个人简介
學歷：
美國伊利諾大學香濱分校博士 (1994)
國立清華大學碩士 (1988)
國立清華大學學士 (1986)
經歷：
國立清華大學教授 (2010~)
國立師範大學教授 (2000~2010)
國立師範大學副教授 (1995~2000)
博士後研究：美國史格寶研究院 (1994~1995)
榮譽得獎：
Asian Core Organic Chemistry Program, lectureship award to China
Asian Core Organic Chemistry Program, lectureship award to HK
國立清華大學104年度產學合作績優獎
Asian Core Organic Chemistry Program, lectureship award to China
Asian Core Organic Chemistry Program, lectureship award to Japan
Award for “Asian and Ocenanian Young Photochemists”
Asian Core Organic Chemistry Program, lectureship award to Japan
Outstanding Scholar Award of 2010 from “Foundation for the Advancement of Outstanding Scholarship"(傑出人才基金會 99 年度第一期傑出人才講座)
重要研究成果：
首次從定制的手性N-亞水楊基 - 釩（V）配合物中定向組裝鬆散的，Na +結合的，氧化釩酸鹽為中心的C4對稱四重體，可以進行高效的Ba2 +或Hg2 +特異性檢測（通過51V NMR 和VCD），運輸（分別形成獨特的螺旋膠囊或帶帽的方形平面複合物），從含有4 種不同鹼土離子或至少10 種相似大小和電荷的不同金屬離子的水相中回收綠色能夠進入CHCl3層而不受氧化或親氧離子如Mg2 +，Ca2 +，Cu2 +，Cd2 +和Pb2 +的干擾﹝Inorg. Chem. 2018, 57, 11511−11523﹞。
報告螺旋配置（順式 - 二苯乙烯）三聚體及其旋塗OLED 器件性能的時間分辨光物理研究。通過脈衝輻射分析研究了螺旋構型的三（順式 - 二苯乙烯）的瞬態吸收曲線。在苯中的初始自由基離子的電荷再結合之後的發射分佈提供了對OLED 器件中的發射機制和效率的見解。通過溶液工藝，用於最大外量子效率（EQE）的藍色，天藍色和綠色發光OLED 器件分別為4.32％，4.70％和2.77％﹝ACS Appl. Mater. Interfaces 2018, 10, 25561−25569﹞。
由含有4-氨基吡啶單元的手性可轉換螺旋烯催化的 氧-羧基吖內酯的鏡像互補Steglich重排:我們研究以假對映體的親核性催化劑做為鏡像互補催化，尤其是在光觸發反應上，很少被深入探討。由含有4-氮-甲基氨基吡啶（MAP）下盤催化單元和C 2對稱（10R,11R）-二甲氧甲基-二汴環庚烷上盤模板組成可光學切換之假對映體螺旋烯。它們在290 nm（P / M’，<1/>99）和340nm（P / M’，91/9）可有效進行互補光學切換，並利用來催化鏡像互補的Steglich的氧-至碳-醯化吖內酯重排反應，分別形成任一對映體的高達90％ee的（R）和94％ee的（S）。據我們所知，本系統是構成多個光或熱控鏡像互補反應中最好互補鏡像控制的系統之一。研究成果已刊登在2017年1月Chem. Sci.2017, 8, 524上﹝SCI IF=9.144﹞。
溶液塗佈可行的深紅色磷光發光體:我們合成出以喹喔啉融環順二苯乙烯-茀烯螺旋接合體為配體的銥錯合物，作為深紅色磷光客體材料Ir(SQ)2(acac)，並在濕式製程中找到良好的主客體元件結構搭配，元件結構為 ITO/PEODT : PSS (35 nm)/NPB : 10% Bebq2 : 5 wt% Ir(SQ)2(acac) (15 nm)/TPBI (40 nm)/LiF (1 nm)/Al (100 nm) 時，得到最大外部量子效率高達 11.2 %，CIE(x, y)座標位於 (0.70, 0.27)，是一高效率的飽和度達108%之深紅光色磷光元件。研究成果已刊登在2016年7月J. Physical Chem. C上﹝SCI IF=4.509﹞。
以假性鏡像螺旋烯的互補式螺旋掌性切換達成具右旋膠體-溶液-左旋膠體三元互換邏輯: 我們合成以C2對稱(10R,11R)雙甲氧甲基取代之掌性二芐環庚烷為上盤骨架，並且在並在兩側引入沒食子醯胺和下盤C-8引入苯基的螺旋烯左旋化合物，其在二氯甲烷經由分子間氫鍵、p-p作用自組裝成螺旋纖維，以波長290 nm的光照射此二氯甲烷膠體溶液，可以完全切換為右旋螺旋纖維膠體溶液，當以波長350 nm進行光異構化反應，也能夠回復至右旋(P/M’ = 90/10)膠體溶液；而當以波長318 nm進行光異構化反應，可得近1/1之組成，而轉為假消旋溶液態。我們首創功能化手性螺旋烯，藉由分子間氫鍵、p-p作用自組裝，所構築的螺旋纖維巨結構可做為螺旋體可逆式的光學切換，在膠態作三元邏輯的記憶裝置，其內的螺旋通道更可作為手性辨識的用途。開創新型微奈米記憶有機材料，同時增加讀寫密度。初步成果已發於表在2013年美國化學學會會誌（1篇，SCI IF=13.038）。
重要會議邀請演講：
