Baldwin, Michael J. - University of Cincinnati

个人简介

Michael Baldwin is an Associate Professor of Chemistry at the University of Cincinnati. He is an inorganic chemist with research interests in catalysis, spectroscopy, bioinorganic chemistry, and oxygen activation. He received a BS degree in chemistry from Seattle University in 1986, and a PhD in chemistry from Stanford University in 1992 for work with Edward Solomon on spectroscopic studies of copper-peroxide complexes modeling the oxygen transport protein oxyhemocyanin and the enzyme oxytyrosinase. As a NIH postdoctoral fellow with Professor Vincent Pecoraro at the University of Michigan, he worked on models of the photosynthetic oxygen evolving complex. In 1997, he joined the faculty at the University of Cincinnati.

研究领域

Bioinorganic Chemistry Catalysis Photochemistry Spectroscopy Oxygen Activation by Transition Metals

近期论文

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Goldcamp, M. J.; Rosa, D. T.; Landers, N. A.; Mandel, S. M.; Krause Bauer, J. A.; Baldwin, M. J. "Facile and Versatile Synthesis of Polydentate Metal Chelators with Both Amide and Oxime Donor Groups". Synthesis (2000), 2033-2038. Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Tris[2-(benzoylamino)ethyl]amine". Acta Cryst. (2000), C56, e602-e603. Rosa, D. T.; Krause Bauer, J.A.; Baldwin, M. J. "Structural and Spectroscopic Studies of the Versatile Coordination Chemistry of the Chiral Ligand N,N-bis(1-propan-2-onyl oxime)methionine N'-methylamide with NiII and ZnII". Inorg. Chem. (2001), 40, 1606-1613. Yanes, E.G.; Gratz, S.R.; Baldwin, M.J.; Robison, S.E.; Stalcup, A.M. "Capillary Electrophoretic Application of 1-Alkyl-3-methylimidazolium-based Ionic Liquids". Anal. Chem. (2001), 73, 3838-3844. Goldcamp, M.J.; Robison, S.E.; Krause Bauer, J.A.; Baldwin, M.J. "Oxygen Reactivity of a Ni(II)-Polyoximate Complex". Inorg. Chem. (2002), 41, 2307-2309. Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Tris(1-propan-2-only oxime)amine". Acta Cryst. (2002), E58, o1354-o1355. Goldcamp, M.J.; Robison, S.E.; Squires, L.N.; Rosa, D.T.; Vowels, N.K.; Coker, N.; Krause Bauer, J.A.; Baldwin, M.J. "Structural and Spectroscopic Studies of Ni(II) complexes with a Library of Bis(oxime)amine-Containing Ligands". Inorg. Chem. (2003), 42, 717-728. Baldwin, M.J. "A Literature-Based, One-Quarter Inorganic Chemistry laboratory Course". J. Chem. Ed. (2003), 80, 307-310. Baldwin, M.J. "Oxygen activation by nickel complexes: Development of oxygen-active Ni(II)-oximate complexes". ChemTracts – Inorganic Chemistry (2003), 16, 1-14. Jones, R.M.; Baldwin, M.J. "Development of a theoretical model of a Nickel(II) tris(oxime)amine dichloride complex with calibration by x-ray crystallography and vibrational spectroscopy". J. Phys. Chem. A. (2004), 108, 3537-3544. Edison, S.E.; Hotz, R.P.; Baldwin, M.J. "Aerobic Oxidation of Methanol by a Ni(II)-O2 Reaction". Chem. Commun. (2004), 1212-1213. Zhuang, J.; Amaroso, J.H.; Kinloch, R.; Dawson, J.H.; Baldwin, M.J.; Gibney, B.R. "Design of a five-coordinate heme protein maquette: A spectroscopic model of deoxymyoglobin". Inorg. Chem. (2004), 43, 8218-8220. Edison, S.E.; Krause Bauer, J.A.; Baldwin, M.J. "Aqua(pyridine N-oxide- ?O[tris(2-hydroxyaminopropyl) amine-?4N]nickel(II) dinitrate". Acta Cryst. (2004), E60, m1930-m1932. Krause Bauer, J.A.; Edison, S.E.; Baldwin, M.J. "Bis(ethylenediamine)nickel(II) dinitrate". Acta Cryst. (2005), E61, m82-m84. Goldcamp, M.J.; Krause-Bauer, J.A.; Baldwin, M.J. "Zn(TRISOX)(OAc)2". J. Chem. Crytallog. (2005), 35, 77-83. Deters, E.A.; Goldcamp, M.J.; Krause Bauer, J.A.; Baldwin, M.J. "Anion-controlled nuclearity in nickel complexes with potentially dinucleating, poly(oxime)amine ligands". Inorg. Chem. (2005), 44, 5222-5228. Cheruzel, L.E.; Edison, S.E.; Cecil, M.R.; Mashuta, M.S.; Baldwin, M.J.; Buchanan, R.M. "Structural and spectroscopic characterization of a copper(II) complexes of a new bis-amide functionalized imidazole tripod and evidence for the formation of a mononuclear end-on Cu-OOH species". Inorg. Chem. (2006), 45, 3191-3202. Zhuang, J.; Amoroso, J.H.; Kinloch, R.; Dawson, J.H.; Baldwin, M.J.; Gibney, B.R. "Evaluation of electron-withdrawing group effects on heme binding in a designed protein: Implications for heme a in cytachrome c oxidase". Inorg. Chem. (2006), 45, 4685-4694. Jones, R.M.; Goldcamp, M.J.; Krause, J.A.; Baldwin, M.J. "Theoretical, structural, and spectroscopic studies of a series of NiII(TRISOXH3)X2 complexes". Polyhedron (2006), 25, 3145-3158. S.E. Edison, S.D. Conklin, N. Kaval, L.E. Cheruzel, J.A. Krause, C.J. Seliskar, W.R. Heineman, R.M. Buchanan, M.J. Baldwin. "Spectroscopic characterization of a Ni-organic radical intermediate in the aerobic oxidation of methanol catalyzed by a Ni(II)(polyoximate) complex". Inorganica Chimica Acta (2008), 361, 947-955.