Cummins, Christopher C - Massachusetts Institute of Technology

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Subhojit Majumdar, Julia M. Stauber, Taryn D. Palluccio, Xiaochen Cai, Alexandra Velian, Elena V. Rybak-Akimova, Manuel Temprado, Burjor Captain, Christopher C. Cummins, Carl D. Hoff, Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes. Inorg. Chem., 2014, 53, 11185–11196. Alexandra Velian, Matthew Nava, Manuel Temprado, Yan Zhou, Robert W. Field, and Christopher C. Cummins, A retro Diels–Alder route to diphosphorus chemistry: Molecular precursor synthesis, kinetics of P2 transfer to 1,3-Dienes, and detection of P2 by molecular beam mass spectrometry. J. Am. Chem. Soc. 2014, 136, 13586–13589. This paper was selected to be the SYNFACT of the Month. Christopher C. Cummins, Phosphorus: From the stars to land and sea. D?dalus 2014, 143, 9–20. Yanfeng Jiang, Khetpakorn Chakarawet, Andrea Laura Kohout, Matthew Nava, Nadia Marino, and Christopher C. Cummins, Dihydrogen Tetrametaphosphate, [P4O12H2]2–: Synthesis, Solubilization in Organic Media, Preparation of its Anhydride [P4O11]2– and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via Protonolysis. J. Am. Chem. Soc. 2014, 136, 11894–11897. See also Chem. Eng. News science concentrate entitled A new and improved cyclic polyphosphate. Andrew M. Ullman, Xianru Sun, Daniel J. Graham, Nazario Lopez, Matthew Nava, Rebecca De Las Cuevas, Peter Müller, Elena V. Rybak-Akimova, Christopher C. Cummins, and Daniel G. Nocera, Electron-transfer studies of a peroxide dianion. Inorg. Chem., 2014, 53, 5384–5391. Christopher C. Cummins, Chao Huang, Tabitha J. Miller, Markus W. Reintinger, Julia M. Stauber, Isabelle Tannou, Daniel Tofan, Abouzar Toubaei, Alexandra Velian, Gang Wu, The stannylphosphide anion reagent sodium bis(triphenylstannyl) phosphide: synthesis, structural characterization, and reactions with indium, tin, and gold electrophiles. Inorg. Chem., 2014, 53, 3678–3687. Jens M. Breunig, Daniel Tofan, Christopher C. Cummins, Contrasting cyclo-P3 ligand transfer reactivity of valence-isoelectronic aryloxide Complexes [(P3)Nb(ODipp)3]– and [(P3)W(ODipp)3]. Inorg. Chem., 2014, 2014, 1605–1609. This article is part of a special cluster issue on Advances in Phosphorus Chemistry with many fine articles on the subject. Ioana Knopf, Takashi Ono, Manuel Temprado Morena, Daniel Tofan, Christopher C. Cummins, Uptake of one and two molecules of CO2 by the molybdate dianion: a soluble, molecular oxide model system for carbon dioxide fixation. Chem. Sci. 2014, 5, 1772–1776. See Chem. Eng. News article by Stephen K. Ritter entitled Molybdate Dianion Traps Carbon Dioxide And Spits Out Formate. Anthony F. Cozzolino, Jared S. Silvia, Nazario Lopez, Christopher C. Cummins, Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide Dalton Trans. 2014, 43, 4639–4652. Cesar M. Manna, Mostafa Y. Nassar, Daniel Tofan, Khetpakorn Chakarawet, Christopher C. Cummins, Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4?) and cyclo-trimetaphosphate ([P3O9]3?). Dalton Trans. 2014, 43, 1509–1518. Lee-Ping Wang, Daniel Tofan, Jiahao Chen, Troy Van Voorhis, Christopher C. Cummins, A pathway to diphosphorus from the dissociation of photoexcited tetraphosphorus. RSC Adv. 2013, 3, 23166–23171. Adam S. Huss, John J. Curley, Christopher C. Cummins, and David A. Blank, Relaxation and Dissociation Following Photoexcitation of the (μ-N2)[Mo(N[t-Bu]Ar)3]2 Dinitrogen Cleavage Intermediate. J. Phys. Chem. B. 2013, 117, 1429–1436. Bess Vlaisavljevich, Paula L. Diaconescu, Wayne L. Lukens, Jr., Laura Gagliardi, Christopher C. Cummins, Investigations of the Electronic Structure of Arene-Bridged Diuranium Complexes. Organometallics 2013, 32, 1341–1352. Taryn D. Palluccio, Elena V. Rybak-Akimova, Subhojit Majumdar, Xiaochen Cai, Megan Chui, Manuel Temprado, Jared S. Silvia, Anthony F. Cozzolino, Daniel Tofan, Alexandra Velian, Christopher C. Cummins, Burjor Captain, and Carl D. Hoff, Thermodynamic and Kinetic Study of Cleavage of the N–O Bond of N-Oxides by a Vanadium(III) Complex: Enhanced Oxygen Atom Transfer Reaction Rates for Adducts of Nitrous Oxide and Mesityl Nitrile Oxide. J. Am. Chem. Soc. 2013, 135, 11357–11372. Daniel Tofan, Manuel Temprado, Subhojit Majumdar, Carl D. Hoff, and Christopher C. Cummins, Functionalization Reactions Characteristic of a Robust Bicyclic Diphosphane Framework Inorg. Chem. 2013, 52, 8851–8864. Cozzolino, Anthony F.; Tofan, Daniel; Cummins, Christopher C.; Temprado, Manuel; Palluccio, Taryn D.; Rybak-Akimova, Elena V.; Majumdar, Subhojit; Cai, Xiaochen; Captain, Burjor; Hoff, Carl D., Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex. J. Am. Chem. Soc. 2012, 134, just accepted. Velian, Alexandra; Cummins, Christopher C., Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene. J. Am. Chem. Soc. 2012, 134, 13978--13981. See Chem. Eng. News article by Stephen K. Ritter entitled New Phosphinidene Transfer Reagents. Tofan, Daniel; Cummins, Christopher C., Bicyclic dinuclear tris-(ditopic diphosphane) complexes of zerovalent group 10 metals. Chem. Sci. 2012, 3, 2474–2478. Free PDF download (permitted under terms of RSC License to Publish). Velian, Alexandra; Cummins, Christopher C., Synthesis of a diniobium tetraphosphorus complex by a 2(3-1) process. Chem. Sci. 2012, 3, 1003–1006. Free PDF download (permitted under terms of RSC License to Publish). Diaconescu, Paula L.; Cummins, Christopher C., μ:η6,η6 Arene-Bridged Diuranium Hexakisketimide Complexes Isolable in Two States of Charge. Inorg. Chem. 2012, 51, 2902–2916.

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