1.2018, Dec. 10-15; “Vanadyl Species-Catalyzed 1,2-Oxidative Trifluoromethylation of Unactivated Olefins”; Invited talk atCatalysis and Fine Chemicals-2018; Bangkok, Tailand.
2.2018, Sept. 27-30; Chairman in Chief in the 10thAsian-European Symposium; Hsinchu, Taiwan.
3.2018, June 24-27; “New Dimensions of Vanadyl Species in Ion Specific Sensing and Synergistic Asymmetric Catalysis”; Invited talk aat the 13th International Symposium on Activation of Dioxygen and Homogeneous Oxidation Catalysis (ADHOC).
4.2018, June 22-25; “Vanadyl Species-Catalyzed Asymmetric Synthesis and Self-assembly””; Invited talk at OM&Cat-2018; Taipei, Taiwan
5.2018, March 13-14; “New Dimensions of Vanadyl Species in Ion Specific Sensing and Synergistic Asymmetric Catalysis”; Invited talk at BIOTECHNOLOGY AND CHEMISTRY FOR GREEN GROWTH; Awaji Island, Japan.
6.2017, Nov. 25-29: “Chiral Trisoxazoline-Derived Oxidovanadium Complexes in Asymmetric Reduction of Cyclic N-Sulfonyl Ketimines”; Invited talk at “International Conference on Cutting-edge Organic Chemistry in Asia-8; ICCEOA-12”; Xian, China
7.2016, Dec. 8-10; Keynote Speechat The 14th International Symposium for Chinese Organic Chemists (ISCOC ;“Chiral vanadyl species-mediated catalysis in asymmetric reduction of -and -keto amide’; NUS, Singapore.
8.2016, Sept. 4-7; Invited talk at9th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis; “New Dimension of Chiral Vanadyl Species-Mediated Catalysis’; Stockholm University, Sweden.
9.2016, April 22-24; Invited talk at International Symposium on Organic Reaction; “Optically Switchable Helical DMAPs in Asymmetric Catalysis of Medicinal Interests”; Kyoto, Japan.
10.2016, April 20-22; Invited talk at “Molecular Chirality in Asia”; “New Dimensions of Vanadyl Species in Ion Specific Sensing and Asymmetric Amplified Transcription”; Osaka, Japan.
11.2016, Feb. 29-march 1st, Invited talk at “The first symposium on molecular chirality research; “New Dimensions of Vanadyl Species in Ion Specific Sensing and Asymmetric Amplified Transcription”; Chiba University, Japan.
12.2015, Oct. 18-21; Invited talk at “International Medicinal Chemistry Symposium in 2015”; Jeju, Korea.
13.2015, Sept. 6-9; Invited talk at “KJF International Conference 2015 on Organic Materials for Electronics and Photonics (KJF-ICOMEP 2015)”; Jeju, Korea.
