研究领域

Environmental Chemistry, Theoretical & Computational Chemistry

Gas phase ion/molecule reactions Negative Ion thermochemistry Solvation thermochemistry & heats of formation by solution calorimetry including maintenance of the NIST Webbook data on gas phase negative ions. Computational chemistry, especially of negative ions Generation of negative ions by electron attachment/dissociative attachment Reaction mechanisms Instrumentation development of ICR spectrometry Development of Fast Atom Bombardment mass spectrometry, using electrochemical techniques Safety and environmental issues in chemistry, especially dealing with hazardous waste releases to the environment

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Swanson, M.B.; Davis, G.A.; Kincaid, L.E.; Schultz, T.W.; Bartmess, J.E.; Jones, S.L.; George, E.L. Environ. Tox. Chem. 1997 16, 372. "A Screening Method for Ranking and Scoring Chemicals by Potential Human Health and Environmental Impacts." Holman, R.W.; Sumpter, T.L.; Farrar, J.; Weigel, K.; Bartmess, J.E.;J. Phys. Org. Chem., 1997 10, 585. (Bordwell honor issue). "Competitive Reactivity as a Probe for Reaction Coordinates in Gas-phase Ion-Molecule Chemistry." Higgins, P.R.; Bartmess, J.E. Int. J. Mass Spectrom. Ion Proc. 1998 175, 71-79. Taft Memorial Issue, "The Gas Phase Acidities of Long Chain Alcohols." Springer, G.; Elam, C.; Edwards, A.; Bowe, C.; Boyles, D.; Bartmess, J.; Chandler, M.; West, K.; Williams, J.; Pagni, R.M.; Kabalka, G.W.; J. Org. Chem. 64 1999 2202-2210. "Chemical and Spectroscopic Studies Related to the Lewis Acidity of Lithium Perchlorate in Diethyl Ether." Bartmess, J.E.; Feigerle, C.S.; Schweizter, G.S.; Fellers, W.; Smith, P.; Chem. Eng. News. 1998 June 15, 4. "Exothermic Demo." (safety letter to editor) Bostwick, D.E.; Shealey, S.J.; Busch, K.L.; Bartmess, J.E. http://base-peak.wiley.com/news/stms.html"The Usenet Newsgroup sci.techniques.mass-spec." Bartmess, J.E.; Pittman, J.L.; Aeschleman, J.A.; Deakyne, C.A.; Int. J. Mass Spectrom. 2000 196, 215-223. "The temperature dependence of absolute gas phase acidities." Higgins, P.R., Hinde, R.J., Bloor, J.E., Grimm, D.T., Bartmess, J.E.; Int. J. Mass Spectrom. 2001 210, 231-240. "The Geometric Dependence of Acidity: Hexamethyldisilazide Anion." Bartmess, J.E. "Encyclopedia of Mass Spectrometry," Vol. 1, Ch. 5, p 315-319, 2003, Elsevier, Amsterdam, 2003. "The Bracketing Method for Determining the Thermochemistry of Ion-Molecule Reactions." Pagni, R.M., Bartmess, J.E.; Chirality, 2003 15, 772-776. Erratum Chirality, 2004 16, 137. "Photoreaction of a Racemate Proceeding Through Radical or Ion Pairs. The Effect of Circularly Polarized Light on the Enantiomeric Excess of Recovered Reactant." Bartmess, J.E., Hinde, R.J.; Can. J. Chem., 2005 83, 2005-2012 "The Gas Phase Acidities of the Elemental Hydrides are Functions of Bond Lengths and Electronegativity." Bartmess, J.E. "Encyclopedia of Mass Spectrometry," Vol. 4, Ch. 1, p 79-88: Elsevier, Amsterdam, 2005. "Gas Phase Acidities: Experiment and Theory." Robertson, W.D., Hammer, N.I., Bartmess, J.E., Compton, R.N., Diri, K., Jordan, K.D.; J. Chem. Phys., 2005, 122, 204319. "Negative Ions of Ethylene Sulfite." Pagni, R.M., Bartmess, J.E.; Chirality, 2006, 18, 419-425. "Theoretical Insights into Photochemical Reactions Initiated with Circularly Polarized Light." Bartmess, J.E. "Encyclopedia of Mass Spectrometry," Vol. 6 "Molecular Ionization," Chapter 1 "Fundamentals of Ionization," pp. 14-21: Elsevier, Amsterdam, 2007. "Proton Affinities." Bartmess, J.E. "Encyclopedia of Mass Spectrometry," Vol. 6 "Molecular Ionization," Chapter 1 "Fundamentals of Ionization," pp. 21-27: Elsevier, Amsterdam, 2007. "Gas-phase Acidities." Bartmess, J.E. "Encyclopedia of Mass Spectrometry," Vol. 6 "Molecular Ionization," Chapter 1 "Fundamentals of Ionization," pp. 27-34: Elsevier, Amsterdam, 2007. "Electron Affinities." Song, L.; Wellman, A.D.; Yao, H.; Bartmess, J.E.; J. Am. Soc. Mass Spectrom., 2007 18, 1789-1798. "Negative ion-atmospheric pressure photoionization: electron capture, dissociative electron capture, proton transfer, and anion attachment." Pagni, R.M.; Bartmess, J.E.; J. Phys. Chem. A, 2007 111, 10604-10608. "A Photochemical Mechanism for Homochirogenesis." Johnson, K.; Pagni, R.M.; Bartmess, J.E.; Monatshefte f|r Chemie, 2007 138 (11) 1077-1102. "Brxnsted Acids in Ionic Liquids: Fundamentals, Organic Reactions and Comparisons." Song, L.; Dykstra, A.B.; Yao, H.; Bartmess, J.E.; J. Am. Soc. Mass Spectrom., 2009 20, 42-50. "Ionization mechanism of negative ion-direct analysis in real time: a comparative study with negative ion-atmospheric pressure photoionization." Song, L.; Bartmess, J.E.; Rapid Commun. Mass Spectrom., 2009 23, 77-84. "Liquid Chromatography/Negative Ion Atmospheric Pressure Photoionization Mass Spectrometry: a Higly Sensitive Method for the Analysis of Organic Explosives."&**