Scheer, Manfred - Universität Regensburg - Institut für Anorganische Chemie

个人简介

2004 Full Professor (C4) of Chemistry at the Institute of Inorganic Chemistry at the University of Regensburg (Germany) 1996 - 2004 Associate Professor (C3) of Chemistry at the Institute of Inorganic Chemistry at the University of Karlsruhe (Germany) 1993 - 1996 Heisenberg-Fellow of the German Research Foundation (DFG) at the Institute of Inorganic Chemistry of the University of Karlsruhe 1992 - 1993 Guest professor at the Department of Chemistry, Indiana University Bloomington (USA) (Prof. Dr. M. H. Chisholm), supportet by a Feodor-Lynen-Fellowship of the Alexander von Humboldt-Foundation 1992 Habilitation at the University of Halle-Wittenberg

研究领域

Research Interest The group is active in the field of molecular chemistry, with a focus on a materials scientific utilization of the synthesized compounds. Our research is directed towards the chemistry of substituent-free main group element ligand complexes, mainly of the elements of group 15. Furthermore, nano-sized fullerene-like clusters are prepared starting from pentaphosphaferrocene and Cu(I) halides, and we are interested in their supramolecular and capsule chemistry. Such compounds are formed in template-controlled reactions as a consequence of molecular recognition.

近期论文

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B. Attenberger, E. V. Peresypkina, M. Scheer Novel two- and three-dimensional organometallic organic hybrid materials based on polyphosphorus complexes Inorg. Chem. 2015, 54, 7021-7029. B. Attenberger, M. Elsayed Moussa, T. Brietzke, V. Vreshch, H.-J. Holdt, C. Lesop*, M. Scheer*Discrete polymetallic arrangements of AgI and CuI ions based on multiple bridging phosphane ligands and π-π interactions Eur. J. Inorg. Chem. 2015, 2934-2938. C. Heindl, E. V. Peresypkina, A. V. Virovets, V. Yu. Komarov, M. Scheer 1,2,4-Triphospholyl Anions - Versatile building blocks for the formation of 1D, 2D and 3D assemblies Dalton Trans. 2015, 44, 10245 - 10252. C. Heindl, A. Kuntz, E. V. Peresypkina, A. V. Virovets, M. Zabel, D. Lüdeker, G. Brunklaus, M. Scheer Unexpected fragmentations of Triphosphaferrocene - Formation of supramolecular assemblies containing the (1,2,4-P3C2Mes2)-ligand Dalton Trans. 2015, 44, 6502-6509. B. M. Gardner, G. Balász, M. Scheer, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle Triamidoamine Uranium-Arsenic complexes containing single [U-AsH2], double [U=AsH] and triple [U≡AsK2] bonding Nat. Chem. 2015, 7, 582-590. F. Dielmann, M. Fleischmann, C. Heindl, E. V. Peresypkina, A. V. Virovets, R. M. Gschwind, M. Scheer Tunable porosities and shape of fullerene-like spheres Chem. Eur. J. 2015, 21, 6208-6214. M. Fleischmann, L. Dütsch, M. Elsayed Moussa, A. Schindler, G. Balász, C. Lescop*, M. Scheer* Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear CuI-fragments Chem. Comm. 2015, 51, 2893-2895. F. Spitzer, M. Sierka, M. Latronico, P. Mastrorilli, A. V. Virovets, M. Scheer Fixation and release of intact E4 tetrahedra (E = P, As) Angew. Chem. 2015, 127, 4467-4472.Angew. Chem. Int. Ed. 2015, 54, 4392-4396. M. Seidl, C. Kuntz, M. Bodensteiner, A. Y. Timoshkin, M. Scheer Reaction of pentelidene complexes with carbodiimides and alkyl azides - A straightforward way to four membered heterocycles Angew. Chem. 2015, 127, 2810-2814.Angew. Chem. Int. Ed. 2015, 54, 2771-2775. C. Heindl, A. Schindler, M. Bodensteiner, E. V. Peresypkina, A. V. Virovets, M. Scheer Synthesis and characterization of the novel 1,2,4-Triphosphaferrocene [Cp*Fe(η5-P3C2Mes2)] containing sterically demanding mesityl groups Phosphorus, Sulfur, Silicon and Relat. Elem. 2015, 190, 397-403. C. Graßl, M. Bodensteiner, M. Zabel, M. Scheer Synthesis of arsenic rich Asn-ligand complexes from yellow arsenic Chem. Sci. 2015, 6, 1379-1382. M. Fleischmann, J. S. Jones,F.P. Gabbai, M. Scheer A comparative study of the coordination behavior of cyclo-P5 and cyclo-As5 ligand complexes towards the trinuclear Lewis acid complex (perfluoro-ortho-phenylene)mercury Chem. Sci. 2015, 6, 132-139. M. Fleischmann, S. Welsch, L. J. Gregoriades, C. Gröger, M. Scheer Supramolecular assemblies of polyphosphorus ligands based on Tl-P and In-P interactions Z. Naturfosch B. 2014, 69B, 1348-1356. F. Dielmann, C. Heindl, F. Hastreiter, E. V. Peresypkina, A. V. Virovets, R. M. Gschwind, M. Scheer A nanosized supramolecule beyond fullerene-topology Angew. Chem. 2014, 126, 13823-13827. Angew. Chem. Int. Ed. 2014, 53, 13605-13608. S. Bauer, C. Hunger, M. Bodensteiner, A. Cros-Gagneux, W.-S. Ojo, B. Chaudret, C. Nayral, F. Delpech, M. Scheer Transition metal complexes containing parent phosphine or phosphinyl ligands and their use as precursors for phosphide nanoparticles Inorg. Chem. 2014, 53, 11438-11446. C. Schwarzmaier, A. Y. Timoshkin, G. Balàzs, M. Scheer Selective formation and unusual reactivity of tetraarsa-bicyclo[1.1.0]butane complexes Angew. Chem. 2014, 126, 9223-9227.Angew. Chem. Int. Ed. 2014, 53, 9077-9081. S. Heinl, M. Scheer Activation of group 15 based cage compounds by [CpBIGFe(CO)2] radicals Chem. Sci. 2014, 5, 3221-3225. S. Heinl, M. Scheer Low temperature of S8, Sered and α-Te with [CpBIGFe(CO)2] radicals Dalton Trans. 2014, 43, 16139-16142. E. V. Peresypkina, C.Heindl, A. Schindler, M. Bo, W. Kremer, M. Scheer Crystal structur of a giant supramolecule encapsulating o-Carborane Z. Krist. 2014,229, 735-740. C.Heindl, S. Heinl, D. Lüdeker, G. Brunklaus, W. Kremer, M. Scheer Novel polymeric agreggates of pentaphosphaferrocenes and monocationic coinage metal salts - Synthesis of [{Cp*Fe(η5‑P5)}{Cu(GaCl4)}2]n and [{CpBIGFe(η5‑P5)}Ag]n[Al(OC(CF3)3)4]n Inorg Chim. Acta 2014,422, 218-223.