14.2014, Dec. 19-22: Plenary lecture at “The 13th International Symposium for Chinese Organic Chemists (ISCOC-13)”; Xiamen, China
15.2014, Sept. 7th-10th: Invited Lecture at “The 8th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis”; Izmir, Turkey.
近期论文
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1.Chien-Tien Chen; 2019; “Spirally configured cis-Stilbene/Fluorene Hybrid Materials for OLED and OPV Applications”; Chem. Commun.2019, 55, an invited feature article (SCI IF 6.29, top 16%)
2.Shiang-Fu Hung, Yi Wei, Fang-Yuan Tsai, Chien-Tien Chen,* Takumi Kimura, Shingo Samori, Mamoru Fujitsuka, TetsuroMajima,* Chun-Hao Lin, Shiang-Hau Peng, and Jwo-HueiJou* ; 2018; “Spirally Configured (cis-Stilbene) Trimers: Steady state and Time-resolved Photophysical Studies and OLED Applications”; ACS Applied Materials & Interfaces2018, 10, 25561−25569. (SCI IF 8.10, top 9%)
3.Chien-Tien Chen,*Yi-Ya Liao,Santosh B. Salunke,Ya-Hui Lin,and Ting-Shen Kuo; 2018; “Directed Self-Assembly of C4-Symmetric,Oxidovanadate-Centered,Vanadyl(V) Quadruplexes for Ba2+- and Hg2+-Specific Recognition, Transport, and Recovery”; Inorg. Chem.2018, 57, 11511−11523 (SCI IF 4.70, top 11%)
4.Chien-Tien Chen,*Fang-Yuan Tsai,Chun-Ying Chiang,and Chih-Ping Chen*; “Spiro-Shaped cis-Stilbene/Fluorene Hybrid Template for the Fabrication of Small-Molecule Bulk Heterojunction Solar Cells”; J. Phys. Chem. C 2017, 121, 15943−15948. (SCI IF 4.536)
5.Chien-Tien Chen,* Cheng-Che Tsai, Pei-Kang Tsou, Gou-Tao Huangand Chin-HuiYu*; “EnantiodivergentSteglich rearrangement of O-carboxylazlactones catalyzed by a chirality switchable helicene containing a 4-aminopyridine unit”; Chem. Sci.2017, 8, 524-529. (SCI IF 9.063; Chem. Multi.; 14/163)
6.Jwo-HueiJou,*Yu-Ting Su,† Ming-Ting Hsiao,Hui-Huan Yu,Zhe-Kai He, Shen-Chin Fu,Chi-Heng Chiang,Chien-Tien Chen,*Chia-hung Chou,and Jing-Jong Shyue; “Solution-Process-Feasible Deep-Red Phosphorescent Emitter”; J. Phys. Chem. C2016, 18794. (SCI IF 4.536; Chem. Physical; 30/144)
7.Jwo-HueiJou*et al, Chien-Tien Chen* et al; 2015; “Enabling a bright orange-red emission with a high EQE with a seven-member-ring based fluorescent emitter with a matching host”; Org. Electronics2015, 26, 285-291. (SCI IF 3.680; No. cited 0; 39/260; Mat. MD)
8.Shiue-Shien Weng,* Wen-Chieh Yang, Anandhan Ramasamy, Gobi Rajeshwaren, Yi-Ya Liao, Chien-Tien Chen*; 2015; “Vanadyl Species-Catalyzed, Complementary-OxidativeCarbonylation of Styrene Derivatives with Aldehydes“; Org. Biomol. Chem.2015, 13, 2385-2392. (SCI IF 3.423; No. Cited 1; 12/58, Org.Chem.)
