王天利 - 四川大学

个人简介

Dr. Tianli Wang was born in Sichuan province. She received her bachelor’s degree in applied chemistry (2006) from Sichuan University under the supervision of Prof. Xiaoming Feng and her Ph.D. in organic chemistry (2011) from the Institute of Chemistry Chinese Academy of Sciences (ICCAS) under the supervision of Prof. Qing-Hua Fan. After working as a Research Fellow with Prof. Yixin Lu at National University of Singapore (NUS), Tianli has been a full professor of chemistry at Sichuan University since the September of 2016. Curriculum Vitae Since 2016.09 Full Professor at Sichuan University 2012.06—2016.08 Research Fellow with Prof. Yixin Lu, National University of Singapore 2011.08—2012.05 Research Assistant, Institute of Chemistry Chinese Academy of Sciences (ICCAS) 2006.09—2011.07 Ph.D. in Organic Chemistry with Prof. Qing-Hua Fan, Institute of Chemistry Chinese Academy of Sciences (ICCAS) 2002.09—2006.07 B.S. in Applied Chemistry with Prof. Xiaoming Feng & Prof. Qing-Hua Fan Selected Awards and Distinctions 2022 The National Science Fund for Outstanding Young Scholars 2022 Sichuan Provincial Fund for Distinguished Young Scholars 2022 Thieme Chemistry Journals Award（2022） 2019 ACP Lectureship Award (to Japan) 2019 Specially Recruited Experts of Chengdu city 2019 Award of Outstanding Mentor, Sichuan University 2018 Specially Recruited Experts of Sichuan province 2018 Award of Outstanding Scientific and Technological Youth Talents, Sichuan University 2018 Outstanding Scholars of Sichuan University 2017 the “1000-Youth Talents Program of China” (2017) 2017 the “1000-Youth Talents Program of Sichuan Province” (2017) 2017 Award of Scientific Chinese People (Youth) of the Year 2017 (2017) 2016 Gold Award of Outstanding Mentor for “Singapore Science and Engineering Fair (SSEF)”

研究领域

Novel Catalysts Methodology Mechanism Bioactive Molecules

近期论文

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Zanjiao Liu,+ Siqiang Fang,+ Haoze Li,+ Chunxiu Xiao, Kai Xiao, Zhishan Su*, Tianli Wang* "Organocatalytic skeletal reorganization for enantioselective synthesis of S-stereogenic sulfinamides" Nat. Commun. 2024, 15, 4348. Xingjie Luo,+ Zhiyu Jiang,+ Siqun Yang, Xiaoyu Ren, Tianli Wang* "Organocatalyzed Asymmetric Conjugate Addition of Alcohols to β-Fluoroalkyl Vinylsulfones by Bifunctional Phosphonium Salt Catalyst" Chem. Eur. J. 2024, e202401325. Jixing Che, Siqiang Fang, Zanjiao Liu, Jiajia He, Jia-Yan Zheng, Fan Wang, Tianli Wang* "Access to Enantioenriched Allylic Alcohols via Peptide-Mimic Phosphonium Salt-Catalyzed Asymmetric Aerobic Hydroxylation" Chin. J. Chem. 2024, 42, 2017-2022. Lingzhu Chen, Youlin Deng, Tingting Li, Deyu Hu,* Xiaoyu Ren, Tianli Wang* "Asymmetric