Li, Gonghu - University of New Hampshire

个人简介

B.S., 1997, Hubei Normal University, China M.S., 2000, Chinese Academy of Sciences, China Ph.D., 2005, University of Iowa Postdoctoral Fellow, 2005-2007, Northwestern University Postdoctoral Associate, 2007-2009, Yale University Assistant Professor, 2009-current, University of New Hampshire

研究领域

We utilize our expertise in surface chemistry and materials chemistry to develop innovative catalysts for sustainable energy applications. A process of particular interest is solar fuel generation by CO2 reduction on surface molecular catalysts. Our projects rely heavily on spectroscopic (FTIR, EPR, UV-vis) and electrochemical techniques to characterize the catalysts and establish structure-function relationships. In addition, we integrate education with research by organizing solar energy workshops for K-12 science teachers.

近期论文

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He, H.; Liu, C.; Louis, M.E.; Li, G. “Infrared Studies of a Hybrid CO2-Reduction Photocatalyst Consisting of a Molecular Re(I) Complex Grafted on Kaolin,” J. Mol. Catal. A 2014, in press. http://dx.doi.org/10.1016/j.molcata.2014.08.020 Jin, T.; Liu, C.; Li, G. “Photocatalytic CO2 Reduction Using a Molecular Cobalt Complex Deposited on TiO2 Nanoparticles,” Chem. Commun. 2014, 50, 6221-6224 * One of the Hot ChemComm articles for May 2014. http://dx.doi.org/10.1039/C4CC00503A Dubois, K.D.; Liu, C.; Li, G. “Involvement of Surface Adsorbed Water in Photochromism of Spiropyran Molecules Deposited on NaY Zeolite,” Chem. Phys. Lett. 2014, 598, 53-57. http://dx.doi.org/10.1016/j.cplett.2014.03.014 Durrell, A.C.; Li, G.; Koepf, M.; Negre, C.F.; Allen, L.J.; McNamara, W.R.; Song, H.; Batista, V.S.; Crabtree, R.H.; Brudvig, G.W. “Photoelectrochemical Oxidation of a Turn-On Fluorescent Probe Mediated by a Surface MnII Catalyst Covalently Attached to TiO2 Nanoparticles,” J. Catal. 2014, 310, 37-44. http://dx.doi.org/10.1016/j.jcat.2013.07.001 Louis, M.; Li, G. “Nanostructured Photocatalysts for Solar Water Splitting,” in Nanoscience. Ed. Paul O’brien, The Royal Society of Chemistry. 2014, 2, 81-97. http://dx.doi.org/10.1039/9781849737623-00081 Dubois, K.D.; Li, G. “Innovative Photocatalysts for Solar Fuel Generation by CO2 Reduction,” in New and Future Developments in Catalysis: Solar Photocatalysis. Ed. Steven L. Suib, Elsevier: Amsterdam. 2013, 219-241 Liu, C.; Dubois, K.D.; Louis, M.E.; Vorushilov, A.; Li, G. “Photocatalytic CO2 Reduction and Surface Immobilization of a Tricarbonyl Re(I) Complex Modified with Amide Groups,” ACS Catal. 2013, 3, 655-662. http://dx.doi.org/10.1021/cs300796e He, H.; Liu, C.; Dubois, K.D.; Jin, T.; Louis, M.E.; Li, G. “Enhanced Charge Separation in Nanostructured TiO2 Materials for Photocatalytic and Photovoltaic Applications,” Ind. Eng. Chem. Res. 2012, 51, 11841-11849. http://dx.doi.org/10.1021/ie300510n Dubois, K.D.; He, H.; Liu, C.; Vorushilov, A.; Li, G. “Covalent Attachment of a Molecular CO2-Reduction Photocatalyst to Mesoporous Silica,” J. Mol. Catal. A 2012, 363-364, 208-213. http://dx.doi.org/10.1016/j.molcata.2012.06.011 Dubois, K.D.; Petushkov, A.; Cardona, E.G.; Larsen, S.C.; Li, G. “Adsorption and Photochemical Properties of a Molecular CO2 Reduction Catalyst in Hierarchical Mesoporous ZSM-5: An In Situ FTIR Study,” J. Phys. Chem. Lett. 2012, 3, 486-492. http://dx.doi.org/10.1021/jz201701y Agarwal, J.; Johnson, R.P.; Li, G. “Reduction of CO2 on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle,” J. Phys. Chem. A 2011, 115, 2877-2881 * One of the top 10 most read articles for Q2 2011 for J. Phys. Chem. A. http://dx.doi.org/10.1021/jp111342r McConnell, I.; Li, G.; Brudvig, G. W. “Energy Conversion in Natural and Artificial Photosynthesis,” Chem. Biol. 2010, 17, 434-447 Li, G.; Sproviero, E. M.; McNamara, W. R.; Snoeberger, R. C. I.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. “Reversible Visible-Light Photooxidation of an Oxomanganese Water-Oxidation Catalyst Covalently Anchored to TiO2 Nanoparticles,” J. Phys. Chem. B 2010, 114, 14214–14222 McNamara, W. R.; Snoeberger III, R. C.; Li, G.; Richter, C.; Allen, L. J.; Milot, R. L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. “Hydroxamate Anchors for Water-Stable Attachment to TiO2 Nanoparticles,” Energy Environ. Sci. 2009, 2, 1173-1175 Li, G.; Richter, C.; Milot, R. L.; Cai, L.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. “Synergistic Effect Between Anatase and Rutile TiO2 Nanoparticles in Dye-Sensitized Solar Cells,” Dalton Trans. 2009, 10078-10085 Li, G.; Sproviero, E. M.; Snoeberger, R. C. I.; Iguchi, N.; Blakemore, J. D.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. “Deposition of an Oxomanganese Water Oxidation Catalyst on TiO2 Nanoparticles: Computational Modeling, Assembly and Characterization,” Energy Environ. Sci. 2009, 2, 230-238 Chen, L.; Graham, M. E.; Li, G.; Gentner, D. R.; Dimitrijevic, N.; Gray, K. A. “Photoreduction of CO2 by TiO2 Nanocomposites Synthesized Through Reactive Direct Current Magnetron Sputter Deposition,” Thin Solid Films 2009, 517, 5641-5645 McNamara, W. R.; Snoeberger, R. C. I.; Li, G.; Schleicher, J. M.; Cady, C. W.; Poyatos, M.; Schmuttenmaer, C. A.; Crabtree, R. H.; Brudvig, G. W.; Batista, V. S. “Acetylacetonate Anchors for Robust Functionalization of TiO2 Nanoparticles with Mn(II)-Terpyridine Complexes,” J. Am. Chem. Soc. 2008, 130, 14329-14338 Li, G.; Dimitrijevic, N.; Chen, L.; Rajh, T.; Gray, K. A. “Role of Surface/Interfacial Cu2+ Sites in the Photocatalytic Activity of Coupled CuO-TiO2 Nanocomposites,” J. Phys. Chem. C 2008, 112, 19040-19044 Li, G.; Dimitrijevic, N.; Chen, L.; Nichols, J.; Rajh, T.; Gray, K. A. “The Important Role of Tetrahedral Ti4+ Sites in the Phase Transformation and Photocatalyt Activity of TiO2 Nanocomposites,” J. Am. Chem. Soc. 2008, 130, 5402-5403