9.Jwo-HueiJou*et al, Jing-Jong Shyue*, Shih-Sheng Sun, Chien-Tien Chen et al; 2014; “Highly Efficient Yellow Organic Light Emitting Diode with aNovel Wet- and Dry-Process Feasible Iridium Complex Emitter’; Adv. Funct. Mater. 2014, 24, 555. (IF 13.325, top 5%; cited 22; 12/260; Mat. Sci. MD)
10.Jwo-HueiJou*, Chien-Tien Chen* et al; 2014; “Artificial Dusk-Light Based on Organic Light Emitting Diode”; ACS Photonics2014, 1, 27-31. (SCI IF 5.404; times cited 9; Mat. MD)
11.Chien-Tien Chen,* Wei-Shan Chao, Hao-Wei Liu, Yi Wei,a Jwo-Huei Jou* and Sudhir Kumarc (2013, May). Spirally configured cis-stilbene/fluorene hybrids as ambipolar, fluorescent materials for organic light emitting diode applications. RSC Advances, 3, 23, 9381-9390.. (SCI, new RSC journals). NSC 101-2627-M-007-007. 本人為第一作者、通訊作者.
12.Chien-Tien Chen*,Chien-Hsiang Chen, Tiow-Gan Ong; 2013; “Complementary HelicityInterchange of Optically Switchable Supramolecular-Enantiomeric Helicenes with (-)-Gel-Sol-(+)-Gel Transition Ternary Logic”; J. Am. Chem. Soc.135, 5294.(SCI IF 13.038, top 5%; No. cited 22; 10/157, Chem. Multidisp.)
13.Hui-Ping Wu, Zih-Wei Ou, Tsung-Yu Pan, Chi-Ming Lan, Wei-Kai Huang, Hsuan-Wei Lee, N. Masi Reddy, Chien-Tien Chen*, Wei-Shan Chao, Chen-Yu Yeh* and Eric Wei-Guang Diau* (2012, Dec). Molecular engineering of cocktail co-sensitization for efficient panchromatic porphyrin-sensitized solar cells. Energy & Environmental Science, 5(12), 9843-9848. (SCI, 3/81, Energy & Fuels). NSC 101-2627-M-007-007. 本人為通訊作者.
14.Jwo-Huei Jou*, Ming-Chun Tang, Pin-Chu Chen, Yi-Shan Wang, Shih-Ming Shen, Bo-Ru Chen, Chun-Hao Lin, Wei-Ben Wang, Szu-Hao Chen, Chien-Tien Chen*, Fang-Yuan Tsai, Ching-Wu Wang, Chien-Chih Chen, Ching-Chiun Wang (2012, Aug). Organic light-emitting diode-based plausibly physiologically- friendly low color-temperature night light. Organic Electronics: physics, materials, applications, 13(8), 1349-1355. (SCI, 31/232, Materials Multidisciplinary). NSC 101-2627-M-007-007.本人為通訊作者.
15.Jwo-Huei Jou*, Yu-Lin Chen, Jing-Ru Tseng, Ri-Zong Wu, Jing-Jong Shyue, K. R. Justin Thomas*, Neha Kapoor, Chien-Tien Chen*, Yi-Ping Lin, Po-Hung Wang, Hsiao-Wen Hung, Jung-Yu Li and Shih-Pu Chen (2012, Aug). The use of a polarity matching and high-energy exciton generating host in fabricating efficient purplish-blue OLEDs from a sky-blue emitter. JOURNAL OF MATERIALS CHEMISTRY, 22(31), 15500-15506. (SCIE, 17/232, Materials, Multidisciplinary). NSC 101-2627-M-007-007. 本人為通訊作者.
16.Wei-Shan Chao, Chien-Tien Chen*, Wei-Kai Huang, Chi-Ming Lan, Eric Wei- Guang Diau* (2012, May). Spirally Configured cis-Stilbene/Fluorene Hybrids as Bipolar, Organic Sensitizers for Solar Cell Applications. CHEMICAL COMMUNICATIONS, 48期, P.4884-P4886. (SCI, 19/154, Chemistry, Multidisciplinary). NSC 100-2627-M-007-010. 本人為通訊作者.
17.Chi-Ming Lan, Hui-Ping Wu, Tsung-Yu Pan, Chia-Wei Chang, Wei-Shan Chao, Chien-Tien Chen*, Chin-Li Wang, Ching-Yao Lin,* and Eric Wei-Guang Diau* (2012, Apr). Enhanced Photo- voltaic Performance with Co-sensitization of Porphyrin and an Organic Dye in Dye-sensitized Solar Cells. Energy & Environmental Science, 5(4), 6460-6464. (SCI, 3/81, Energy & Fuels). NSC 101-2627-M-007-007. 本人為通訊作者.