Nucleophilic Additions Promoted by Quaternary Phosphonium Ion-Pair Catalysts" CCS Chem. 2024. DOI: 10.31635/ccschem.024.202403858. Jia-Yan Zheng,+ Fan Wang,+ Yan Zhang,+ Zheng Zheng, Jia-Hong Wu, Xiaoyu Ren, Zhishan Su, Wenchuan Chen,* Tianli Wang* "Novel Stereo-Induction Pattern in Pudovik Addition/Phospha-Brook Rearrangement towards Chiral Trisubstituted Allenes" Angew. Chem. Int. Ed. 2024, 63, e202403707. Jia-Hong Wu, Siqiang Fang, Xingtao Zheng, Jiajia He, Yi Ma, Zhishan Su, Tianli Wang* "Organocatalytic Dynamic Kinetic ResolutionEnabled Asymmetric Synthesis of Phosphorus-Containing Chiral Helicenes" Angew. Chem. Int. Ed. 2023, 62, e202309515. Siqiang Fang,+ Jiajia He,+ Zanjiao Liu, Zhishan Su,* Fengyuan Guo, and Tianli Wang* “Atherton-Todd Reaction-Guided Enantioselective Synthesis of Axially Chiral Olefins via Bifunctional Phosphonium Salt-Regulating Ketone-Enol Tautomerism" ACS Catal. 2023, 13, 13077−13088. Fengyuan Guo,+ Siqiang Fang,+ Jiajia He,+ Zhishan Su* and Tianli Wang* "Enantioselective Organocatalytic Synthesis of Axially Chiral Aldehyde-containing Styrenes via SNAr Reaction-Guided Dynamic Kinetic Resolution" Nat. Commun. 2023, 14, 5050. Hui-Lin Hu,+ Siqiang Fang,+ Yulin Chen, Wei Wan, Yuqiao Zhou, Zhipeng Xu,* Tianli Wang* "Access to Phosphorous-containing Cyclopenta[b]benzofuranols via Bifunctional Phosphonium Salt-promoted Serendipitous Cascade Reaction" Org. Chem. Front. 2023, 10, 5817-5822. Siqiang Fang+, Zanjiao Liu+, Tianli Wang* "Design and Application of Peptide-Mimic Phosphonium Salt Catalysts in Asymmetric Synthesis" Angew. Chem. Int. Ed. 2023, 62, e202307258. Siqiang Fang, Zanjiao Liu, Tianli Wang* "Recent Advances of the Atherton-Todd Reaction" Chin. J. Org. Chem. 2023, 43, 1069-1083. Jixing Che,+ Siqiang Fang,+ Jianke Pan, Lixiang Zhu, Xiaoyu Ren, and Tianli Wang* "Asymmetric Mannich/Radical Debromination Cascade of a-Bromoketones by Dipeptide-Phosphonium Salt Catalysis: Enantioselective Synthesis of β-Amino Ketone-Pyrazolinones" Asian J. Org. Chem 2023, 12, e202300079. Jia-Hong Wu,+ Jian-Ping Tan,+ Jia-Yan Zheng,+ Jiajia He, Zhenlei Song,* Zhishan Su, Tianli Wang* "Towards Axially Chiral Pyrazole-Based Phosphorus Scaffolds by Dipeptide-Phosphonium Salt Catalysis" Angew. Chem. Int. Ed. 2023, 62, e202215720. Kehan Li,+ Dongming Lu,+ Jian-Ping Tan,* Xiaoyu Ren, Tianli Wang* "Chemoselective Annulation of 2-Benzothiazolimines Enabled by Bifunctional Phosphonium Salt: Highly Enantioselective Synthesis of Indole-fused Cyclic Thiourea Scaffolds" Asian J. Org. Chem. 2022, 11, e202200368. Hui-Lin Hu,+ Xiaoyu Ren,+ Jiajia He, Lixiang Zhu, Siqiang Fang, Zhishan Su, Tianli Wang* "Stereodivergently Asymmetric Synthesis of Chiral Phosphorus Compounds