个人简介

Allan Pinhas is a Professor of Chemistry at the University of Cincinnati. After his BS degree from the University of Rochester, he went to Cornell University where he earned a PhD. It was at Cornell, working under the direction of Prof. Barry Carpenter, that he became interested in experimental organometallic chemistry. In addition, while in graduate school, he studied theoretical chemistry with Prof. Roald Hoffmann. He then went to Yale University as a postdoctoral fellow, working with Prof. Jerry Berson on the photochemistry of molecules in their triplet state. He took a second postdoctoral fellowship at the University of North Carolina, working with Prof. Maurice Brookhart on the reactivity of organometallic complexes. Dr. Pinhas joined the faculty of the University of Cincinnati in 1982.

研究领域

Organometallic chemistry; Molecular rearrangements; Catalysis; Carbon-carbon bond formation

He is a physical-organic chemist who is interested in the effect metal complexes have on organic molecules, especially organic compounds that contain small rings. In addition, he is interested in new methods for the formation of carbon-carbon bonds.

近期论文

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Hancock, M. T.; Pinhas, A. R. "A Convenient and Inexpensive Conversion of an Aziridine to an Oxazolidinone". Tetrahedron Lett. (2003), 44, 5457-5460. Hancock, M. T.; Pinhas, A. R. "The Conversion of an Aziridine Plus an Iminium Salt to a 1,2-Diamine". Tetrahedron Lett. (2003), 44, 7125-7128. Hancock, M. T.; Minto, R. E.; Pinhas, A. R. "The Conversion of an Aziridine Plus a Phenyl-substituted Amine Oxide or Aminoether to a Benzodiazepine Derivative". Tetrahedron Lett. (2003), 44, 8357-8360. Vonderheide, A. P.; Meija, J.; Tepperman, K.; Puga, A.; Pinhas, A. R.; States, J. C.; Caruso, J. A. "Retention of Cr(III) by High-Performance Chelation Ion Chromatography Interfaced to Inductively-Coupled Plasma-Mass Spectrometric Detection with Collision Cell". Journal of Chromatography A (2004), 1024, 129-137. Hancock, M. T.; Pinhas, A. R. "Synthesis of Oxazolidinones and 1,2-Diamines from N-Alkyl Aziridines". Synthesis (2004), 2347-2355. Wallace, J. R.; Lieberman, D. L.; Hancock, M. T.; Pinhas, A. R. "Conversion of an Aziridine to an Oxazolidinone Using a Salt and Carbon Dioxide in Water". J. Chem. Ed. (2005), 82, 1229-1230. Mack, E. T.; Brown, M. J.; Krause, J. A.; Lieberman, D. L.; Pinhas, A. R. "2-(2-Bromo-4-chloroanilino)-2-phenylethanol". Acta Cryst. (2005), E61, 2810-2812. Hermanson, J. R.; Figley, T. M.; Seibert, A. L.; Pinhas, A. R. "The Reactivity of a Nucleophilic Nickel Acylate Complex". Journal of Organometal. Chem. (2008), 693, 2061-2064. Keller, C. L.; Dalessandro, J. D.; Hotz, R. P.; Pinhas, A. R. "Reactions In Water: Alkyl Nitrile Coupling Reactions Using Fenton's Reagent". Journal of Organic Chemistry (2008), 73, 3616-3618. McNeely, S. C.; Belshoff, A. C.; Taylor, B. F.; Fan, T. W.-M.; McCabe, M. J.; Pinhas, A. R.; States, J. C. "Sensitivity to Sodium Arsenite in Human Melanoma Cells Depends Upon Susceptibility to Arsenite-induced Mitotic Arrest". Toxicology and Applied Pharmacology (2008), 229, 252-261. "The High Yield and Regioselective Conversion of an Unactivated Aziridine to an Oxazolidinone Using Carbon Dioxide with Ammonium Iodide as the Catalyst"” Phung, C.; Pinhas, A. R. Tetrahedron Lett. 2010, 51, 4552-4554. "A Kinetic Study using Evaporation of Different Types of Hand-Rub Sanitizers" J. Chem. Ed. 2010, 87. 950-951. A Redox Titration for a General-Organic-Biochemistry (GOB) Course Using Povidone Iodine” Pinhas, A. R. J. Chem. Ed. 2010, 87. 985-986. “Learning about Regiochemistry from a Hydrogen-Atom Abstraction Reaction in Water” Sears-Dundes, C.; Huon, Y.; Hotz, R. P.; Pinhas, A. R. J. Chem. Ed. 2011, 88, 1437-1438. “The Solvent-free and Catalyst-free Conversion of an Aziridine to an Oxazolidinone Using Only Carbon Dioxide” Phung, C.; Ulrich, R. M.; Ibrahim, M.; Tighe, N. T. G.; Lieberman, D. L.; Pinhas, A. R. Green Chem. 2011, 13, 3224-3229. “Sodium Arsenite ± Hyperthermia Sensitizes p53 Expressing Human Ovarian Cancer Cells to Cisplatin by Modulating Platinum DNA Damage Responses” Muenyi, C. S.; Pinhas, A. R.; Fan, T. W.; Brock, G. N.; Helm, C. W.; States, J. C. Toxicol. Sci. 2012, 127, 139-149. “Food Waste as a Source of Biofuels” Pratt, L. M.; Gunasekaran, M.; Voit, S.; Thach, L. N.; Thi, L. T. X.; Khiem, C. N. D.; Slocum, J.; McCallister, M.; Herrmann, Z. M.; Doepke, A.; Nubel, C.; Pinhas, A. R.; Gardner, O. Journal of Science and Technology Development 2012, 15, 46-56.