Asandei, Alexandru D. - University of Connecticut

个人简介

Postdoctoral Fellow, University of Pennsylvania, Philadelphia, 1999-2001 Ph.D. Case Western Reserve University B.S./M.S Polytechnical Institute of Iasi, Romania

研究领域

Design, synthesis and characterization of organic and inorganic monomers and polymers; complex, unconventional organic, inorganic, organometallic and polymer synthesis, new concepts, reactions and mechanisms with projects on catalysis, living radical and ring opening polymerizations, complex polymer architectures, fluoro and biodegradable polymers, liquid crystals, self-assembly and nanostructures.

近期论文

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Mn2(CO)10-Visible Light Photomediated, Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof. Asandei, Alexandru D.; Adebolu, Olumide I.; Simpson, Christopher P. Handbook of Fluoropolymer Science and Technology. 2014, 21-42. DOI: 10.1002/9781118850220.ch2 [PDF] Visible light hypervalent iodide carboxylate photo(trifluoro)methylations and controlled radical polymerization of fluorinated alkenes. Asandei, Alexandru D.; Adebolu, Olumide I.; Simpson, Christopher P.; Kim, J. S. Angew. Chem., Int. Ed. 2013, 52(38),10027-10030.DOI: 10.1002/anie.201303826. [PDF] Mild-Temperature Mn2(CO)10-Photomediated Controlled Radical Polymerization of Vinylidene Fluoride and Synthesis of Well-Defined Poly(vinylidene fluoride) Block Copolymers Asandei, Alexandru D.; Adebolu, Olumide I.; Simpson, Christopher P. Journal of the American Chemical Society 2012, 134(14), 6080-6083. DOI: 10.1021/ja300178r. [PDF] Towards metal mediated radical polymerization of vinylidene fluoride Asandei, Alexandru D.; Simpson, Christopher P.; Adebolu, Olumide I.; Chen, Yanhui ACS Symposium Series 2012, 1106 Advances in Fluorine-Containing Polymers , 47-63.DOI: 10.1021/bk-2012-1106.ch004. [PDF] Stabilization of Graphene Sheets by a Structured Benzene/Hexafluorobenzene Mixed Solvent Oyer, Andrew J.; Carrillo, Jan-Michael Y.; Hire, Chetan C.; Schniepp, Hannes C.; Asandei, Alexandru D.; Dobrynin, Andrey V.; Adamson, Douglas H. Journal of the American Chemical Society 2012, 134(11), 5018-5021. DOI: 10.1021/ja211225p. [PDF] Biopolymer composites of wheat gluten with silica and alumina Hemsri, Sudsiri; Asandei, Alexandru D.; Grieco, Kasia; Parnas, Richard S. Composites, Part A: Applied Science and Manufacturing 2011, 42A(11), 1764-1773. DOI: 10.1016/j.compositesa.2011.07.032. [PDF] Aqueous electrospinning of wheat gluten fibers with thiolated additives Dong, Jing; Asandei, Alexandru D.; Parnas, Richard S. Polymer 2010, 51(14), 3164-3172. DOI: 10.1016/j.polymer.2010.04.058. [PDF] Cp2TiCl-mediated controlled radical polymerization of isoprene initiated by epoxide radical ring opening Asandei, Alexandru D.; Simpson, Christopher P.; Yu, Hyun S.; Adebolu, Olumide I.; Saha, Gobinda; Chen, Yanhui ACS Symposium Series 2009, 1024 Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP 149-163. DOI: 10.1021/bk-2009-1024.ch010. [PDF] Cp2TiCl-catalyzed radical chemistry: living