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研究领域

inorganic chemistry organometallic synthesis homogenous catalysis pincer compounds trivalent nickel

Professor Zargarian’s research is centred on synthesis of organometallic complexes and studies of their diverse reactivities with the objective of developing new catalytic reactions.

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Berline Mougang-Soumé, Francine Belanger-Gariépy, Davit Zargarian “Synthesis, Characterization and Oxidation of New POCNimine-Type Pincer Complexes of Nickel”, Organometallics 2014, 33, ASAP. http://pubs.acs.org/doi/abs/10.1021/om500529e. Boris Vabre, Pauline Petiot, Richard Declercq, Davit Zargarian, “ Fluoro and Trifluoromethyl Derivatives of POCOP-Type Pincer Complexes of Nickel : Preparation and Reactivities in SN2 Fluorination and Direct Benzylation of Unactivated Arenes”, Organometallics 2014, 33, 5173-5184. Dean Roddick and Davit Zargarian, “Pentacoordination for Pincer and Related Terdentate Coordination Compounds: Revisiting Structural Properties and Trends for d8 Transition Metal Systems”, Inorganica Chimica Acta 2014, 422, 251-264. Invited contribution for the special issue dedicated to T. D. Tilley. Jingjun Hao, Boris Vabre, Berline Mougang-Soumé, Davit Zargarian, “Small Molecule Activation by POCsp3OP-Nickel Complexes”, Chem. Eur. J. 2014, 20, 12544-12552. Jingjun Hao, Berline Mougang-Soumé, Boris Vabre, Davit Zargarian, “On the Stability of a POCsp3OP-Type Pincer Ligand in Nickel(II) Complexes”, Angew. Chem. Int. Ed. 2014, 53, 3218-3222. DOI: 10.1002/anie.201310386. Muhammad Said, Amin Badshah, Naseer Ali Shah, Hizbullah Khan, Ghulam Murtaza, Boris Vabre, Davit Zargarian, Muhammad Rashid Khan, "Antitumor, Antioxidant and Antimicrobial Studies of Substituted Pyridylguanidines”, Molecules 2013, 18, 10378-10396, DOI: 10.3390/molecules180910378. Cécile Barthes, Christine Lepetit, Yves Canac, Carine Duhayon, Davit Zargarian, Remi Chauvin, « P(CH)P Pincer Rhodium Complexes : The Key Role of Electron-Poor Imidazoliophosphine Extremities », Inorg. Chem. 2013, 52, 48-58. http://dx.doi.org/10.1021/ic3006508 B. Vabre, F. Lindeperg, D. Zargarian, “Direct, one-pot synthesis of POCOP-type pincer complexes from metallic nickel », Green Chem. 2013, 15, 3188-3194. Cécile Barthes, Christine Lepetit, Yves Canac, Carine Duhayon, Davit Zargarian, Remi Chauvin, « P(CH)P Pincer Rhodium Complexes : The Key Role of Electron-Poor Imidazoliophosphine Extremities », Inorg. Chem. 2013, 52, 48-58. http://dx.doi.org/10.1021/ic3006508 Davit Zargarian, Annie Castonguay, Denis M. Spasyuk, “ECE-Type Pincer Complexes of Nickel”, Top. Organomet. Chem. 2013, 40, 131-174. Eds. G. van Koten and D. Milstein. DOI: 10.1007/978-3-642-31081-2_5. Springer-Verlag, Berlin Heidelberg. Invited review. Boris Vabre, Denis M. Spasyuk, Davit Zargarian, "Impact of Backbone Substituents on POCOP-Ni Pincer complexes: A Structural, Spectroscopic and Electrochemical Study”, Organometallics 2012, 31, 8561-8570. http://dx.doi.org/10.1021/om3009475. Boris Vabre, Yves Canac, Carine Duhayon, Remi Chauvin, and Davit Zargarian, Chem. Comm.2012, 48 (84), 10446 – 10448. Boris Vabre, Melinda L. Lambert, Alban Petit, Daniel H. Ess, Davit Zargarian, “On The Nickellation of PCP- and POCOP-Type Pincer Ligands: Kinetics and Mechanism”, Organometallics 2012, 31, 6041. Abderrahmen Salah, Caroline Offenstein, and Davit Zargarian, “Hydroamination and Alcoholysis of Acrylonitrile Promoted by the Pincer Complex {kP,kC,kP-2,6-(Ph2PO)2C6H3}Ni(OSO2CF3), Organometallics 2011, 30, 5352-5364. Abderrahmen Salah and Davit Zargarian, “The Impact of P-Substituents on the Structures, Spectroscopic Properties, and Reactivities of POCOP-Type Pincer Complexes of Nickel(II)”, Dalton Trans. 2011, 40, 8977- 8985. Abderrahmen Salah and Davit Zargarian, “{2,6-Bis[(diphenylphosphanyl)oxy]-phenyl-[kappa]3P,C1,P'}hydroxidonickel(II)”, Acta Cryst. 2011, E67, m940. Abderrahmen Salah and Davit Zargarian, “{2,6-Bis[(diphenylphosphanyl)oxy]-phenyl-[kappa]3P,C1,P'}iodidonickel(II)”, Acta Cryst. 2011, E67, m437. Denis M. Spasyuk, Serge I. Gorelsky, Art van der Est, and Davit Zargarian, “Characterization of Divalent and Trivalent Species Generated in the Chemical and Electrochemical Oxidation of a Dimeric Pincer Complex of Nickel”, Inorg. Chem. 2011, 50, 2661-2674. Xavier Lefèvre, Guillaume Durieux, Stéphanie Lesturgez, and Davit Zargarian, “Addition of Amines and Phenols to Acrylonitrile Derivatives Catalyzed by the POCOP-Type Pincer Complex [{kP,kC,kP-2,6-(i-Pr2PO)2C6H3}Ni(NCMe)]-[OSO2CF3]”, J. Mol. Catal. A. 2011, 335, 1-7. Editor's Choice Paper. http://www.sciencedirect.com/scidirimg/clear.gifdoi:10.1016/j.molcata.2010.11.010 Xavier Lefèvre, Denis M. Spasyuk, and Davit Zargarian, ”New POCOP-Type Pincer Complexes of Nickel(II)”, J. Organomet. Chem. 2011, J. Organomet. Chem. 2011, 696, 864-870. doi:10.1016/j.jorganchem.2010.10.019.

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