Farha, Omar K. - Northwestern University

个人简介

EDUCATION Ph.D. in Chemistry – UCLA, 2006 Dissertation of the Year B.S. in Chemistry – UCLA, 2002 University of California Highest Honors (Summa cum laude) Departmental Highest Honors in Chemistry A.A. in Chemistry – Fullerton College,1999 Highest Honors EXPERIENCE Charles E. and Emma H. Morrison Professorship in Chemistry 2021 – Present Department of Chemistry Northwestern University Dow Chemical Company Research Professorship in Chemistry 2020 – 2021 Department of Chemistry Northwestern University Professor of Chemical and Biological Engineering (Courtesy Appointment) 2017 – Present Department of Chemical and Biological Engineering Northwestern University Professor of Chemistry 2020 – Present Department of Chemistry Northwestern University Associate Editor, ACS Applied Materials & Interfaces 2016 – Present Associate Professor 2017 – 2020 Department of Chemistry Northwestern University Research Professor 2013 – 2017 Department of Chemistry Northwestern University Research Associate Professor 2011 – 2013 Department of Chemistry Northwestern University Research Assistant Professor 2009 – 2011 Department of Chemistry Northwestern University Postdoctoral Fellow – Research in Porous Materials 2007 – 2008 Department of Chemistry Northwestern University

研究领域

Crystal Design & MOF Synthesis Detoxification of Chemical Warfare Agents Enzyme Encapsulation Actinide-based MOFs Heterogeneous Catalysis for Energy-Related Applications Water Purification Gas Storage/Separation Chemical Separation Physical and Chemical Stability of MOFs Characterization Tools for MOFs Porous Organic Polymers Porous Clusters Composite Materials

近期论文

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Cationic Metal–Organic Framework with Amino-Functionalized Isonicotinic Acid for Chromium(VI) Removal Hou, S.; Liu, F.; Xie, H.; Sha, F.; Fahy, K. M.; Wang, X.; Zhang, C.; Chen, Y.; Li, Z.; Farha, O. K. Cryst. Growth Des. 2024, in press. https://doi.org/10.1021/acs.cgd.4c00288 An active, stable cubic molybdenum carbide catalyst for the high-temperature reverse water-gas shift reaction Khoshooei, M. A.; Wang, X.; Vitale, G.; Formalik, F.; Kirlikovali, K. O.; Snurr, R. Q.; Pereira-Almao, P.; Farha, O.. K. Science 2024, 384, 6695, 540-546 https://doi.org/10.1126/science.adl1260 Exploring the Chemical Space of Metal–Organic Frameworks with rht Topology for High Capacity Hydrogen Storage Liu, K.; Chen, Z.; Islamoglu, T.; Lee, S.; Chen, H.; Yildirim, T.; Farha, O. K.; Snurr, R. Q. J. Phys. Chem. C 2024, 128, 18, 7435–7446. https://doi.org/10.1021/acs.jpcc.4c00638 Constraining Flexibility in the MIL-88 Topology through Integration of 3-Dimensional Linkers Smoljan, C. S.; Sha, F.; Campitelli, P.; Xie, H.; Eddaoudi, M. A.; Mian, M. R.; Di Nicola, C.; Kirlikovali, K. O.; Snurr, R. Q.; Farha, O. K. Cryst. Growth Des. 2024, 24, 9, 3941–3948. https://doi.org/10.1021/acs.cgd.4c00287 Programmable Water Sorption through