by Synergistic Combination of Ion-pair Catalyst and Base" Sci. China Chem. 2022, 65, 2500-2511. Yuan Chen,+ Jiajia He,+ Cheng Zhuang, Zanjiao Liu, Kai Xiao, Zhishan Su,* Xiaoyu Ren, and Tianli Wang* "Synergistic Catalysis between a Dipeptide Phosphonium Salt and a Metal-Based Lewis Acid for Asymmetric Synthesis of N-Bridged [3.2.1] Ring Systems" Angew. Chem. Int. Ed. 2022, 61, e202207334. Lixiang Zhu,+ Heling Peng,+ Yan Guo, Jixing Che, Jia-Hong Wu, Zhishan Su, and Tianli Wang* "Enantioselective Synthesis of Atropisomeric Biaryl Phosphorus Compounds by Chiral Phosphonium-Salt-Enabled Cascade Arene Formation" Angew. Chem. Int. Ed. 2022, 61, e202202467. Jian-Ping Tan,+ Kehan Li,+ Boming Shen,+ Cheng Zhuang, Zanjiao Liu, Kai Xiao, Peiyuan Yu*, Bing Yi,* Xiaoyu Ren and Tianli Wang* "Asymmetric synthesis of N-bridged [3.3.1] ring systems by phosphonium salt/Lewis acid relay catalysis" Nat. Commun. 2022, 13, 357. Xuemei Wang,+ Liang Zhou,+ Hongkui Zhang, Xiaoyu Ren,* Guowei Gao, and Tianli Wang* "Enantioselective γ‑Addition-Driven Cascade of β,γ-Unsaturated Ketones by Ion-Pair Catalysis: Access to Chiral 1,3-Dioxolochroman Scaffolds" Org. Lett. 2022, 24, 38-42. Jian-Ping Tan,+ Yuan Chen,+ Xiaoyu Ren,* Yumeng Guo, Bing Yi,* Hongkui Zhang, Guowei Gao, and Tianli Wang* “In situ phosphonium-containing Lewis base-catalyzed 1,6-cyanation reaction: facile way to α-diaryl and α-triaryl acetonitriles” Org. Chem. Front. 2022, 9, 156-162. Yuan Chen,+ Zhaoyuan Yu,+ Zhiyu Jiang,+ Jian-Ping Tan, Jia-Hong Wu, Yu Lan,* Xiaoyu Ren, and Tianli Wang* "Asymmetric Construction of Tertiary/Secondary Carbon− Phosphorus Bonds via Bifunctional Phosphonium Salt Catalyzed 1,6-Addition" ACS Catal. 2021, 11, 14168−14180. Siqiang Fang, Zanjiao Liu, Hongkui Zhang, Jianke Pan, Yuan Chen, Xiaoyu Ren, and Tianli Wang* "Access to S‑Stereogenic Free Sulfoximines via Bifunctional Phosphonium Salt-Catalyzed Desymmetrization of Bisphenols" ACS Catal. 2021, 11, 13902−13912. Hongkui Zhang,+ Jiajia He,+ Yayun Chen,+ Cheng Zhuang, Chunhui Jiang,* Kai Xiao, Zhishan Su,* Xiaoyu Ren, and Tianli Wang* “Regio- and Stereoselective Cascade of β,γ-Unsaturated Ketones by Dipeptided Phosphonium Salt Catalysis: Stereospecific Construction of Dihydrofuro-Fused [2,3-b] Skeletons” Angew. Chem. Int. Ed. 2021, 60，19860-19870. Zhenghuai Feng, Hongkui Zhang, Xiaoyu Ren,* Chunhui Jiang, Guowei Gao and Tianli Wang* "Enantioselective Construction of Tertiary C(sp3)-P Bonds by Thiourea-based Bifunctional Phosphonium Salt-catalyzed Hydrophosphonylation of Ketone Compounds" ChemCatChem. 