Daugulis, Olafs - University of Houston

个人简介

Postdoctoral Associate, University of North Carolina at Chapel Hill, 2000-2003 Ph.D., University of Wisconsin-Madison, 1999 Riga Technical University, Riga, Latvia, 1991

研究领域

Broad interests in synthetic organic and organometallic methodology including: • Group 11 metal chemistry • Application of organometallic chemistry to organic synthesis and polymer chemistry • Development of new enantio- and diastereoselective transformations Students and postdocs in our group will be exposed to research at the convergence of organic, organometallic and polymer chemistry, often having direct technological applications. The training will provide these individuals with the capacity to make contributions in both science and technology.

近期论文

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"Copper-Promoted Sulfenylation of sp2 C-H Bonds"" Tran, L. D.; Popov, I.; Daugulis, O.* J. Am. Chem. Soc. 2012, 134, 18237. "Direct Intermolecular Aniline Arylation via Benzyne Intermediates"" Truong, T.; Daugulis, O.* Org. Lett. 2012, 14, 5964. "Divergent Reaction Pathways for Phenol Arylation by Arynes: Synthesis of Helicenes and 2-Arylphenols"" Truong, T.; Daugulis, O.* Chem. Sci. 2013, 4, 531. "Directed Amination of Non-Acidic Arene C H Bonds by a Copper–Silver Catalytic System"" Tran, L. D.; Roane, J.; Daugulis, O.* Angew. Chem., Int. Ed. 2013, 52, 6043. "Copper-Catalyzed, Directing Group-Assisted Fluorination of Arene and Heteroarene C−H Bonds"" Truong, T.; Klimovica, K.; Daugulis, O.* J. Am. Chem. Soc. 2013, 135, 9342. C&E News Perspective. "Superhydrophobic Perfluorinated Metal-Organic Frameworks"" Chen, T. -H.; Popov, I.;* Zenasni, O.; Daugulis, O.; Miljanić, O.* Chem. Commun. 2013, 49, 6846. "Synthesis of Highly Branched Polyethylene Using “Sandwich” (8-p-Tolyl Naphthyl α-Diimine)Nickel(II) Catalysts"" Zhang, D.; Nadres, E. T.; Brookhart, M.*; Daugulis, O.* Organometallics 2013, 32, 5136. "Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C-H Bonds"" Nadres, E. T.; Santos, G. I. F.; Shabashov, D.; Daugulis, O.* J. Org. Chem. 2013, 78, 9689. "Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide"" Tran-Vu, H.; Daugulis, O.* ACS Catalysis 2013, 3, 2417. "Copper-Catalyzed Etherification of Arene C-H Bonds"" Roane, J.; Daugulis, O.* Org. Lett. 2013, 15, 5842. "Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events"" Vaidya, T.; Klimovica, K.; LaPointe, A.; Keresztes, I.; Lobkovsky, E.; Daugulis, O.*; Coates, G.* J. Am. Chem. Soc. 2014, 136, 7213. "A General Method for Functionalized Polyaryl Synthesis via Aryne Intermediates"" Truong, T.; Mesgar, M.; Le, K. K. A.; Daugulis, O.* J. Am. Chem. Soc. 2014, 136, 8568. "Cobalt-Catalyzed, Aminoquinoline-Directed sp2 C-H Bond Alkenylation by Alkynes"" Grigorjeva, L.; Daugulis, O.* Angew. Chem., Int. Ed. 2014, 53, 10209. "Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp2 C-H Bonds with Alkenes"" Grigorjeva, L.; Daugulis, O.* Org. Lett. 2014, 16, 4684. ACS Editors Choice for August 22. "Cobalt-Catalyzed Direct Carbonylation of Aminoquinoline Benzamides"" Grigorjeva, L.; Daugulis, O.* Org. Lett. 2014, 16, 4688. "Thermally robust and porous noncovalent organic framework with high afﬁnity for ﬂuorocarbons and Freons"" Chen, T.-H.; Popov, I.; Kaveevivitchai, W.; Chuang, Y.-C.; Chen, Y.-S.; Daugulis, O.; Jacobson, A. J.; Miljanić, O.* Nat. Comm. 2014, 5, 5131. PhysOrgChem Perspective. C&E News Perspective. "Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using ""Sandwich"" Diimine Palladium Catalysts"" Allen, K.; Campos, J.; Daugulis, O.; Brookhart, M.* ACS Catalysis 2015, 5, 456. "Synthesis of Branched Ultra-High-Molecular-Weight Polyethylene Using Highly Active Neutral, Single-Component Ni(II) Catalysts"" Chen, Z.; Mesgar, M.; White, P.; Daugulis, O.*; Brookhart, M.* ACS Catalysis 2015, 6, 631. "Macrocycle Embrace: Encapsulation of Fluoroarenes by m-Phenylene Ethynylene Host"" Popov, I.; Chen, T.-H.; Belyakov, S.; Daugulis, O.; Wheeler, S. E.; Miljanic, O. S.* Chemistry - A European Journal 2015, 21, 2750. "Cobalt-Promoted Dimerization of Aminoquinoline Benzamides"" Grigorjeva, L.; Daugulis, O.* Org. Lett., in press.