Linker Installation into a Zirconium Metal–Organic Framework Chen, Y.; Xie, H.; Zhong, Y.; Sha, F.; Kirlikovali, K. O.; Wang, X.; Zhang, C.; Li, Z.; Farha, O. K. J. Am. Chem. Soc. 2024,146, 16, 11202–11210. https://doi.org/10.1021/jacs.3c14699 High-Performance Porous Organic Polymers for Environmental Remediation of Toxic Gases Rabbani, M. G.; Sasse, R. K.; Behera, S.; Jena, P.; Liu, J.; Thallapally, P. K.; Islamoglu, T.; Shehab, M. K.; Kaid, M. M.; Farha, O. K.; El-Kaderi, H. M. Langmuir 2024, 40, 15, 8024–8034. https://doi.org/10.1021/acs.langmuir.3c03980 Investigation of Anionic Metal–Organic Frameworks with Extra-Framework Cations for Room Temperature Hydrogen Storage Pham, T. D.; Sengupta, D.; Farha, O. K.; Snurr, R. Q. Chem. Mater. 2024, 36, 8, 3794–3802. https://doi.org/10.1021/acs.chemmater.4c00126 Probing Structural Imperfections: Protein-Aided Defect Characterization in Metal–Organic Frameworks Sha, F.; Xie, H.; Kirlikovali,K. O.; Gong, W.; Chen, Y.; Farha, O. K. ACS Materials Lett. 2024, 6, 4, 1396–1403 https://doi.org/10.1021/acsmaterialslett.4c00199 3-dimensional linker-based metal–organic frameworks for sub-angstrom control and enhanced thermal stability Smoljan, C. S.; Snurr, R. Q.; Farha, O.K. J. Mater. Res. 2024, 39, 1047–1056. https://doi.org/10.1557/s43578-024-01309-5 Biomimetic Mineralization of Large Enzymes Utilizing a Stable Zirconium-Based Metal-Organic Frameworks Akpinar, I.; Wang, X.; Fahy, K.; Sha, F.; Yang, S.; Kwon, T.; Das, P. J.; Islamoglu, T.; Farha, O. K.; Stoddart, J. F. J. Am. Chem. Soc. 2024, 146, 8, 5108–5117. https://doi.org/10.1021/jacs.3c07785 Thermodynamic insights into phosphonate binding in metal–azolate frameworks Fahy, K. M.; Lee. S.; Akpinar, I.; Sha. F.; Ahmadi Khoshooei, M.; Su. S.; Islamoglu T.; Gianneschi, N.C.; Farha. O.K. J. Am. Chem. Soc. 2024, 146, 8, 5661–5668. https://doi.org/10.1021/jacs.3c14643 Tröger’s Base-Enriched Conjugated Cyclopentannulated Copolymers: Prominent Adsorbents of CO2, H2, and Iodine Shetty, S.; Baig, N.; Sengupta, D.; Farha, O. K.; Alameddine, B. ACS Appl. Mater. Interfaces 2024, 16, 6, 8130–8139. https://doi.org/10.1021/acsami.3c18055 A Synthetic Strategy Towards Single Crystal of Zr6 Cluster and Phosphonate-Based Metal–Organic Framework Xie, H.; Kirlikovali, K. O.; Chen, Z.; Idrees, K. B.; Islamoglu, T.; Farha, O. K. J. Mater. Chem. A 2024, 12, 6399-6404. https://doi.org/10.1039/D3TA07163D Metal–Organic Frameworks as a Tunable Platform to Deconvolute Stereoelectronic Effects on the Catalytic Activity of Thioanisole Oxidation Lee, S.; Xie, H.; Chen, Z.; Mian, M. R.; Gómez-Torres, A.; Syed, Z. H.; Reischauer, S.; Chapman, K. W.; Delferro, M.; Farha, O. K. J. Am. Chem. Soc. 2024, 146, 6, 3955–3962. https://doi.org/10.1021/jacs.3c11809 Tailoring Hydrophobicity and Pore Environment in Physisorbents for Improved Carbon Dioxide Capture under High Humidity Wang, X.; Alzayer, M.; Shih, A. J.; Bose, S.; Xie, H.; Vornholt, S. M.; Malliakas, C. D.; Alhashem, H.; Joodaki, F.; Marzouk, S.; Xiong, G.; Del Campo, M.; LeMagueres, P.; Formalik, F.; Sengupta, D.; Idrees, K. B.; Ma, K.; Chen, Y.; Kirlikovali, K. O.; Islamoglu, T.; Chapman, K.; Haile, S.