个人简介

B.S. City College; Ph.D. Princeton; Postdoctoral research at MIT

研究领域

Bioinorganic chemistry; study of redox potentials in electron transfer proteins; noncovalent influence on the modulation of the redox potentials

Walters group designs nanoparticulate contrast agents for MRI image enhancement. Related research focuses on the syntheses and characterization of metal complexes that form self-assembled monolayers (SAMS) on silver for use in contrast agents and sensors.

近期论文

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Walters, M. A.; Vapnyar, V.; Bolour, A.; Incarvito, C.; Rheingold, A. L. “Iron (III) nitrilotriacetate and iron (III) iminodiacetate, their X-ray crystallographic structures and chemical properties”. Polyhedron (2003), 22/7, 941-946. Marc A. Walters, Justin Barad, Anthony Sireci, James A. Golen, and Arnold L. Rheingold “Xanthate sulfur as a hydrogen bond acceptor: the free xanthate anion and ligand sulfur in nickel tris-ethylxanthate.” Inorg. Chim. Acta (2004) 358/3, 633-640. Marc A. Walters, Pamela M. Tadross, Arnold L. Rheingold, Lev N. Zakharov, Danai Mudzudzu, John Texter “Amide-ligand hydrogen bonding in reverse micelles.” Inorg. Chem. (2005) 44, 1172-1174. Rompel, A. Cinco, R. M.; Robblee, J. H.; Latimer, M.J.; McFarlane, K.L.; Huang, J.; Walters, M.A.; Yachandra, V.K. "S, K- and L-Edge X-ray absorption spectroscopy to determine metal-ligand charge distribution in molybdenum-sulfur compounds", J. Synchrotron Rad. (2001) 8, 1006-1008 Bokacheva, L.; Kent, A. D.; Walters, M. A. "Micro-Hall magnetometry studies of thermally assisted and pure quantum tunneling in single molecule magnet Mn12-acetate", Polyhedron (2001), 20, 1717-1721. Damo, Steven M.; Lam, Kin-Chung; Rheingold, Arnold; Walters, Marc A. " Titanium Alkoxide Complexes: Condensed Phase and Gas Phase Comparisons." Inorg. Chem. (2000), 39(8), 1635-1638. Walters, M.A.; Lam, K.-C.; Damo, S.; Sommer, R.D.; Rheingold, A.L. "A neutral trizirconium cluster with chelating and exobidentate dialkoxide groups. The synthesis and crystal structure of Zr3(μ3-O)-(DMPD)4(DMPDH)2:(DMPDH2 = 2,4-dimethylpentane-1,4-diol)" Inorg. Chem. Comm. (2000) 000, 00-00. Chung, W.; Dewan, J.C.; Tuckerman, M.; Walters, M.A. "The Effect of N-H...S Hydrogen Bonding on Metal-Ligand Bond Lengths of [M(S2-o-xyl]2- Complex Anions." Inorg. Chim. Acta (1999) 291, 388-394. Bose, K.; Huang, J.; Haggerty, B. S.; Rheingold, A. L.; Salm, R. J.; Walters, M. A. "Evidence for Charge-Dipole Effects in the Rubredoxin Model Compound [(CH3)4N]2{Fe[SCH2CON(CH3)2]4}". Inorg. Chem. (1997) 36, 4596-4599 The synthesis and electrochemistry of Mo[HB(Me2pz)3] (NO) [S(CH2)2 CONH (CH2)2S] as a probe of the effects of NH...S hydrogen bonding on redox potentials, with Huang, J., R. L. Ostrander and A. L. Rheingold. Inorg. Chem. 34. 1995. 1090-1093. Hydrotris (3, 4-diphenyl-5-methylpyrazol-1-yl)borate: The control of coordination number via an equatorial substituent, with Huang, J., L. Lee, B. S. Haggerty and A. L. Rheingold. Inorg. Chem. 34. 1995. 4268-4270.