个人简介
Professor, born 1947; B.S. University of Wisconsin-Eau Claire (1970); Ph.D. University of Wisconsin-Madison (1977); National Research Council Postdoctoral Fellow-NIST, Boulder, CO (1977-79); Dreyfus Award (1979); Presidential Young Investigator Award (1984); Miller Research Professor (1985-86); E.K. Plyler Prize for Molecular Spectroscopy (1989); Michelson Prize for Spectroscopy (1989); Lippincott Medal for Spectroscopy (1992); Berkeley Distinguished Teaching Award (1992); ACS Harrison Howe Award (1992); Royal Society of Chemistry Bourke Medal (1992); Churchill Fellowship, Cambridge University (1995); Humboldt Senior Scientist Award (1995); Fellow of American Academy of Arts and Sciences (1995); Fellow of APS, OSA, and Royal Society of Chemistry; Member of National Academy of Sciences (1999); Pittsburgh Spectroscopy Award (1999); ACS Irving Langmuir Prize in Chemical Physics (2000); Centenary Medal of the Royal Society of Chemistry (2001); E.O. Lawrence Award (2004); Johannes Markus Marci Medal (Czechoslovakia, 2004); Morino Lectureship (Japan, 2005); Oxford University Hinshelwood Lectureship (2006); Inaugural Solvay Chair in Chemistry (Belgium, 2008); ACS Peter DeBye Award in Physical Chemistry (2009); J.C. Bose Memorial Lecturer (Indian Association for the Cultivation of Science, Kolkata, 2011); Morris Travers Lecturer (Indian Institute of Science, Bangalore, 2011); UK Royal Society of Chemistry Faraday Lectureship Prize (2012).
研究领域
Physical Chemistry, Surface Science, Analytical Chemistry, Materials and Solid State Chemistry — New laser and synchrotron spectroscopy methods are developed for the study of chemistry in aqueous systems, properties and reactions at liquid surfaces, new forms of matter, and molecular astrophysics with an emphasis on the study of water and aqueous systems.
Active projects include terahertz laser spectroscopy of clusters, synchrotron X-ray spectroscopy of liquids and their surfaces, nonlinear chemical imaging microscopy of novel and nanostructured materials, and chemical reactions at liquid surfaces. We continue to focus on problems involving liquid water and its surface.
Physical Chemistry, Surface Science, Analytical Chemistry, Materials and Solid State Chemistry — New laser and synchrotron spectroscopy methods are developed for the study of chemistry in aqueous systems, properties and reactions at liquid surfaces, new forms of matter, and molecular astrophysics with an emphasis on the study of water and aqueous systems.
Active projects include terahertz laser spectroscopy of clusters, synchrotron X-ray spectroscopy of liquids and their surfaces, nonlinear chemical imaging microscopy of novel and nanostructured materials, and chemical reactions at liquid surfaces. We continue to focus on problems involving liquid water and its surface.
近期论文
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Saykally, R. J. "Mid-IR laser action in the H3 Rydberg molecule and some possible astrophysical implications" AIP Conf. Proc. 1642, 413 (2015); DOI: 10.1063/1.4906707
Otten, D. E., Saykally, R. J. "Spectroscopy and modeling of aqueous interfaces" in Proceedings of the International School of Physics "Enrico Fermi", Course 187 "Water: Fundamentals as the Basis for Understanding the Environment and Promoting Technology," edited by P. G. Debenedetti, M. A. Ricci, and F. Bruni (IOS Press, Amsterdam; SIF, Bologna) 2015.
Lam, R. K., England, A. H., Sheardy, A. T., Shih, O., Smith, J. W., Rizzuto, A. M., Prendergast, D., Saykally, R. J., "The hydration structure of aqueous carbonic acid from X-ray absorption spectroscopy" Chem. Phys. Lett., 614, 282-286 (2014) *Cover Article.
Smith, J. W., Lam, R. K., Sheardy, A. T., Shih, O., Rizzuto, A. M., Borodin, O., Harris, S. J., Prendergast, D., Saykally, R. J., "X-Ray absorption spectroscopy of LiBF4 in propylene carbonate: a model lithium ion battery electrolyte" Phys. Chem. Chem. Phys., 2014, 16 (23), 23496-24110 *Cover Article.