18.Jwo-Huei Jou*, Pin-Chu Chen, Ming-Chun Tang, Yi-Shan Wang, Chun-Hao Lin,a Szu-Hao Chen, Chien-Chih Chen, Ching-Chiun Wang, and Chien-Tien Chen* (2012, Mar). Organic light-emitting diodes with roll-up character. Journal of Photonics for Energy, 2(1), 021208. (SCIE, e-journal). NSC 101-2627-M-007-007. 本人為通訊作者.
19.Jiunn-Min Shieh, Tzu-Tang Wei, Yen-An Tang, Sin-Ming Huang, Wei-Ling Wen, Mei-Yu Chen, Hung-Chi Cheng, Santosh B. Salunke, Ching-Shih Chen, Pinpin Lin, Chien-Tien Chen*, and Yi-Ching Wang* (2012, Jan). Mitochondrial apoptosis and FAK signaling disruption by a novel histone deacetylase inhibitor, HTPB, in antitumor and antimetastatic mouse models. PLoS One, 7(1), e30240, P.1-P.11.(SCI, 18/155, Medical Science). NSC 99-2627-M-003-001. 本人為通訊作者.
20.Jwo-Huei Jou*, Yi-Shan Wang, Chun-Hao Lin, Shih-Ming Shen, Pin-Chu Chen, Ming-Chun Tang, Yi Wei, Fang-Yuan Tsai and Chien-Tien Chen* (2011, Sep). Nearly non-roll-off high efficiency fluorescent yellow organic light-emitting diodes. JOURNAL OF MATERIALS CHEMISTRY, 21(34)期, P.12613-. (SCI, 17/232, Materials, Multidisciplinary). NSC 100-3113-E-007-002. 本人為通訊作者.
21.Santosh B. Salunke, N. Seshu Babu, and Chien-Tien Chen* (2011, Aug). Iron(III) Chloride as anEfficient Catalyst for Stereoselective Synthesis of Glycosyl Azides and a Cocatalyst with Cu(0) for the Subsequent Click Chemistry. Chem. Commun., 47(37), p. 10440-10442. (SCI, 19/154, Chemistry, Multidisciplinary). NSC 97-2627-M-003-001. 本人為通訊作者.
22.Santosh B. Salunke, N.Seshu Babu, and Chien-Tien Chen* (2011, Apr). Asymmetric Aerobic Oxidation of alpha-Hydroxy Acid Derivatives Catalyzed by Reusable, Polystyrene Supported Chiral N-salicylidine oxidovanadium(V) t- Leucinates. Advanced Synthesis & Catalysis, 353期, p. 1234-1240. (SCI, 2/71, Chemistry, Applied). NSC 99-2627-M-003-001. 本人為通訊作者.
23.Chien-Tien Chen*, Jun-Qi Kao, Cheng-Yuan Liu and Ling-Yu Jiang (2011, Mar).Oxidative, photo-activated TiO2 nanoparticles in the catalytic acetylation of primary alcohols. Catal. Sci. Technol., 1期, P. 54-P.57. (SCI). NSC 97-2627-M-003-001. 本人為第一作者、通訊作者.
24.Cheng-Yuan Liu, Hui-Ling Chen, Chih-Min Ko, and Chien-Tien Chen* (2011, Feb). Chemoselective Deacylation of Functionalized Esters Catalyzed by Dioxomolybdenum Dichloride. Tetrahedron, 67(5), P. 872-P. 876. (SCI, 16/56, Chemistry, Organoc). NSC 97-2627-M-003-001. 本人為第一作者、通訊作者.
25.Chien-Tien Chen*, Jun-Qi Kao, Santosh B. Salunke, and Ya-Hui Lin (2011, Jan).Catalytic, Enantioselective Aerobic Oxidation and Kinetic Resolution of alpha- Hydroxy-Ketones by Oxidovanadium(V) Methoxides Bearing Chiral, N-Salicylidene-tert-butylglycinates. Organic Letters, 13(1)，P.26-p.29. (SCI, 6/56,Chemistry, Organic). NSC 98-2119-M-003-005-MY3. 本人為第一作者、通訊作者.
