研究领域

organic chemistry catalysis continuous flow chemistry green chemistry

Professor Collins’ group develops catalytic and asymmetric strategies for the synthesis of organic intermediates difficult to prepare using current technology, with the emphasis on syntheses applying green chemistry principles and exploiting modern technologies such as continuous-flow synthesis.

近期论文

查看导师新发文章 （温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Bédard, A.-C.; Vlassova, A.; Hernandez-Perez, A. C.; Bessette, A.; Hanan, G. S.; Heuft, M. A.; Collins, S. K. "Synthesis, Crystal Structure and Photophysical Properties of Pyrene/Helicene Hybrids." Chem. Eur. J. 2013, 19, 16295-16302. Hernandez-Perez, A. C.;; Collins, S. K. "A Visible Light Mediated Synthesis of Carbazoles." Angew. Chem., Int. Ed. 2013, 52, 12696-12700. Holtz-Mulholland, M.; Collins, S. K. "Synthesis of Chiral C1-Symmetric N-Heterocyclic Carbene Ligands: Application Toward Copper-Catalyzed Homocoupling of 2-Naphthols." Synthesis 2013, 24, 375-380. Bédard, A.-C.; Régnier, S.; Collins, S. K. "Continuous-Flow Macrocyclization at High Concentrations: Synthesis of Macrocyclic Lipids." Green Chem. 2013, 15, 1962-1966. Bédard, A.-C.; Collins, S. K. "Influence of Poly(Ethylene)Glycol Structure on Its Ability to Control Dilution Effects in Macrocyclization Reactions." ACS Catal. 2013, 3, 773-782. Holtz-Mulholland, M.; de Léséleuc, M.; Collins, S. K. "Heterocoupling of 2-Naphthols Enabled by a Copper/N-Heterocyclic Carbene Complex." Chem. Commun. 2013, 1835-1837. Bédard, A.-C.; Collins, S. K. "Exploiting Aggregation to Achieve Phase Separation in Macrocyclization." Chem. Eur. J. 2012, 19, 2108-2113. Hernandez-Perez, A.-C.; Vlassova, A.; Collins, S. K. "Toward a Visible Light Mediated Photocyclization: Cu-Based Sensitizers for the Synthesis of [5]Helicene." Org. Lett. 2012, 14, 2988-2991. Bédard, A.-C.; Collins, S. K. "Microwave Accelerated Glaser-Hay Macrocyclizations at High Concentrations." Chem. Commun. 2012, 6420-6422. LeGall, T.; Collins, S. K. "1-Mesityl-3,4-Dimethyl-4H-1,2,4-Triazol-1-ium Tetrafluoroborate." e-EROS 2012, 10.1002/047084289X.rn01422. Holz-Mulholland, M.; Collins, S. K. "3-(2,4,6-Trimethylphenyl)1-Methyl-1H-Benzo[d]Imidazol-3-ium Iodide." e-EROS 2012, 10.1002/047084289X.rn01423. Bédard, A.-C.; Collins, S. K. "Phase Separation as a Strategy Towards Controlling Dilution Effects in Macrocyclic Glaser-Hay Couplings." J. Am. Chem. Soc. 2011, 133, 19976-19981. Collins, S. K. "1,4-Dimethyl-1H-1,3,4-Triazol-4-ium Iodide." e-EROS 2011, DOI: 10.1002/047084289X.rn013(28) LeGall, T.; Baltatu, S.; Collins, S. K. "Synthesis of Mono- and Bis-N-Heterocyclic Carbene Cu(1) Complexes via Decarboxylative Generation of Carbenes." Synthesis 2011, 3687-3691. Bolduc, P.; Jacques, A.; Collins, S. K. "Efficient Macrocyclization Achieved via Conformational Control Using Intermolecular Noncovalent π-Cation/Arene Interactions." J. Am. Chem. Soc. 2010, 132, 12790-12791. Dubois, M.-A.; Grandbois, A.; Collins, S. K.; Schmitzer, A. R. "Introduction of Axial Chirality in a Planar Aromatic Ligand Results in Chiral Recognition with DNA." J. Mol. Recognit. 2010, 23, 288-294. Collins, S. K. "Enantioselective and Diastereoselective Metathesis." Science of Synthesis 2010, 819-871. Holtz-Mullholland, M.; Collins, S. K. "Ruthenium, [(4R,5R)-4,5-bis(1,1-Dimethylethyl)-1-[5-(1,1-Dimethylethyl)-4-Methoxy-2-(1-Methylethyl)phenyl]-3-Methyl-2-Imidazolidinylidene]dichloro(phenylmethylene)(tricyclohexylphosphine)]." e-EROS 2010, DOI: 10.1002/047084289X.rn01244. Stenne, B.; Timperio, J.; Savoie, J.; Dudding, T.; Collins, S. K. "Desymmetrizations Forming Tetrasubstituted Olefins Using Enantioselective Olefin Metathesis." Org. Lett. 2010, 12, 2032-2035. Grandbois, A.; Mayer, M.-E.; Bédard, M.; Collins, S. K.; Michel, T. "Synthesis of C1-Symmetric BINOLs Employing N-Heterocyclic Carbene-Copper Complexes." Chem. Eur. J. 2009, 15, 9655-9659.