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2024, 146, 6, 3943–3954. https://doi.org/10.1021/jacs.3c11671 Probing Structural Transformations and Degradation Mechanisms by Direct Observation in SIFSIX-3-Ni for Direct Air Capture Barsoum, M. L.; Hofmann, J.; Xie, H.; Chen, Z.; Vornholt, S. M.; dos Reis, R.; Burns, N.; Kycia, S.; Chapman, K. W.; Dravid, V. P.; Farha, O. K. J. Am. Chem. Soc. 2024, 146, 10, 6557–6565. https://doi.org/10.1021/jacs.3c11503 Effective Strategy toward Obtaining Reliable Breakthrough Curves of Solid Adsorbents Alhashem, H.; Sengupta, D.; Bose, S.; Wang, X.; Sha, S.; Islamoglu, T.; Farha, O. K. ACS Appl. Mater. Interfaces 2024, Just Accepted Article. https://doi.org/10.1021/acsami.3c15859 Chiral Reticular Chemistry: A Tailored Approach Crafting Highly Porous and Hydrolytically Robust Metal–Organic Frameworks for Intelligent Humidity Control Gong, W.; Chen, X.; Wahiduzzaman, M.; Xie, H.; Kirlikovali, K. O.; Dong, J.; Maurin, G.; Farha, O. K.; Cui, Y. J. Am. Chem. Soc. 2024, Just Accepted Article. https://doi.org/10.1021/jacs.3c11733 Rational Design and Reticulation of Infinite qbe Rod Secondary Building Units into Metal–Organic Frameworks through a Global Desymmetrization Approach for Inverse C3H8/C3H6 Separation Gong, W.; Xie, Y.; Yamano, A.; Ito, S.; Reinheimer, E. W.; Dong, J.; Malliakas, C. D.; Proserpio, D. M.; Cui, Y.; Farha, O. K. Angew. Chem., Int. Ed. 2023, e202318475 https://doi.org/10.1002/anie.202318475 Modulator-Dependent Dynamics Synergistically Enabled Record SO2 Uptake in Zr(IV) Metal–Organic Frameworks Based on Pyrene-Cored Molecular Quadripod Ligand Gong, W.; Xie, Y.; Yamano, A.; Ito, S.; Tang, X.; Reinheimer, E. W.; Malliakas, C. D.; Dong, J.; Cui, Y.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 49, 26890–26899 https://doi.org/10.1038/s41536-023-00331-1 Topical Application of Synthetic Melanin Promotes Tissue Repair Biyashev, D.; Siwicka, Z. E.; Onay, U. V.; Demczuk, M.; Xu, D.; Ernst, M. K.; Evans, S. T.; Nguyen, C. V.; Son, F. A.; Paul, N. K.; McCallum, N. C.; Farha, O. K.; Miller, S. D.; Gianneschi, N. C. NPJ Regen. Med., 2023, 8, 61 https://doi.org/10.1038/s41536-023-00331-1 Ortho-Alkoxy-benzamide Directed Formation of a Single Crystalline Hydrogen-bonded Crosslinked Organic Framework and Its Boron Trifluoride Uptake and Catalysis Li, F.; Li, E.; Samanta, K.; Zheng, Z.; Wu, L.; Chen, A. D.; Farha, O. K.; Staples, R.; Niu, J.; Schmidt-Rohr, K.; Ke, C. Angew. Chem., Int. Ed., 2023, e202311601 Robust Carborane-Based Metal–Organic Frameworks for Hexane Separation Idrees, K. B.; Kirlikovali, K. O.; Setter, C; Xie, H.; Brand, H.; Lal, B.; Sha, F.; Smoljan, C. S.; Wang, X.; Islamoglu, T.; Macreadie, L. K.