26.Chian-Hui Lai, Chia-Yi Lin, Huan-Ting Wu, Hau-Shien Chan, Yung-Jen Chuang, Chien-Tien Chen, andChun-Cheng Lin* (2010, Nov). Galactose Encapsulated Multifunctional Nanoparticle for HepG2 Cell Internalization. ADVANCED FUNCTIONAL MATERIALS, 20(22), 3948-3958. (SCI, 10/232, Materials Science/Multidisciplinary). NSC 96-2627-M-003-001.
27.Wen-Ching Chen, Po-Chiao Lin, Chien-Hsiang Chen, and Chien-Tien Chen* (2010, Nov). Modulation of Photoswitching Profiles by 10,11-Dialkoxymethyl Substituents in C2-Symmetric Dibenzosuberane-based Helicene. Chemistry - A European Journal, 16, P.12822-12830. (SCI, 20/154, Chemistry, Multidisciplinary).NSC 98-2119-M-003-006-MY3. 本人為通訊作者.
28.Chien-Tien Chen, Ching-Shih Chen6, Yi-Ching Wang* (2010, Sep). A Novel Histone Deacetylase Inhibitor Exhibits Antitumor Activity via Apoptosis Induction, F-Actin Disruption and Gene Acetylation in Lung Cancer. PLoS One,5(9):e12417, P. 1-P.10. (SCIE). NSC 96-2627-M-003-001.
29.Wen-Ching Chen, Yi-Wei Lee, and Chien-Tien Chen* (2010, Apr). Diastereoselective, Synergistic Dual-Mode Optical Switch with Integrated Chirochromic Helicene and Photochromic Bis-azobenzene Moieties. Organic Letters, 12 (7), 1472-1475. (SCI, 6/56, Chemistry, Organic). NSC 98-2119-M-007-012-MY3. 本人為通訊作者.
30.Cheng-Yuan Liu, Vijay D. Pawar, Jun-Qi Kao, and Chien-Tien Chen* (2010, Jan). Substitution- and Elimination-free Phosphorylation of Functionalized Alcohols Catalyzed by Oxidomolybdenum Tetrachloride. ADVANCED SYNTHESIS & CATALYSIS, 352期, p. 188-p. 194. (SCI, 2/71, Chemistry, Applied). NSC 97-2623-M-003-001. 本人為通訊作者.
31.Chien-Tien Chen*, Yow-Dzer Lin, Cheng-Yuan Liu (2009, Oct). Catalytic Carbon-Sulfur Bond Formation by Amphoteric Vanadyl Triflate:Exploring with Thia-Michael Addition, Thioacetalization and Transthioacetalization Reactions. Tetrahedron, 65, p10470-p10476. (SCI, 16/56, Chemistry, Organic). NSC 98-2113-M-003-001. 本人為第一作者、通訊作者.
32.Yi Wei, Shingo Samori, Sachiko Tojo, Mamoru Fujitsuka, Jin-Sheng Lin, Chien- Tien Chen*, Tetsuro Majima* (2009, May). Emission Mechanism of Doubly Ortho-linked Quinoxaline/Diphenylfluorene or cis-Stilbene/Fluorene Hybrid Compounds Based on the Transient Absorption and Emission Measurements during the Pulse Radiolysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131(19)，p6698-p6707. (SCI, 11/154, Chemistry, Multidisciplinary).NSC 97-2627-M-003-001. 本人為通訊作者.
33.Way-Zen Lee*, Tzu-Li Wang, Huan-Sheng Tsang, Cheng-Yuan Liu, Chien-Tien Chen*, and Ting-Sheng Kuo (2009, Jan). Temperature Dependant Nuclearity in bis-(Benzimidazoyl) Nickel Complexes and Their Catalysis Towards Conjugate Addition of Thiophenols to alpha,beta-Unsaturated Enones. Organometallics, 28(2), p652-655. (SCI, 6/44, Chemistry, Inorganic). NSC 97-2627-M-003-001.本人為通訊作者.
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