2021, 13, 3754-3760. Song Zhang,+ Zhenghuai Feng,+ Chunhui Jiang*, Xiaojun Yu, Jianke Pan, Juan Du, Zhiyu Jiang, Yuan Chen, and Tianli Wang* "Highly Enantioselective Synthesis of Phosphorus-containing e-Benzosultams via Bifunctional Phosphonium Salt-promoted Hydrophosphonylation" Chem. Eur. J. 2021, 27, 11285-11290. Zhiyu Jiang,+ Xin Liu,+ Hongkui Zhang, Jian-Ping Tan, Xiaoyu Ren*, Guowei Gao, Tianli Wang* "Asymmetric Cyclodearomatization of 2-Nitroindoles and 2-Nitrobenzofurans for Constructing CF3-containing Spiro-polycycles by Bifunctional Phosphonium Salt Catalysis" Adv. Synth. Catal. 2021, 363, 3115-3120. Siqiang Fang,+ Jian-Ping Tan,+ Jianke Pan, Hongkui Zhang, Yuan Chen, Xiaoyu Ren, Tianli Wang* "Enantiodivergent Kinetic Resolution of 1,1'-Biaryl-2,2'-Diols and Amino Alcohols by Dipeptide-Phosphonium Salt Catalysis Inspired by the Atherton-Todd Reaction" Angew. Chem. Int. Ed. 2021, 60, 14921-14930. Lixiang Zhu, Xiaoyu Ren, Juan Du, Jia-Hong Wu, Jian-Ping Tan, Jixing Che, Jianke Pan, Tianli Wang* “Transition metal-free multicomponent reaction towards constructing chiral 2H-1,4-benzoxazine scaffolds” Green Chem. 2020, 22, 7506-7512. Dongming Lu, Jia-Hong Wu, Jianke Pan, Xue Chen, Xiaoyu Ren, Tianli Wang* "Asymmetric Synthesis of Benzothiazolopyrimidines with High Catalytic Efficiency and Stereoselectivity under Bifunctional Phosphonium Salt System" Chem. Commun. 2020, 56, 11231-11234. Jian-Ping Tan,+ Xiaojie Li,+ Yuan Chen, Xianle Rong, Lixiang Zhu, Chunhui Jiang, Kai Xiao, Tianli Wang* "Highly Stereoselective Construction of Polycyclic Benzofused Tropane Scaffolds and Their Latent Bioactivities: Bifunctional Phosphonium Salt-enabled Cyclodearomatization Process" Sci. China Chem. 2020, 63, 1091-1099. Hongkui Zhang,+ Chunhui Jiang,+ Jian-Ping Tan, Hui-Lin Hu, Yayun Chen, Xiaoyu Ren, Hong-Su Zhang, Tianli Wang* “Highly Enantioselective Construction of Fully-substituted Stereocenters Enabled by In-situ Phosphonium-containing Organocatalysis” ACS Catal. 2020, 10, 5698-5706. (Highted by B. List*, Synfacts, 2020, 16, 0967) Xiaojun Yu, Song Zhang, Zhiyu Jiang, Hong-Su Zhang, Tianli Wang* “Highly efficient and convenient access to phosphinates via CHCl3-assisted direct phosphorylation between R2P(O)H and ROH by phosphonium salt catalysis” Eur. J. Org. Chem. 2020, 20, 3110-3113. Juan Du, Jia-Hong Wu, Lixiang Zhu, Xiaoyu Ren, Chunhui Jiang, Tianli Wang* "Bifunctional Phosphonium Salt-Catalyzed Enantioselective [4 + 2] Annulation of Isoindigos with Allenes: Access to Complex Heterocycles with Centerpiece of 4H-Pyrans." Adv. Synth. Catal. 2020, 362, 2510-2516. Dongming Lu, Xin Liu, Jia-Hong Wu, Song Zhang, Jian-Ping Tan, Xiaojun Yu, Tianli Wang* “Asymmetric Construction of Bispiro‐Cyclopropane‐Pyrazolones via a [2 + 1] Cyclization Reaction by Dipeptide‐Based Phosphonium Salt Catalysis” Adv. Synth. Catal. 