Schrock, Richard Royce - Massachusetts Institute of Technology

研究领域

Inorganic/Materials & Nanoscience/Organic

近期论文

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"Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds Through Stereoselective Catalytic Cross-Metathesis Reactions" Kiesewetter, E. T.; O’Brien, R. V.; Yu, E. C.; Meek, S. J.; Schrock, R. R.; Hoveyda, A. H. J. Am. Chem. Soc. 2013, 135, 6026-6029. "MonoAryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Mo and W that Contain 2,6-(2,5-R2pyrrolyl)2Phenoxide (R = i-Pr or Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene" Reithofer, M. R.; Dobereiner, G. E.; Schrock, R. R.; Müller, P.; Smith, S. J. Organometallics 2013, 32, 2489-2492. "Synthesis and ROMP Chemistry of Decafluoroterphenoxide Molybdenum Imido Alkylidene and Ethylene Complexes" Yuan, J.; Schrock, R. R.; Gerber, L. C. H.; Müller, P.; Smith, S. J. Organometallics 2013, 32, 2983-2992. "Alkyne Metathesis by Molybdenum and Tungsten Alkylidyne Complexes" Schrock, R. R. Chem. Commun. 2013, 49, 5529-5531. "Catalytic Z-Selective Cross-Metathesis with Secondary Silyl- and Benzyl-Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis" Mann, T. J.; Speed, A. W. H.; Schrock, R. R.; Hoveyda, A. H. Angew. Chem. Int. Ed. 2013, 52, 8395-8400. "Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes" Townsend, E. M.; Kilyanek, S. M.; Schrock, R. R.; Müller, P.; Smith, S. J.; Hoveyda, A. H. Organometallics 2013, 32, 4612 - 4617. "Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross Metathesis" Dobereiner, G. E.; Yuan, J.; Schrock, R. R.; Goldman, A. S.; Hackenberg, J. D. J. Am. Chem. Soc. 2013, 135, 12572-12575. "Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten" Jeong, H.; Kozera, D. J.; Schrock, R. R.; Smith, S. J.; Zhang, J.; Ren, N.; Hillmyer, M. A. Organometallics 2013, 32, 4843-4850. "B(C6F5)3 Activation of Oxo Tungsten Complexes That are Relevant to Olefin Metathesis" Peryshkov, D. V.; Forrest, W. P., Jr.; Schrock, R. R.; Smith, S. J.; Müller, P. Organometallics 2013, 32, 5256-5259. "Synthesis of Methylidene Complexes that Contain a 2,6-Dimesitylphenylimido Ligand and Ethenolysis of 2,3-Dicarbomethoxynorbornadiene" Gerber, L. C. H.; Schrock, R. R. Organometallics 2013, 32, 5573-5580. "Synthesis of a TREN in which the Aryl Substituents are Part of a 45 Atom Macrocycle" Cain, M. F.; Forrest, W. P. Jr., Peryshkov, D. V.; Schrock, R. R.; Müller, P. J. Am. Chem. Soc. 2013, 135, 15338-15341. "Rational Design of Highly Active "Hybrid" Phosphine-Phosphinite Pincer Iridium Catalysts for Alkane Metathesis" Nawara-Hultzsch, A. J.; Hackenberg, J. D.; Punji, B.; Supplee, C.; Bailey, B.; Schrock, R. R.; Maurice Brookhart, M.; Goldman, A. S. ACS Catalysis 2013, 3, 2505-2514. "A Well-Defined Silica-Supported Tungsten Oxo Alkylidene Is a Highly Active Alkene Metathesis Catalyst" Conley, M. P.; Mougel, V.; Peryshkov, D. V.; Forrest, W. P.; Gajan, D.; Lesage, A.; Emsley, L.; Copéret, C.; Schrock, R. R. J. Am. Chem. Soc. 2013, 135, 19069-19070. "Tungsten Oxo Alkylidene Complexes as Initiators for the Stereoregular Polymerization of 2,3-Dicarbomethoxynorbornadiene" Forrest, W. P.; Axtell, J. C.; Schrock, R. R. Organometallics 2014, 33, 2313-2325. "Synthesis of Stereoregular Polymers through Ring-Opening Metathesis Polymerization" Schrock, R. R. Acc. Chem. Res. 2014, 47, 2457-2466. "Stereospecific Ring-Opening Metathesis Polymerization of Norbornadienes Employing Tungsten Oxo Alkylidene Initiators" Forrest, W. P.; Weis, J. G.; John, J. M.; Axtell, J. C.; Simpson, J. H.; Swager, T. M.; Schrock, R. R. J. Am. Chem. Soc. 2014, 136, 10910-10913. "A One-Pot Tandem Olefin Isomerization/Metathesis-Coupling (ISOMET) Reaction" Dobereiner, G. E.; Erdogan, G.; Larsen, C. R.; Grotjahn, D. B.; Schrock, R. R. ACS Catal. 2014, 4, 3069-3076. "The Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain Sterically Demanding Aryl Thiolate Ligands" Townsend, E. M.; Hyvl, J.; Forrest, W. P.; Schrock, R. R.; Müller, P.; Hoveyda, A. H. Organometallics 2014, 33, 5334-5341. "Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand" Axtell, J. C.; Schrock, R. R.; Müller, P.; Smith, S. J.; Hoveyda, A. H. Organometallics 2014, 33, 5342-5348. "Characterization and Olefin Metathesis Activity of a Highly Stable Heterogeneous Tungsten Oxo Alkylidene Catalyst" Conley, M. P.; Forrest, W. P.; Mougel, V.; Siddiqi, G.; Safonova, O. V.; Copéret, C.; Schrock, R. R. Angew. Chem. Int. Ed., Sept 8.