研究领域

inorganic chemistry green chemistry catalysis biodegradable polymers

Catalysis is one of the main principles of green chemistry. Professor Schaper’s group researches the synthesis and characterization of inorganic complexes that catalyze reactions important to research and industry. In particular, it is developing new catalysts for the polymerization of cyclic esters into biodegradable polymers.

近期论文

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Lactide polymerization catalyzed by Mg and Zn diketiminate complexes with flexible ligand frameworks T. J. J. Whitehorne; B. Vabre; F. Schaper Dalton Transactions 2014, 43, 6339-6352. [PDF] Lactide, beta-butyrolactone, delta-valerolactone, and epsilon-caprolactone polymerization with copper diketiminate complexes T. J. J. Whitehorne; F. Schaper Canadian Journal of Chemistry 2014, 92, 206-214. [PDF] Square-Planar Cu(II) Diketiminate Complexes in Lactide Polymerization T. J. J. Whitehorne; F. Schaper Inorg. Chem. 2013, 52, 13612-13622. [PDF] Selective and Nonselective Aza-Michael Additions Catalyzed by a Chiral Zirconium Bis-Diketiminate Complex I. El-Zoghbi; M. Kebdani; T. J. J. Whitehorne; F. Schaper Organometallics 2013, 32, 6986-6995. [PDF] Exceptionally high lactide polymerization activity of zirconium complexes with bridged diketiminate ligands I. El-Zoghbi; T. J. J. Whitehorne; F. Schaper Dalton Transactions 2013, 42, 9376-9387. [PDF] NacnacBnCuOiPr: A strained geometry resulting in very high lactide polymerization activity T. J. J. Whitehorne; F. Schaper Chem Commun. 2012, 48, 10334-10336. [PDF] Formation and reactivity of 3-diazopyridinium cations and influence on their reductive electrografting on glassy carbon J. Agullo; S. Canesi; F. Schaper; M. Morin; D. B閘anger Langmuir 2012, 28, 4889�4895. [PDF] Zinc complexes of chiral ligands obtained from methylbenzylamine M. F. Pastor; T. J. J. Whitehorne; P. O. Oguadinma; F. Schaper Inorg. Chem. Commun. 2011, 14, 1737-1741. [PDF] A bifunctional diketimine ligand for secondary building blocks: Formation of a 2D copper-zinc coordination polymer �. Rousset; T. J. J. Whitehorne; V. Baslon; C. Reber; F. Schaper Eur. J. Inorg. Chem. 2011, 331. [PDF] Red Phosphorescence in RuII Complexes of a Tridentate N-Heterocyclic Carbene Ligand Incorporating Tetrahydropyrimidine V. Friese; S. Nag; J. Fang; M.-P. Santoni; G. S. Hanan; F. Schaper Eur. J. Inorg. Chem. 2011, 39-44. [PDF] NacnacBnMgOtBu: a diketiminate-based catalyst for the polymerisation of rac-lactide with isotactic preference F. Drouin; T. J. J. Whitehorne; F. Schaper Dalton Trans. 2011, 40, 1396. [PDF] Highly symmetrical chromium(II) bisdiketiminate complexes S. Latreche; F. Schaper Inorg. Chim. Acta 2011, 365, 49-53. [PDF] Intramolecular p-Stacking in Copper(I) Diketiminate Phenanthroline complexes P. O. Oguadinma; A. Rodrigue-Witchel; C. Reber; F. Schaper Dalton Trans. 2010, 39, 8759-8768. [PDF] One-pot Synthesis of b-Diketimine Ligands I. El-Zoghbi; A. Ased; P. O. Oguadinma; E. Tchirioua; F. Schaper Can. J. Chem. 2010, 88, 1040-1045. [PDF] Lactide Polymerisation with Chiral b-Diketiminate Zinc Complexes F. Drouin; P. O. Oguadinma; T. J. J. Whitehorne; R. E. Prud'homme; F. Schaper Organometallics 2010, 29, 2139�2147. [PDF] Bis(diketiminate) chromium complexes S. Latreche; F. Schaper Organometallics 2010, 29, 2180�2185. [PDF] Synthesis and Structures of Isopropyl-?-Diketiminato Copper(I) complexes P. O. Oguadinma; F. Schaper Can. J. Chem. 2010, 88, 472-477. [PDF] Ansa-Chromocenes: An alternative route to Me2Si(C5Me4)2Cr F. Charbonneau; P. O. Oguadinma; F. Schaper Inorg. Chim. Acta 2010, 363, 1779�1784. [PDF] Zirconium Complexes of Symmetric and of Chiral Diketiminate Ligands � Synthesis, Crystal Structures and Reactivities I. El-Zoghbi; S. Latreche; F. Schaper Organometallics 2010, 29, 1551�1559. [PDF] Coordination Modes in Zirconium beta-Diketiminate Complexes I. El-Zoghbi; E. Verguet; P. O. Oguadinma; F. Schaper Inorg. Chem. Commun. 2010, 13, 529�533. [PDF]