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 23433–23441 https://doi.org/10.1021/jacs.3c04641 Humidity-Responsive Polymorphism in CALF-20: A Resilient MOF Physisorbent for CO2 Capture Chen, Z.; Ho, C.; Wang, X.; Vornholt, S. M.; Rayder, T. M.; Islamoglu, T.; Farha, O. K.; Paesani, F.; Chapman, K. W. ACS Materials Lett. 2023, 5, 2942–2947. https://doi.org/10.1021/acsmaterialslett.3c00930 Metal–Organic Frameworks for Water Vapor Adsorption Shi, L.; Kirlikovali, K. O.; Chen,Z.; Farha, O. K. Chem, 2023, 10, 1-20. https://doi.org/10.1016/j.chempr.2023.09.005 Challenges and Opportunities: Metal–Organic Frameworks for Direct Air Capture Bose, S.; Sengupta, D.; Rayder, T. M.; Wang, X.; Kirlikovali, K. O.; Sekizkardes, A. K.; Islamoglu, T.; Farha, O. K. Adv. Funct. Mater. 2023, Just Accepted Article. https://doi.org/10.1002/adfm.202307478 Expanding the Library of Ions for Moisture-Swing Carbon Capture Hegarty,J.; Shindel, B.; Sukhareva, D.; Barsoum, M. L.; Farha, O. K.; Dravid, V. Environ. Sci. Technol. 2023, Just Accepted Article. https://doi.org/10.1021/acs.est.3c02543 Balancing chemical warfare agent degradation and permeability in a zirconium-based metal-organic framework fiber composite Ma, K.; Jung, D.; Mahle, J. J.; Akpinar, I.; Peterson, G. W.; Farha, O. K. Cell Rep. Phys. Sci. 2023, 101608. https://doi.org/10.1016/j.xcrp.2023.101608 Defect-induced confinement in zirconium metal-organic frameworks for enhanced hydrogen adsorption Duncan, J.; Sengupta, D.; Bose, S.; Kirlikovali, K. O.; Farha, O. K. SCENV, 2023, 100032. doi.org/10.1016/j.scenv.2023.100032 Investigating the Mechanical Stability of Flexible Metal–Organic Frameworks Son, F. A.; Fahy, K. M.; Gaidimas, M. A.; Smoljan, C. S.; Wasson, M. C.; Farha, O. K. Commun. Chem. 2023, 6, 185 https://doi.org/10.1038/s42004-023-00981-8 Air-Stable Cu(I) Metal–Organic Framework for Hydrogen Storage Sengupta, D.; Melix, P.; Bose, S.; Duncan, J.; Wang, X.; Mian, M. R.; Kirlikovali, K. O.; Joodaki, F.; Islamoglu, T.; Yildirim, T.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 20492–20502 https://doi.org/10.1021/jacs.3c06393 Influence of Linker Identity on the Photochemistry of Uranyl-Organic Frameworks Knapp, J. G.; Livshits, M. Y.; Gilhula, J. C.; Hanna, S. L.; Piedmonte, I. D.; Rice, N. T.; Wang, X.; Stein, B. W.; Kozimor, S. A.; Farha, O. K. ACS Appl. Mater. Interfaces, 2023, 15, 43667–43677. https://doi.org/10.1021/jacs.3c06393 Mapping the Complete Reaction Energy Landscape of a Metal–Organic Framework Phase Transformation Hanna, S. L.; Barsoum, M.; Debela, T. T.; Malliakas, C. D.; Gaidimas, M. A.; Knapp, J. G.; Kirlikovali, K. O.; Hendon, C. H.; Dravid, V. P.; Farha, O. K. ACS Materials Lett. 2023, 5, 2518–2527 https://doi.org/10.1021/acsmaterialslett.3c00598 Suitability of a diamine functionalized metal–organic framework for direct air capture Bose, S.; Sengupta, D.; Malliakas, C. D.; Idrees, K. B.; Xie, H.; Wang, X.; Barsoum, M. L.; Barker, N. M.; Dravid, V. P.; Islamoglu, T.; Farha, O. K. Chem. Sci. 2023, 14, 9380-9388 