汪洋 - 郑州轻工业大学 - 材料与化学工程学院

个人简介

一、个人情况汪洋，男，1989年11月出生，河南省固始县人，理学博士，讲师。主要从事有机催化反应的反应机理、立体和区域选择性的理论研究，以及相关理论方法的改进和创新工作，主要涉及有机小分子（氮杂环卡宾，NHC）催化环化反应、C-X键功能化反应机理、过渡金属催化C-H功能化反应机理的理论研究。通过对NHC不对称催化烯醛的环化反应、C(sp3)-X键活化等的反应机理的理论研究工作，找到了这一类催化反应能量最占优势的反应路径，而且合理解释了立体选择性、区域额选择性产生的原因，揭示了催化剂在反应中提高反应物活性和反应立体选择性的关键角色，为人们设计更高效的有机小分子催化剂提供了理论依据。迄今共发表SCI论文30余篇，其中包括Adv. Synth. Catal. 1篇，Catal. Sci. Catal. 1篇，Org. Chem. Front. 4篇，J. Org. Chem. 2篇，ChemCatChem. 1篇，Org. Biomol. Chem. 1篇，J. Phys. Chem. A 2篇。二、教育背景 2007.09-2011.07 河南大学行政管理专业，获管理学学士学位； 2011.09-2017.07 郑州大学物理化学专业，获理学博士学位；三、工作经历 2017.05-今郑州轻工业学院化学系，讲师

研究领域

有机小分子（氮杂环卡宾，NHC）催化环化反应、C-X键功能化反应机理过渡金属催化C-H功能化反应机理

近期论文

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Wang, Y.; Du, C.; Wang, Y. Y.; Guo, X. K.; Fang, L.; Song, M.-P.; Niu, J.-L.; Wei, D. H.; High-Valent Cobalt Catalyzed C-H Activation/Annulation of 2-Benzamidopyridine 1-Oxide with Terminal Alkyne: A Combined Theoretical and Experimental Study, Adv. Synth. Catal., 2018, 360, 2668–2677. Wang, Y.; Wang, Y. Y.; Wang, X. H.;, Li, X.; Qu, L.-B.; Wei, D. H. Competing Mechanisms and Origins of Chemo- and Stereo-Selectivities of NHC-Catalyzed Reactions of Enals with 2-Aminoacrylates, Catal. Sci. Technol., 2018, 8, 4229–4240. Wang, Y.; Zhang, S.-R.; Wang, Y. Y.; Qu, L.-B.; Wei, D. H. Insights into the NHC-catalyzed cascade Michael/aldol/lactamization reaction: mechanism and origin of stereoselectivity, Organic Chemistry Frontiers, 2018, 5, 2065–2072. Wang, Y.; Wei, D. H.; Zhang, W. J. Recent Advances on Computational Investigations of N-Heterocyclic Carbene Catalyzed Cycloaddition/Annulation Reactions: Mechanism and Origin of Selectivities, ChemCatChem, 2018, 10, 338–360 Wang, Y.; Wei, D. H.; Tang, M. S. Computational Study on γ-C–H Functionalization of α,β-Unsaturated Ester Catalyzed by N-Heterocyclic Carbene: Mechanisms, Origin of Stereoselectivity, and Role of Catalyst, J. Org. Chem., 2017, 82, 13043−13050. Wang, Y., Qiao, Y., Wei, D. H., Tang, M. S. Computational study on NHC-catalyzed enantioselective and chemoselective fluorination of aliphatic aldehydes, Organic Chemistry Frontiers, 2017, 4, 1987-1998. Wang, Y.; Wu, B. H.; Zheng, L. J.; Wei, D. H.; Tang, M. S. DFT perspective toward [3 + 2] annulation reaction of enals with α-ketoamides through NHC and Brønsted acid cooperative catalysis: mechanism, stereoselectivity, and role of NHC, Org. Chem. Front. 2016, 3, 190-203. Wang, Y.; Tang, M. S.; Wang, Y. Y.; Wei, D. H. Insights into Stereoselective Aminomethylation Reaction of α,β-Unsaturated Aldehyde with N,O-Acetal via N Heterocyclic Carbene and Brønsted Acid/Base Cooperative Organocatalysis, J. Org. Chem., 2016, 81, 5370-5380. Wang, Y.; Wu, B. H.; Zhang, H. Y.; Wei, D. H.; Tang, M. S. A computational study on the N-heterocyclic carbene-catalyzed Csp2–Csp3 bond activation/[4+2] cycloaddition cascade reaction of cyclobutenones with imines: a new application of the conservation principle of molecular orbital symmetry, Phys. Chem. Chem. Phys., 2016, 18, 19933-19943. Wang, Y.; Zheng, L. J.; Wei, D. H.; Tang, M. S. A quantum mechanical study of the mechanism and stereoselectivity of the N-heterocyclic carbene catalyzed [4 + 2] annulation reaction of enals with azodicarboxylates, Org. Chem. Front. 2015, 2, 874-884. Wang, Y.; Guo, X. K.; Tang, M. S.; Wei, D. H. Theoretical Investigations toward the Asymmetric Insertion Reaction of Diazoester with Aldehyde Catalyzed by N-Protonated Chiral Oxazaborolidine: Mechanisms and Stereoselectivity, J. Phys. Chem. A 2015, 119, 8422-8431. Wang, Y.; Guo, X. K.; Wu, B. H.; Wei, D. H.; Tang, M. S. Mechanistic and stereoselectivity study for the reaction of trifluoropyruvates with arylpropenes catalyzed by a cationic Lewis acid rhodium complex, RSC Adv. 2015, 5, 100147-100158. Wang, Y.; Wei, D. H.; Zhang, W. J.; Wang, Y. Y.; Zhu, Y. Y.; Jia, Y.; Tang, M. S. A theoretical study on the mechanisms of the reactions between 1,3-dialkynes and ammonia derivatives for the formation of five-membered N-heterocycles, Org. Biomol. Chem. 2014, 12, 7503-7514. Wang, Y.; Wei, D. H.; Li, Z. Y.; Zhu, Y. Y.; Tang, M. S. DFT study on the mechanisms and diastereoselectivities of Lewis acid-promoted ketene-alkene [2 + 2] cycloadditions: what is the role of Lewis acid in the ketene and C = X (X = O, CH2, and NH) [2 + 2] cycloaddition reactions? J. Phys. Chem. A 2014, 118, 4288-4300. Wang, Y.; Ren, J. Y.; Qi, S. J.; Wei, D. H.; Tang, M. S. Mechanistic insights into the stereoselective C2-functionalization of 1-substituted imidazoles with cyanophenylacetylene and aldehydes, Comput. Theor. Chem. 2014, 1049, 35-41. Wang, Y.; Wei, D. H.; Zhu, Y. Y.; Liu, P.; Tang, M. S. A DFT study on the reaction mechanisms of isocyanide-based multicomponent synthesis of polysubstituted cyclopentenes, Comput. Theor. Chem. 2013, 1018, 85-90.