Lin+, C. Zhu+, X. Pang, Y. Zhang, X. Wang, X. Li, B. Wang,* H. Xia,* G. Liu,* Metalla-aromatic loaded magnetic nanoparticles for MRI/photoacoustic imaging-guided cancer phototherapy.J. Mater. Chem. B, 2018, 6, 2528-2535. Z. Lu+, C. Zhu+, Y. Cai, J. Zhu, Y. Hua, Z. Chen, J. Chen,* H. Xia,* Metallapentalenofurans and Lactone-Fused Metallapentalynes. Chem. Eur. J., 2017, 23, 6426-6431. Q. Zhu, C. Zhu, Z. Deng, J. Chen, G. He,* J. Zhu, H. Xia,* Synthesis and characterization of osmium polycyclic aromatic complexes via nucleophilic reactions of osmapentalyne.Chin. J. Chem., 2017, 35, 628-634. J. K. Lam, C. Zhu, K. V. Bukhryakov, P. Müller, A. Hoveyda, R. R. Schrock,* Synthesis and evaluation of molybdenum and tungsten monoaryloxide halide alkylidene complexes for Z‑selective cross-metathesis of cyclooctene and Z‑1,2-dichloroethylene.J. Am. Chem. Soc.,2016, 138, 15774-15783. M. Luo, C. Zhu, L. Chen, H. Zhang,* H. Xia,* Halogenation of carbyne complexes: Isolation of unsaturated metallaiodirenium ion and metallabromirenium ion.Chem. Sci.,2016, 7, 1815-1818. Z. Lin,* C. Zhu, H. Xia, HRMS studies on the fragmentation pathways of metallapentalyne.Spectrochim. Acta A, 2015, 136, 906-910. X. Wang, C. Zhu, H. Xia,* J. Zhu,* Theoretical study on the stability and aromaticity of metallasilapentalynes.Organometallics, 2014, 33, 1845-1850. J. Huang, R. Lin, L. Wu, Q. Zhao, C. Zhu, T. B. Wen,* H. Xia,* Synthesis, characterization, and electrochemical properties of bisosmabenzenes bridged by diisocyanides.Organometallics, 2010, 29, 2916-2925.