彭之皓 - 台湾清华大学

个人简介

學歷：美國賓州大學博士(Ph.D.) (2009) 國立台灣大學學士(碩士) (2001) 國立台灣大學學士(學士) (1999) 經歷： 2016國立清華大學副教授 2011 ~ 2016國立清華大學助理教授 2009 ~ 2011博士後研究：美國卡內基美濃大學專書： 1.Peng, C.-H.; Li, S.; Wayland, B. B. "Formation, Dissociation, and Radical Exchange of Organo-Cobalt Complexes in Mediating Living Radical Polymerization" ACS Symp. Ser. 2009, 1024, 115. 2.Wayland, B. B.*; Fu, X.; Peng, C.-H.; Lu, Z.; Fryd, M. "Living radical polymerizations mediated by metallo-radical and organo-transition metal complexes" ACS Symp. Ser. 2006, 944, 358.

研究领域

有機金屬催化、可控自由基聚合反應、新型有機/無機混合材料研發

近期论文

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26. Wang, F.-S.; Yang, T.-Y.; Hsu, C.-C.;Chen,Y.-J.; Li, M.-H.; Hsu, Y.-J.; Chuang, M.-C.;Peng, C.-H.*"The Mechanism and Thermodynamic Studies of CMRP: Different Control Mechanisms Demonstrated by CoII(TMP), CoII(salen*), and CoII(acac)2 Mediated Polymerization and The Correlation of Reduction Potential, Equilibrium Constant, and Control Mechanism" Macromol. Chem. Phys.2015, DOI: 10.1002/macp.201500311. (Invited paper for special issue of Young Talents in Polymer Science) 25. Chen,Y.-J.; Wu, B.-J.; Wang, F.-S.; Chi, M.-H.; Chen, J.-T.*;Peng, C.-H.*"Hybridization of CMRP and ATRP: A Direct Living Chain Extension from Poly(vinyl acetate) to Poly(methyl methacrylate) and Polystyrene"Macromolecules 2015,48(19), 6832. 24. 謝宜良，王富生，彭之皓* "有機鈷金屬錯合物在高分子合成上的應用" 化學2015, 73, 119. 23. Zhao,Y.;Yu, M.; Zhang, S.;Wu, Z.;Liu, Y.;Peng, C.-H.*; Fu, X.* "A Well-defined Versatile Photoinitiator (salen)Co-CO2CH3 for Visible Light Initiated Living/Controlled Radical Polymerization"Chemical Science, 2015, 6, 2979. 22. Hsieh, Y.-L.; Huang, N.; Lee, G.-H.; Peng, C.-H.* "Bipyridine-Phenolate Based Aluminum Complexes Mediated Ring-Opening Polymerization of ε-Caprolactone and Lactides with A High Stereoselectivity" Polymer2015,72, 281. 21. Hsieh, Y.-L.; Lin, Y.-C.; Lee, G.-H.; Peng, C.-H.* "Zinc Complexes Coordinated by Bipyridine-Phenolate Ligands as An Efficient Initiator for Ring-Opening Polymerization of Cyclic Esters" Polymer2015,56, 237. 20. Lin, Y.-C.; Hsieh, Y.-L.; Lin, Y.-D.; Peng, C.-H.* "Cobalt Bipyridine Bisphenolate Complex in Controlled/Living Radical Polymerization of Vinyl Monomers" Macromolecules2014,47(21), 7362. 19. Peng, C.-H.*; Yang, T.-Y.; Zhao, Y.; Fu, X.*"Reversible deactivation radical polymerization mediated by cobalt complexes: recent progress and perspectives" Org. Biomol. Chem. 2014, 12, 8580. 18. Hsu, C.-S.; Yang, T.-Y.; Peng, C.-H.*"Vinyl acetate living radical polymerization mediated by cobalt porphyrins: kinetic–mechanistic studies"Polym. Chem. 2014, 5 (12), 3867. 17. Hsiao, C.-Y.; Han, H.-A.; Lee, G.-H.; Peng, C.-H.*"AGET and SARA ATRP of styrene and methyl methacrylate mediated by pyridyl-imine based copper complexes"Eur. Polym. J.2014,51, 12. 16. Liao, C.-M.; Hsu, C.-C.; Wang, F.-S.; Wayland, B. B.; Peng, C.-H.* "Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes" Polym. Chem. 2013, 4, 3098. 15. 王富生，彭之皓* "新穎高分子合成方法: 原子轉移自由基聚合" 科儀新知2013,34, 42. 14. Chi, M.-H.; Chang, C.-W.; Ko, H.-W.; Su, C.-H.; Lee, C.-W.; Peng, C.-H.; Chen, J.-T.* "Solvent-Induced Dewetting on Curved Substrates: Fabrication ofPorous Polymer Nanotubes by Anodic Aluminum Oxide Templates" Macromolecules2015,48(17), 6241. 13. Zhao, Y.; Zhang, S.; Wu, Z.; Liu, X.; Zhao, X.; Peng, C.-H.; Fu, X.* "Visible-Light-Induced Living Radical Polymerization (LRP) Mediated by (salen)Co(II)/TPO at Ambient Temperature" Macromolecules2015,48(15), 5132. 12. Ko,H.-W.; Chi, M.-H.; Chang, C.-W.; Su, C.-H.; Wei, T.-H.; Tsai, C.-C.; Peng, C.-H.; Chen, J.-T.* "Fabrication of Multicomponent PolymerNanostructures Containing PMMA Shells andEncapsulated PS Nanospheres in the Nanoporesof Anodic Aluminum Oxide Templates" Macromol. Rapid Commun.,2015,36, 439. 