https://doi.org/10.1039/D3SC02554C Mechanistic Determination of Metal–Organic Framework Degradation Under Humid Conditions Through Ex-situ STEM-PDF Barsoum, M. L.; dos Reis, R.;Farha, O. K.; Dravid, V. P. Microsc. Microanal., 2023, 29, 1786–1787, doi.org/10.1093/micmic/ozad067.924 Rationally Tailored Mesoporous Hosts for Optimal Protein Encapsulation Sha, F.; Xie, H.; Son, F. A.; Kim, K. S.; Gong, W.; Su, S.; Ma, K.; Wang, Sha, F.; Xie, H.; Son, F. A.; Kim, K. S.; Gong, W.; Su, S.; Ma, K.; Wang, X.; Wang, X.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 16383–16390 doi.org/10.1021/jacs.3c01989 Fibrous Zr-MOF Nanozyme Aerogels with Macro-Nanoporous Structure for Enhanced Catalytic Hydrolysis of Organophosphate Toxins Ma, K.; Cheung, Y. H.; Kirlikovali, K. O.; Xie, H.; Idrees, K. B.; Wang, X.; Islamoglu, T.; Xin, J. H.; Farha, O. K. Adv. Mater. 2023, 145, e2300951. doi.org/10.1002/adma.202300951 Reticular Chemistry in Its Chiral Form: Axially Chiral Zr(IV)-Spiro Metal–Organic Framework as a Case Study Gong, W.; Chen, X.; Fahy, K. M.; Dong, J.; Liu, Y.; Farha, O. K.; Cui, Y. J. Am. Chem. Soc. 2023, 145, 13869–13878. doi.org/10.1021/jacs.3c03036 Metal–Organic Frameworks with a Bioinspired Porous Polymer Coating for Sieving Separation Su, S.; Zhou, X.; Gong, X.; Idrees, K. B.; Kirlikovali, K. O.; Islamoglu, T.; Farha, O. K.; Gianneschi. N. C. J. Am. Chem. Soc. 2023, 145, 13195–13203. doi.org/10.1002/adfm.202301607 Evidence of a Uranium-Paddlewheel Node in a Catecholate-Based Metal-Organic Framework Knapp, J. G.; Wang, X.; Rosen, A. S.; Wang, X.; Gong, X.; Schneider, M.; Elkin, T.; Kirlikovali, K. O.; Fairley, M.; Krzyaniak, M. D.; Wasielewski, M. R.; Gianneschi, N. C.; Snurr, R. Q.; Farha, O. K. Angew. Chem. Int. Ed. Engl. 2023, 62, e202305526 . doi.org/10.1002/adfm.202301607 Functional Textiles with Smart Properties: Their Fabrications and Sustainable Applications Zhang, Y.; Xia, X.; Ma, K.; Xia, G.; Wu, M.; Cheung, Y. H.; Yu, H.; Zou, B.; Zhang, X.; Farha, O. K.; Xin, J. H. Adv. Func. Mater. 2023, 33, 2301607. doi.org/10.1002/adfm.202301607 Unveiling Unexpected Modulator-CO2 Dynamics within a Zirconium Metal–Organic Framework Rayder, T. M.; Formalik, F.; Vornholt, S. M.; Frank, H.; Lee, S.; Alzayer, M.; Chen, Z.; Sengupta, D.; Islamoglu, T.; Paesani, F.; Chapman, K. W.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, 11195–11205. doi.org/10.1021/jacs.3c01146 Photoreactive Carbon Dioxide Capture by a Zirconium–Nanographene Metal–Organic Framework Zheng, X.; Drummer, M. C.; He, H.; Rayder, T. M.; Niklas, J.; Weingartz, N.P.; Bolotin, I. L.; Singh, V.; Kramar, B. V.; Chen, L. X.; Hupp, J. T.; Poluektov, O. G.; Farha, O. K.; Zapol, P.; Glusac, K. D. J. Phys. Chem. Lett. 2023, 14, pp. 4334–4341. doi.org/10.1021/acs.jpclett.3c00049 Boosting the Ceramics with In Situ MOF-Derived Nanocarbons Duden, E. I.; Bayrak, K. G.; Balkan, M.; Cakan, N.; Demiroglu, A.; Ayas, E.; Caglar, M.; Turan, S.; Islamoglu, T.; Farha, O. K.; Erkartal, M.; Sen, U. ACS