个人简介

PhD, University of Bonn, Germany

研究领域

Centre for Advanced Solar Materials

Synthesis and advanced characterization of phosphaorganic and organometallic pi-conjugated materials, polymers and their associated model compounds. The chemistry involved is multidisciplinary uniting organic, inorganic and polymeric objectives and techniques. This field of research is centred around modern materials science; development of novel 'smart' materials is a major goal. Our research mainly focuses on the synthesis of materials suitable for applications in organic electronics, such as Organic Light Emitting Diodes (OLEDs), Organic Field Effect Transistors (OFETs), Organic Photovoltaic Cells (OPVs) or supramolecular switches. In addition to our work on organic electronics we are also interested in low-coordinate phosphorus ligands. Phosphorus, as part of a multiple bond, exhibits relatively poor sigma-donor character but displays a much stronger pi-accepting capacity compared to ‘regular' phosphanes. Corresponding transition metal complexes exhibit unique properties that can be utilized in catalysis. Current research projects fall into one of these three main topics: Polymers and molecular materials based on phosphaorganic oligothiophenes Molecular self-assembly through coordinative bonds for the synthesis of metal-rich supramolecules and polymers Design and synthesis of novel sp2-hybridized phosphorus ligands for catalysis

近期论文

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“Synthesis and properties of electron accepting star-shaped phosphaviologen oligomers” L. Striepe, M. Vespa, T. Baumgartner* Org. Chem. Front. 2017, online. (link) (invited article for themed issue: Novel π-electron molecular scaffolds) “Cooperative-Assembly of Phosphole-Lipids and Single-Walled Carbon Nanotubes" Y. Ren, J. Gao, A. K. Hailey, T. Baumgartner, Y.-L. Loo* Chem. Mater. 2016, 28, 8407-8414. (link) “Xylene-Bridged Phosphaviologen Oligomers and Polymers as High-Performance Electrode Modifiers for Li-Ion Batteries” M. Stolar, C. Reus, T. Baumgartner* Adv. Energy Mater. 2016, 6, 1600944. (link) “Dithienophosphole-based Phosphinamides with Intriguing Self-Assembly Behavior” Z. Wang, B. S. Gelfand, T. Baumgartner* Angew. Chem. 2016, 128, 3542-3546; Angew. Chem. Int. Ed. 2016, 55, 3481-3485. (link) “Tuning the Aggregation-Induced Emission Behavior and Self-Assembly of Phosphole-Lipids” Z. Wang, B. S. Gelfand, P. Dong, S. Trudel, T. Baumgartner* J. Mater. Chem. C 2016, 4, 2936-2944. (link) (invited article for themed issue: Shape-Responsive Fluorophores) “A Structure-Property Study Toward pi-Extended Phosphole Chromophores with Ambipolar Redox Properties” Y. Ren, T. Baumgartner* Can. J. Chem. 2016, 94, 297-304. (link) (University of Calgary 50th anniversary issue) “Stimuli-Responsive Chromism in Organophosphorus Chemistry” C. Reus, T. Baumgartner* Dalton Trans. 2016, 45, 1850-1855. (link) (invited Frontier article for themed issue: Phosphorus Chemistry: Discoveries and Advances) “Structure-Property Studies of P-Triarylamine-Substituted Dithieno[3,2-b:2’,3’-d]phospholes” H. Puntscher, P. Kautny, B. Stöger, A. Tissot, C. Hametner, H. R. Hagemann, J. Fröhlich, T. Baumgartner,* D. Lumpi* RSC Adv. 2015, 5, 93797-93807. (link) “A Convenient N-Arylation Route for Electron-Deficient Pyridines: The Case of pi-Extended Electrochromic Phosphaviologens” C. Reus, M. Stolar, J. Vanderkley, J. Nebauer, T. Baumgartner* J. Am. Chem. Soc. 2015, 137, 11710-11717. (link) “Synthesis and Tunability of Highly Electron-Accepting, N-Benzylated ‘Phosphaviologens’” M. Stolar, J. Borau-Garcia, M. Toonen, T. Baumgartner* J. Am. Chem. Soc. 2015, 137, 3366-3371. (link) (Highlighted in SYNFACTS 05/2015) “P-Containing Heteroarenes: Synthesis, Properties, Applications” M. Stolar, T. Baumgartner* in: Polycyclic Arenes and Heteroarenes: Synthesis, Properties, and Applications, Wiley-VCH, 2015, 309-329. (link) (invited book chapter) “Organophosphorus Avenues Toward Self-Assembled Conjugated Soft Materials” Z. Wang, T. Baumgartner* Chem. Rec. 2015, 15, 199-217. (link) (invited personal account article for special issue on Novel Aromatics - Nozoe/ISNA) “Insights on the Design and Electron-Acceptor Properties of Conjugated Organophosphorus Materials” T. Baumgartner Acc. Chem. Res. 2014, 47, 1613-1622. (link) (invited account article) “Synthesis and Properties of Cholesteric Click-Phospholes” X.-M. He, J.-B. Lin, W. H. Kan, S. Trudel, T. Baumgartner* Org. Lett. 2014, 16, 1366-1369. (link) adfm201470039-gra-0001-m “Phosphorus-Containing Materials for Organic Electronics” M. Stolar, T. Baumgartner* Chem. Asian J. 2014, 9, 1212-1225. (link) (invited focus review & featured article) “P-Terthienyl Functionalized Dithieno[3,2-b:2’,3’-d]phospholes” C. J. Chua, Y. Ren, M. Stolar, S. Xing, T. Linder, T. Baumgartner* Eur. J. Inorg. Chem. 2014, 1767-1774. (link) (invited contribution for cluster issue on Advances in Phosphorus Chemistry) “Molecular Engineering of “Click”-Phospholes Towards Self-Assembled Luminescent Soft Materials” X.-M. He, J.-B. Lin, W. H. Kan, P. Dong, S. Trudel, T. Baumgartner* Adv. Funct. Mater. 2014, 24, 897-906. (link) (front cover page) “Synthesis and Properties of a Dicationic pi-Extended Dithieno[3,2-c:2’,3’-e]-2,7-diketophosphepin” X.-M. He, T. Baumgartner* Organometallics 2013, 32, 7625-7628. (link) “Synthesis of P-Triazole Dithienophospholes and a Cyclodextrin-based Sensor via Click Chemistry” X.-M. He, P. Zhang, J.-B. Lin, H. V. Huynh, S. E. Navarro Muñoz, C.-C. Ling, T. Baumgartner* Org. Lett. 2013, 15, 5322-5325. (link) “Phosphinine-Lipids: A Successful Marriage between Electron-Acceptor and Self-Assembly Features” X.-M. He, J.-B. Lin, W. H. Kan, T. Baumgartner* Angew. Chem. 2013, 125, 9160-9164; Angew. Chem. Int. Ed. 2013, 52, 8990-8994. (link)