11. Wang, Y.; Zhong, M.; Zhu, W.; Peng, C.-H.; Zhang, Y.; Konkolewicz, D.; Bortolamei, N.; Isse, A. A.; Gennaro, A.; Matyjaszewski, K.* "Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. Comproportionation–Disproportionation Equilibria and Kinetics" Macromolecules ,2013, 46,3793. 10. Peng, C.-H.; Zhong, M.; Wang, Y.; Kwak, Y.; Zhang, Y.; Zhu, W.; Tonge, M.; Buback, J.; Park, S.; Krys, P.; Konkolewicz, D.; Gennaro, A.; Matyjaszewski, K.* "Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. Activation of Alkyl Halides by Cu(0)" Macromolecules, 2013, 46, 3803. 9. Zhang, Y.; Wang, Y.; Peng, C.-H.; Zhong, M.; Zhu, W.; Konkolewicz, D.; Matyjaszewski, K.*"Copper-Mediated CRP of Methyl Acrylate in the Presence of MetallicCopper: Effect of Ligand Structure on Reaction Kinetics"Macromolecules,2012,45, 78. 8. Peng, C.-H.; Kong, J.; Seeliger, F.; Matyjaszewski, K. "Mechanism of Halogen Exchange in ATRP"Macromolecules 2011,44, 7546-7557. 7. Peng, C.-H.; Li, S.;Wayland, B. B."Formation and Interconversion of Organo-Cobalt Complexes in Reactionsof Cobalt(II) Porphyrins with Cyanoalkyl Radicals and Vinyl Olefins"Inorganic Chemistry,2009,48, 5039-5046. 6. Peng, C.-H.; Li, S.;Wayland, B. B."Aspects of Living Radical Polymerization Mediated by Cobalt Porphyrin Complexes"Journal of the Chinese Chemical Society (Taipei),2009,56(2), 219-233. 5. Li, S.; de Bruin, B.;Peng, C.-H.; Fryd, M.;Wayland, B. B.*"Exchange of Organic Radicals with Organo-Cobalt Complexes Formed in the Living Radical Polymerization of Vinyl Acetate" Journal of the American Chemical Society,2008,130, 13373-13381. 4. Peng, C.-H.; Scricco, J.; Li, S.; Fryd, M.; Wayland, B. B.* "Organo-Cobalt Mediated Living Radical Polymerization of Vinyl Acetate" Macromolecules, 2008, 41, 2368-2373. 3. Peng, C.-H.; Fryd, M.; Wayland, B. B.* "Organocobalt Mediated Radical Polymerization of Acrylic Acid in Water" Macromolecules 2007,40, 6814-6819. 2. Wayland, B. B.*; Peng, C.-H.; Fu, X.; Lu, Z.; Fryd, M. "Degenerative Transfer and Reversible Termination Mechanisms for Living Radical Polymerizations Mediated by Cobalt Porphyrins" Macromolecules 2006,39, 8219-8222. 1. Peng, C.-H.;Wang, C. -C.; Lee, H. -C.; Lo, W. -C.; Lee, G. -H.; Peng, S. -M.* " Two Polymeric Linear Tri-nickel(II) Complexes: [Ni3(m3-dpa)4(C4O4Me)]n(BF4)n and [Ni3(m3-dpa)4(N3)]n(PF6)n Synthesis, Structural Characterization and Magnetic Properties " Journal of the Chinese Chemical Society,2001, 48, 987-996. 會議論文： 1.Peng, C.-H.; Zhong, M.; Wang, Y.; Zhang, Y.; Konkolewicz, D.; Magenau, A. J. D.; Matyjaszewski, K. "Supplemental Activator and Reducing Agent: The True Role of Copper(0) in ATRP" Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2011, 52(2), 586-587. 2.Peng, C.-H.; Li, S.; Wayland, B. B. "Formation, Dissociation, and Radical Exchange of Organo-Cobalt Complexes in Mediating Living Radical Polymerization of Vinyl Monomers" Polym. Prepr. (IUPAC MACRO 2008) 2008. 3.Wayland, B. B.; Li, S.; Peng, C.-H.; Fryd, M. "Formation, Dissociation, and Radical Exchange of Organo-Cobalt Complexes in Mediating Living Radical Polymerization of Vinyl Monomers" Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2008, 49(2), 123-124. 4.Peng, C.-H.; Wayland, B. B.* "Cobalt porphyrin mediated living radical polymerization of acrylic acid in water" Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2007, 48, 254. 5.Peng, C.-H.; Scricco, J.; Fu, X.; Fryd, M.; Wayland, B. B.* "Living radical polymerization of acrylic acid and vinyl acetate mediated by organo-cobalt porphyrin complexes" Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2006, 47, 543.