Materials Lett. 2023, 5, pp. 1537–1545. doi.org/10.1021/acsmaterialslett.3c00302 Expanding Linker Dimensionality in Metal-organic Frameworks for sub-Ångstrom Pore Control for Separation Applications Macreadie, L. K.; Idrees, K. B.; Smoljan, C. S.; Farha, O. K. Angew. Chem. Int. Ed. 2023, Just Accepted Article doi.org/10.1002/anie.202304094 Energy–Structure–Property Relationships in Uranium Metal–Organic Frameworks Hanna, S. L.; Farha, O. K. Chem. Sci. 2023, 14, 4219-4229 doi.org/10.1039/D3SC00788J Reticular Chemistry in Pore Engineering of a Y-Based Metal–Organic Framework for Xenon/Krypton Separation Song, X.; Huang, Q.; Liu, J.; Xie, H.; Idrees, K. B.; Hou, S.; Yu, L.; Wang, X.; Liu, F.; Qiao, Z.; Wang, H.; Chen, Y.; Li, Z.; Farha, O. K. ACS Appl. Mater. Interfaces 2023, 15, 18229–18235. doi.org/10.1021/acsami.3c01229 Engineering Metal–Organic Frameworks for Selective Separation of Hexane Isomers Using 3-Dimensional Linkers Smoljan, C. S.; Li, Z.; Xie, H.; Setter, C. J.; Idrees, K. B.; Son, F. A.; Formalik, F.; Shafaie, S.; Islamoglu, T.; Macreadie, L. K.; Snurr, R. Q.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, pp. 6434–6441. doi.org/10.1021/jacs.2c13715 Zirconium-Based Metal–Organic Frameworks as Reusable Antibacterial Peroxide Carriers for Protective Textiles Ma, K.; Cheung, Y. H,; Xie, H.; Wang, X.; Evangelopoulos, M.; Kirlikovali, K. O.; Su, S.; Wang, X.; Mirkin, C. A.; Xin, J. H.; Farha, O.K. Chem. Mater. 2023, 35, pp. 2342–2352. doi.org/10.1021/acs.chemmater.2c03288 Pore Aperture Control Toward Size-Exclusion-Based Hydrocarbon Separations Lal, B.; Idrees, K. B.; Xie, H.; Smoljan, C. S.; Shafaie, S.; Islamoglu, T.; Farha, O. K. Angew. Chem. Int. Ed. 2023, 62, e202219053. doi.org/10.1002/anie.202219053 Adsorption of a PFAS Utilizing MOF-808: Development of an Undergraduate Laboratory Experiment in a Capstone Course VanOursouw, T. M.; Rottiger, T.; Wadzinski, K. A.; VanderWaal, B. E.; Snyder, M. J.; Bittner, R. T.; Farha, O. K.; Riha, S. C.; Mondloch, J. E. J. Chem. Educ. 2023, 100, pp. 861-868. https://doi.org/10.1021/acs.jchemed.2c00910 Reticular Design of Precise Linker Installation into a Zirconium Metal–Organic Framework to Reinforce Hydrolytic Stability Chen, Y.; Idrees, K. B.; Mian, M. R.; Son, F.A.; Zhang, C.; Wang, X.; Farha, O. K. J. Am. Chem. Soc. 2023, 145, pp. 3055-3063. https://doi.org/10.1021/jacs.2c11830 Programmed Polarizability Engineering in a Cyclen-Based Cubic Zr(IV) Metal–Organic Framework to Boost Xe/Kr Separation Gong, W.; Xie, Y.; Wang, X.; Kirlikovali O.K. Idrees, K. B.; Sha, F.; Xie, H.; Liu, Y.; Chen, B.; Cui, Y.; Farha, O.K. J. Am. Chem. Soc. 2023, 145, pp. 2679-2689. https://doi.org/10.1021/jacs.2c13171 Back to the Basics: Developing Advanced Metal–Organic Frameworks Using Fundamental Chemistry Concepts Kirlikovali, K. O.; Hanna, S. L.; Son, F. A.; Farha, O. K. ACS Nanosci. Au 2023, 145, pp. 37-45. doi.org/10.1021/acsnanoscienceau.2c00046