2020, 362, 1966-1971. Xin Liu, Dongming Lu, Jia-Hong Wu, Jian-Ping Tan, Chunhui Jiang, Guowei Gao,* Tianli Wang* “Stereoselective Synthesis of CF3-Containing Spirooxindoles via 1,3-Dipolar Cycloaddition by Dipeptide-Based Phosphonium Salt Catalysis” Adv. Synth. Catal. 2020, 362, 1490-1495. Jia-Hong Wu, Jianke Pan, Juan Du, Xiaoxia Wang, Xuemei Wang, Chunhui Jiang, Tianli Wang.* “Enantioselective Synthesis of Multifunctionalized 4H-Pyrans via Formal [4 + 2] Annulation Process by Bifunctional Phosphonium Salt Catalysis” Org. Lett. 2020, 22, 395-399. Jian-Ping Tan,+ Hongkui Zhang,+ Zhiyu Jiang, Yuan Chen, Xiaoyu Ren, Chunhui Jiang, Tianli Wang* “Enantioselective Construction of Spiro[chroman-thiazolones]: Bifunctional Phosphonium Salt-Catalyzed [2+4] Annulation between 5-Alkenyl Thiazolones and ortho-Hydroxyphenyl- Substituted para-Quinone Methides”. Adv. Synth. Catal. 2020, 362, 1058-1063. Chunhui Jiang,+ Yayun Chen,+ Hongkui Zhang, Jian-Ping Tan, Tianli Wang* "Catalyst-Free Synthesis of a-Functionalized 2H-Chromenes in Water:ATandem Self-Promoted pseudo-Substitution and Decarboxylation Process" Chem. Asian. J. 2019, 14, 2938-2944. Jianke Pan,+ Jia-Hong Wu,+ Hongkui Zhang, Xiaoyu Ren, Jian-Ping Tan, Lixiang Zhu, HongSu Zhang, Chunhui Jiang, Tianli Wang* “Highly Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines: aza-Darzens Reaction of Cyclic Imines with α-halogenated Ketones Catalyzed by Bifunctional Phosphonium Salt”. Angew. Chem. Int. Ed. 2019, 58, 7425-7430. Jian-Ping Tan,+ Peiyuan Yu,+ Jia-Hong Wu, Yuan Chen, Jianke Pan, Chunhui Jiang, Xiaoyu Ren, HongSu Zhang, Tianli Wang.* “Bifunctional Phosphonium Salt Directed Enantioselective Formal [4+ 1] Annulation of Hydroxyl-Substituted Quinone Methides with α-halogenated Ketones” Org. Lett. 2019, 21, 7298-7302. Lixiang Zhu,+ Xiaoyu Ren,+ Zhongxiu Liao, Jianke Pan, Chunhui Jiang, and Tianli Wang.* “Asymmetric Three-Component Cyclizations toward Structurally Spiro Pyrrolidines via Bifunctional Phosphonium Salt Catalysis”. Org. Lett. 2019, 21, 8667-8672. Song Zhang,+ Xiaojun Yu,+ Jianke Pan, Chunhui Jiang,* Hongsu Zhang, Tianli Wang.* “Asymmetric Synthesis of Spiro-Structural 2,3-Dihydrobenzofurans via the Bifunctional Phosphonium Salt-Promoted [4 + 1] Cyclization of Ortho-Quinone Methides with α-Bromoketones” Org. Chem. Front. 2019, 6, 3799-3803. Guofei Huang,+ Xiaoyu Ren,+ Chunhui Jiang, Jia-Hong Wu, Guowei Gao, Tianli Wang.* “Efficient Synthesis of (E)-2-Nitromethylcinnamates via Phosphine-Catalyzed Tandem α-Addition and 1,3-Rearrangement”. Org. Chem. Front. 2019, 6, 2872-2876. Jia-Hong Wu,+ Jianke Pan,+ Tianli Wang* “Dipeptide-Based Phosphonium Salt Catalysis: Application to Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines”. Synlett 2019, 30, 2101-2106.