styrene polymerizations from epoxides, aldehydes, halides, and peroxides Asandei, Alexandru D.; Chen, Yanhui; Saha, Gobinda; Moran, Isaac W. Tetrahedron 2008, 64(52), 11831-11838. DOI: 10.1016/j.tet.2008.08.106 [PDF] Imaging and Thermal Studies of Wheat Gluten/Poly(vinyl alcohol) and Wheat Gluten/Thiolated Poly(vinyl alcohol) Blends. Dong, J.; Dicharry, R.; Waxman, E.; Parnas, R. S.; Asandei, A. D. Biomacromolecules 2008, 9, 568–573.DOI: 10.1021/bm7011136. [PDF] Living Ring Opening Polymerization of e-Caprolactone with Ti Alkoxides Derived from the Cp2TiCl-Catalyzed SET Reduction of Aldehydes. Alexandru, A. D.; Chen, Y.; Adebolu, O. I.; Simpson, C. P. J. Polym. Sci.: Part A: Polym. Chem. 2008, 46(8), 2869-2877. DOI: 10.1002/pola.22621. [PDF] Similarities and Differences of Epoxide, Aldehyde and Peroxide Initiators for Cp2TiCl-Catalyzed Styrene Living Radical polymerizations. Asandei, A. D.; Chen Y.; Moran, I. W.; Saha, G. J. Organomet. Chem. 2007, 692, 3174. doi:10.1016/j.jorganchem.2007.01.042. [PDF] Cp2TiCl-Catalyzed Epoxide Radical Ring Opening: A New Initiating Methodology for Graft Copolymer Synthesis. Asandei, A. D.; Saha, G. Macromolecules 2006,39, 8999. DOI:10.1021/ma0618833. [PDF] Cp2TiCl-Catalyzed SET Reduction of Aldehydes: A new Initiating Protocol for Living Radical Polymerizations. Asandei, A. D.; Chen, Y. Macromolecules 2006, 39, 7549. DOI: 10.1021/ma0604791. [PDF] Better Polymers from Renewable Materials: Wheat Gluten / Thiolated Polyvinyl Alcohol Blends with Improved Properties. Dicharry, R. M.; Ye, P.; Saha, G.; Waxman, E.; Asandei, A. D.; Parnas, R. S. Biomacromolecules 2006, 7, 2837. DOI: 10.1021/bm060432n. [PDF] Book Chapter: Ti-Catalyzed Living Radical Polymerization of Styrene Initiated by Epoxide Radical Ring Opening. Asandei, A. D.; Moran, I. W.; Saha, G.; Chen, Y. ACS Symposium Series, Progress in Controlled/Living Radical Polymerization. 2006, 944, 125. DOI:10.1021/bk-2006-0944.ch010. Ti-Mediated Living Radical Styrene Polymerizations. VI. Cp2TiCl-Catalyzed Initiation by Epoxide Radical Ring Opening: Effect of Reducing Agents, Temperature, Ti/Epoxide and Ti/Zn Ratios. Asandei, A. D.; Moran, I. W.; Saha, G.; Chen, Y. J. Polym. Sci.: Part A: Polym. Chem. 2006, 44, 2156. DOI: 10.1002/pola.21326. [PDF] Ti-Mediated Living Radical Styrene Polymerizations. V. Cp2TiCl-Catalyzed Initiation by Epoxide Radical Ring Opening: Effect of Solvents and Additives. Asandei, A. D.; Moran I. W.; Saha, G.; Chen, Y. J. Polym. Sci.: Part A: Polym. Chem. 2006, 44, 2015. DOI:10.1002/pola.21307. [PDF] The Ligand Effect in Ti-Mediated Living Radical Styrene Polymerizations Initiated by Epoxide Radical Ring Opening: 3. Substituted Sandwich Complexes. Asandei, A. D.; Moran, I. W. J. Polym. Sci.: Part A: Polym. Chem. 2006, 44, 1060.Article featured on the journal cover DOI:10.1002/pola.21220. [PDF] Cp2TiCl-Catalyzed Living Radical Polymerization of Styrene Initiated from Peroxides. Asandei, A. D.; Saha, G. J. Polym. Sci.: Part A: Polym. Chem. 2006, 44, 1106. DOI:10.1002/pola.21206. [PDF]