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教育经历(Education) 1999年9月–2003年7月 安徽师范大学化学专业 理学学士 2003年9月–2008年7月 中国科学院上海有机化学研究所 有机化学专业 理学博士 工作经历(Research experience) 2008年–2009年 中国科学院上海有机化学研究所助理研究员 2009年–2011年 Montana State University (USA) 博士后 2011年–2012年 Université de Rouen et INSA de Rouen (France) 博士后 2012年至今 安徽师范大学化学与材料科学学院 讲师,副教授,教授(2017年7月起)

研究领域

不对称催化,有机合成

近期论文

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Pei-Jun Yang, Ling Qi, Zhen Liu, Gaosheng Yang, Zhuo Chai,* “Lewis Acid-Catalyzed Dynamic Kinetic Asymmetric Transformation of Racemic N-Sulfonylaziridines”, J. Am. Chem. Soc. 2018, 140, 17211–17217. Zhuo Chai, Yemei Wang, Mujun Tang, Xiaolong Mu, Jinsong Hou, Gaosheng Yang,* “Chiral rare-earth metal complexes with a tridentate amido-fluorenyl ligand: Syntheses, structures and catalytic performance”, J. Organomet. Chem. 2017,846, 236–241. Deju Hua, Pengfei Yang, Yue Shen, Gaosheng Yang,* Zhuo Chai,* “PCl5-mediated ring-openings of trans-2,3-disubstituted cyclopropane-1,1-diesters: a stereoselective way to trisubstituted vinyl cholorides”, Tetrahedron 2017, 73, 1205–1210. Zhuo Chai, Jiang Chu, Yunyi Qi, Mujun Tang, Jinsong Hou and Gaosheng Yang,* “Half-sandwich chiral rare-earth metal complexes with linked tridentate amido-indenyl ligand: synthesis, characterization, and catalytic properties for intramolecular hydroamination”, RSC Adv., 2017, 7, 1759–1765. Zhuo Chai,* Pei-Jun Yang, Hu Zhang, Shaowu Wang, Gaosheng Yang, “Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis ofN-Tosylaziridines”, Angew. Chem. Int. Ed. 2017, 56, 650–654 (highlighted in Synfacts, 2017, 396). Zhuo Chai,* Jia-Nan Chen, Zhen Liu, Xue-Fei Li, Pei-Jun Yang, Ji-Ping Hu, Gaosheng Yang, “[3+2]-Annulations of N-alkyl-3-substituted indoles with quinone monoketals catalysed by Br?nsted acids”, Org. Biomol. Chem. 2016, 14, 1024–1030. Zhuo Chai,* You-Min Zhu, Pei-Jun Yang, Shaoyin Wang, Shaowu Wang,* Zhen Liu, Gaosheng Yang, “Copper(I)-Catalyzed Kinetic Resolution of N-Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines”, J. Am. Chem. Soc. 2015, 137, 10088–10091 (highlighted by X-MOL: http://www.x-mol.com/news/5199). Gaosheng Yang,* Tingting Wang, Jun Chai, Zhuo Chai,* “AlCl3-Catalyzed [3+2] Annulations of cis-2,3-Disubstituted Cyclopropane 1,1-Diesters with Cyclic Ketones: Diastereoselective Construction of Spirotetrahydrofurans”, Eur. J. Org. Chem. 2015, 1040–1046. Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu, Gaosheng Yang,* “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination”, Chem. Commun. 2014, 50, 177–179. Zhuo Chai,* Biao Wang, Jia-Nan Chen, Gaosheng Yang, “Arylation of Azlactones using Diaryliodonium Bromides and Silver Carbonate: Facile Access to alpha-Tetrasubstituted Amino Acid Derivatives”, Adv. Synth. Catal. 2014,356, 2714–2718. Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu, Gaosheng Yang,* “Rare-earth metal complexes with tridentate linked amido-indenyl ligand: Synthesis, characterization, and catalytic properties for intramolecular hydroamination”, J. Organomet. Chem. 2014, 768, 136–139. Shaoyin Wang, Xiancui Zhu, Zhuo Chai,* and Shaowu Wang,* “Synthesis of polysubstituted pyrroles via [3+2]-annulation of aziridines and beta-nitroalkenes under aerobic conditions”, Org. Biomol. Chem. 2014, 12, 1351–1356. Yongxian Sun, Gaosheng Yang,* Zhuo Chai,* Xiaolong Mu, Jun Chai, “AlCl3-promoted [3+2] annulation of cis-2,3-disubstituted cyclopropane 1,1-diesters with isothiocyanates: stereoselective synthesis of densely substituted 2-iminodihydrothiophenes”, Org. Biomol. Chem. 2013, 11, 7859–7868. Yongxian Sun, Gaosheng Yang,* Yue Shen, Hua Zan, Zhuo Chai,* “Stereoselective cyclopropanation of a-bromochalcone with diethyl malonate promoted by K2CO3”, Tetrahedron 2013, 69, 5104–5111. Gaosheng Yang,* Yongxian Sun, Yue Shen, Zhuo Chai,* Shuangliu Zhou, Jiang Chu, Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3+2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans”, J. Org. Chem. 2013, 78, 5393–5400. Zhuo Chai, Jean-Philippe Bouillon, Dominique Cahard,* “Chiral Br?nsted Acid-Catalyzed Diastereo- and Enantioselective Synthesis of CF3-Substituted Aziridines”, Chem. Commun. 2012, 48, 9471–9473. Zhuo Chai, Trevor J. Rainey,* “Pd(II)/Br?nsted Acid Catalyzed Enantioselective Allylic C-H Activation for the Synthesis of Spirocyclic Rings”,J. Am. Chem. Soc. 2012, 134, 3615–3618. Zhuo Chai, Gang Zhao,* “Efficient Organocatalysts Derived From Simple Chiral Acyclic Amino Acids in Asymmetric Synthesis” Catal. Sci. Technol. 2012, 2, 29–41. Zhuo Chai, Hai-Feng Wang, Gang Zhao,* “Ni-Catalyzed Carbocyclization of 1,6-Enynes Mediated by Dialkylzinc Reagents: Me2Zn or Et2Zn Makes a Difference”, Synlett 2009, 1785–1790. Zhuo Chai, Zheng-Feng Xie, Xin-Yuan Liu, Ji-De Wang*, Gang Zhao*, “Tandem Addition/Cyclization Reaction of Organozinc Reagents to 2-Alkynyl Aldehydes: Highly Efficient Regio- and Enantioselective Synthesis of 1,3-Dihydroisobenzofurans and Tetrasubstituted Furans”, J. Org. Chem. 2008, 73, 2947–2950 (highlighted in Synfacts, 2008, 712).

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