Kavallieratos, Konstantinos - Florida International University - Department of Chemistry and Biochemistry

个人简介

B.S., University of Athens, Greece M.S., Yale University Ph.D., Yale University Postdoctoral Research Associate, Oak Ridge National Laboratory

研究领域

Inorganic Chemistry, Supramolecular chemistry, molecular recognition, and selfassembly. Application of hydrogen bonding in organometallic chemistry, ion sequestration and separation, altering chemical reactivity, designing ligand environments for metals, and mimicking biological systems. Novel materials for selective separation and sensing of environmentally and biologically important ions.

近期论文

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20. R. J. Alvarado, J. M. Rosenberg, A. Andreu, J. C. Bryan, W.-Z. Chen, T. Ren, K. Kavallieratos. Structural insights into the coordination and extraction of Pb(II) by disulfonamide ion exchangers. Inorg. Chem., 2005, in press. 19. K. Kavallieratos, A. J. Sabucedo, A. T. Pau, J. M. Rodriguez. APCI-MS characterization of anionic adducts. J. Am. Soc. Mass Spectrom. 2005, 16, 1377 . 18. K. Kavallieratos, J. M. Rosenberg, W. Chen, T. Ren, Fluorescent sensing and selective extraction of Pb(II) by a dansylamide ion-exchanger, J. Am. Chem. Soc. 2005, 127, 6514. 17. K. Kavallieratos, J. M. Rosenberg, J. C. Bryan, Pb(II) coordination and synergistic extraction by combinations of disulfonamide ion-exchangers and 2,2'-bipyridine, Inorg. Chem., 2005, 44, 2573. 16. J. C. Bryan, J. M. Rosenberg, K. Kavallieratos, 1,2-bis(phenyl)-phenylenediamine, Acta Crystallogr. E. 2005, E61, o-396. 15. K. Kavallieratos, J. C. Bryan, R. A. Sachleben, G. J. Van Berkel, , O.E. Espetia, M. A. Kelly, A. M. Danby, K. Bowman-James, B. A. Moyer Dual-Host combinations:Using Tripodal Amides to Enhance Cesium Nitrate Extraction by Crown Ethers. In Fundamentals and Applications of Anion Separations; B. A. Moyer and R. Singh, Eds.; Kluwer: New York, 2004, pp 125-150. 14. C. T. Eagle, K. Kavallieratos, J. C. BryanNon-preorganized neutral acyclic anion receptors; structural investigations of N,N'- diphenyl-1,3-benzenedisulfonamide and N,N'-bis(4-t-butylphenyl)-1,3- benzenedisulfonamide.J. Chem. Crys. 2002, 32, 165. 13. B. A. Moyer, P. V. Bonnesen, L. H. Delmau, T. J. Haverlock, K. Kavallieratos, T. G. Levitskaia, Toward recognition of the anion in the extraction of alkali metal salts by crown ethers and calixarenes. Int. Solv. Extr. Conf., 2002, 299-306. 12. K. Kavallieratos, B. A. MoyerSpectacular Cs extraction by the use of a potent dual-host combination.Chem. Commun. 2001, 1620. 11. W. Yao, K. Kavallieratos, S. R. de Gala, R. H. CrabtreeTripyrimidylamine. A new thermally robust ligand for Ruthenium.Inorg. Chim. Acta 2000, 311, 45. 10. K. Kavallieratos, A. M. Danby, G. J. Van Berkel, M. A. Kelly, R. A. Sachleben, B. A. Moyer,K. Bowman-JamesTriamide derivatives of tris(2-aminoethyl)amine (tren) as Cesium nitrate co-extractants.Anal. Chem. 2000, 72, 5258. 9. J. C. Bryan, K. Kavallieratos, R. A. SachlebenUnusual ligand coordination for Cesium.Inorg. Chem. 2000, 39, 1568. 8. K. Kavallieratos, R. A. Sachleben, G. J. Van Berkel, B. A. MoyerNovel dual-host approach in ion-pair extraction.A simple tripodal anion hostfacilitates Cesium Nitrate transfer to 1,2-dichloroethane by a large crown ether.Chem. Commun. 2000, 187. 7. A. Castellanos, J. A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao,K. Kavallieratos, R. H. CrabtreeFast H NMR relaxation from hydride-proton interactions in some Ru hydrides.Comptes Rendus Acad. Sci. (Paris) Ser. IIc1999, 2, 359. (Invited for H. Poiblanc issue). 6. P. Desmurs, K. Kavallieratos, W. Yao, R. H. CrabtreeIntermolecular Re-H...H-N and Re-H...base hydrogen bonding estimated in solution by a UV-VIS spectroscopic method.New J. Chem. 1999, 23, 1111. 5. K. Kavallieratos, C. M. Bertao, R. H. Crabtree Hydrogen bonding in anion recognition. A family of versatile, non-preorganized,neutral and acyclic receptors.J. Org. Chem. 1999, 64, 1675. 4. K. Kavallieratos, R. H. CrabtreeCatalysis of aldehyde imination by hydrogen bonding with a simple receptor.Chem. Commun. 1999, 2109. 3. K. Kavallieratos, S. Hwang, R. H. Crabtree Aminoferrocene derivatives in chloride recognition and electrochemical sensing.Inorg. Chem. 1999, 38, 5184. 2. B. P. Patel, K. Kavallieratos, R. H. Crabtree Effects of dihydrogen bonding on fluxionality in ReH5(PPh3)2L.J. Orgmet. Chem. 1997, 28, 205. 1. K. Kavallieratos, S. R. de Gala, D. J. Austin, R. H. CrabtreeA readily available non-preorganized neutral acyclic halide receptor with anunusual nonplanar binding conformation.J. Am. Chem. Soc. 1997, 119, 2325.