Lin, W., Steyert, D. W., Hlavacek, N. C., Mukhopadhyay, A., Page, R. H., Siegel, P. H., Saykally, R. J. "Terahertz Vibration-Rotation-Tunneling Spectroscopy of the Propane-Water Dimer: the ortho--state of a 20 cm-1 Torsion" Chem. Phys. Lett., 2014, 614, 167-171.
Saykally, R. J. "Aqua incognita: liquor aquae superficies" in AQUA INCOGNITA: Why Ice Floats on Water and Galileo 400 years on, Pierandrea Lo Nostro & Barry W Ninham (Editors), (ISBN: 9781925138214; Connor Court, Australia; 2014).
Lam, R. K., Shih, O., Smith, J. W., Sheardy, A. T., Rizzuto, A. M., Prendergast, D., Saykally, R. J. "Electrokinetic detection of X-ray spectra of weakly interacting liquids: n-decane and n-nonane" J. Chem. Phys., 2014, 140, 234202.
Shih, O., England, A.H., Dallinger, G.C., Smith, J.W., Duffey, K.C., Cohen, R.C., Prendergast, D., and Saykally, R. J. "Cation-Cation Contact Pairing in Water: Guanidinium" J. Chem. Phys., 2013, 139, 035104.
Kelly, D.N., Lam, R.K., Duffin, A., and Saykally, R. J. "Characterization of Dilute Aqueous Interfaces with Liquid Microjet Electrokinetics" J. Phys. Chem. C., 2013, 117 (24), 12702-12706.
Richardson, J.O., Wales, D.J., Althorpe, S. C., McLaughlin, Shih, O. and Saykally, R.J. "Investigation of Terahertz Vibration–Rotation Tunneling Spectra for the Water Octamer" J. Phys. Chem. A. 2013, 117 (32), 6960-6966
*Duffey, K.C., Shih, O., Wong, N.L., Drisdell, W.S., Saykally, R.J., and Cohen, R.C. "Evaporation kinetics of aqueous acetic acid droplets: effects of soluble organic aerosol components on the mechanism of water evaporation" Phys. Chem. Chem. Phys. 2013, 15 (28), 11634-11639. *Cover Article.
Saykally, R.J. "Viewpoint: Simplest Water Cluster Leaves Behind its Specral Fingerprint"Physics. 6, 22 February 2013.
Saykally, R.J. "Air/Water Interface: Two Sides of the Acid Base Story" Nature Chem. 5,82-84 January 2013.
Saykally, R.J. and D. J. Wales, "Pinning Down the Water Hexamer," Science 336, 814-815 (2012).
D.E. Otten, P. Shaffer, P. Geissler, R. J. Saykally "Elucidating the Mechanism of Selective Ion Adsorption to the Liquid Water Surface," PNAS 109 (3), 701-705 (2012).
D.E. Otten, R. Onorato, R. Michaels, J. Goodknight, R. J. Saykally "Strong Surface Adsorption of Aqueous Sodium Nitrite as an Ion Pair," Chem. Phys. Letters 519-520, 45-48 (2012).
*A. H. England, A. M. Duffin, C. P. Schwartz, J. S. Uejio, D. Prendergast, and R. J. Saykally "On the Hydration and Hydrolysis of Carbon Dioxide," Chem. Phys. Lett. 514, 187-195 (2011) *Cover Article.
*A. M. Duffin, A. H. England, C. P. Schwartz, J. S. Uejio, G. C. Dallinger, O. Shih, D. Prendergast, and R. J. Saykally "Electronic Structure of Aqueous Borohydride: A Potential Hydrogen Storage Medium" Phys. Chem. Chem. Phys., 13,17077 - 17083 (2011) *Cover Article.
A. M. Duffin, C. P. Schwartz, A. H. England, J. S. Uejio, D. Prendergast, and R. J. Saykally "pH-Dependent X-ray Absorption Spectra of Aqueous Boron Oxides," J. Chem. Phys.134, 154503 (2011).
A. E. Miller, P. B. Peterson, C. W. Hollars, R. J. Saykally, J. Hyeda and P. Jungwirth "Behavior of β-Amyloid 1 16 at the Air Water Interface at Varying pH by Nonlinear Spectroscopy and Molecular Dynamics Simulation" J. Phys. Chem. A 115, 5873-5880 (2011).
R. J. Saykally, E. A. Michael, J. Wang and Chris H. Greene Recombination-pumped Triatomic Hydrogen Infrared Lasers, J. Chem. Phys. 133, 234302 (2010).