个人简介

1987 ~ Professor of NTHU 1983 ~ 1987 Associate Professor of NTHU 1981 ~ 1982 Postdoctoral Research, Texas A&M University - College Station

研究领域

Organic, Organometallics and Inorganic

Our current interest focuses on elaboration of transition metal unsaturated hydrocarbyl complexes such as η'-alkynyl, η'-propargyl species for stereoselective synthesis of oxygen heterocyclics. For example, we have been successful in utilization of CpMo (CO)2(π-allyl) as chiral auxiliary for stereoselective synthesis of complex 1, 3-diol, α-methylene butyrolactones, furanones and tetrahydrofuran compounds. Recently, we have also employen tungsten-hl-propargyl compounds for synthesis of (-)-methylenelactocin, (-)-Paraconic Acid and (-)-Avenacinolide.

近期论文

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1.Diboron compound-based organic light-emitting diodes with high efficiency and reduced efficiency roll-off. Tien-Lin Wu, Min-Jie Huang, Chih-Chun Lin, Pei-Yun Huang, Tsu-Yu Chou, Ren-Wu Chen-Cheng, Hao-Wu Lin *, Rai-Shung Liu* and Chien-Hong Cheng,*Nature Photonics.2018, 12, 235. 2.Gold-catalyzed [4+3]- and [4+2]-Annulations of 3-En-1-ynamides with Isoxazoles via Novel 6p-Electrocyclizations of 3-Azaheptatrienyl Cations.SovanSundarGiri and Rai-ShungLiu,*Chem. Sci.2018, 9, 2991. 3.Brønsted Acids Enable Three Molecular Rearrangements of One 3-Alkylidene-2H-1,2-oxazine Molecule: Availability of Four Distinct Heterocycles from Nitroso [4+2] Cycloadditions.Bhanudas D. Mokar, Jinxian Liu and Rai-ShungLiu,*Org. Lett. 2018, 20, 1038. 4.Gold-catalyzed N,O-functionalizations of 1,4-diyn-3-ols with N-hydroxyanilines to form highly functionalized pyrrole derivatives.Yu-Chen Hsu, Shu-An Hsieh, Po-Hsuan Li and Rai-ShungLiu,*ChemCommun.2018, 54, 2114. 5.Gold-catalyzed Oxidative Hydroacylation Reactions of α-Iminoalkynes with Aldehydes and O2.Yu-Chen Hsu, Jing-He Lai and Rai-ShungLiu,*Chem. Commun.2017, 53, 6009. 6.Gold-catalyzed N,O-Functionalizations of 6-Allenyl-1-ynes with N-Hydroxyanilines to Construct Benzo[b]-azepin-4-one Cores.Antony SekarKulandai Raj, Balaji S. Kale,Bhanudas D. Mokar and Rai-ShungLiu,*Org. Lett.2017, 19, 5340. 7.Gold-catalyzed [4+2]-Annulation/Cyclization Cascades of Benzoisoxazoles with Propiolate Derivatives to Access Highly Oxygenated Tetrahydroquinolines.RajkumarLaljiSahani, and Rai-ShungLiu,*Angew. Chem. Int. Ed.2017, 56, 12736. 8.Ground-State Dioxygen Undergoes Metal-Free [3+2]-Annulations with Allenes and Nitrosoarenes Under Ambient Conditions.Jinxian Liu,Manisha Skaria,and Rai-ShungLiu,*Chem. Science, 2017, 8, 5482. 9.Gold-catalyzed Oxidative [2+2+1] Annulations of Aryldiazo Nitriles with Imines to Yield PolyarylatedImidazolium Salts.Samir KundlikPawar, Ming-Chung Yang, Ming-Der Su* and Rai-ShungLiu,*Angew. Chem. Int. Ed. 2017, 56, 5035. 10.Copper-catalyzed Three-Component Annulations of Alkenes, Nitrosoarenes and N-hydroxyallylamines to Form Fused Oxazinane/isoxazolidine Heterocycles. Rahul KisanKawade and Rai-ShungLiu,*Angew. Chem. Int. Ed. 2017, 56, 2035. 11.Development of Gold-catalyzed [4+1] and[2+2+1]/[4+2]Annulations between Propiolate Derivatives and Isoxazoles.RajkumarLaljiSahani, and Rai-ShungLiu,*Angew. Chem. Int. Ed. 2017, 56, 1026. 12.Two Distinct Cyclizations of 2-Propenyl-1-ethynyl benzenes with Aryldiazo Esters Using Au and Rh/Au catalysts respectively. SachinBhausahebWagh, Yu-Chen Hsu and Rai-ShungLiu,*ACS Catalysis, 2016, 6, 7160. 13.Gold-catalyzed Intermolecular Oxidations of 2-Ketonyl-1-ethynyl benzenes with N-Hydoxyanilines to Yield 2-Aminoindenones via Gold Carbene Intermediates. BhanudasDattatrayMokar, Deepak B. Huple and Rai-ShungLiu,*Angew. Chem. Int. Ed. 2016, 55, 11892. 14.Gold-catalyzed [3+2]-Annulations of α-Aryl Diazonitriles with Ynamides and Allenamides to Yield 1-Amino-1H-Indenes. RahulKumarRajmani Singh, Samir KundlikPawar and Rai-ShungLiu,*Chem. Commun.2016, 52, 11434. 15.Recent Advance in Gold-Catalyzed N- and O-Functionalizations of Alkynes with Nitrones, Nitroso, Nitro and Nitroxy Species. Deepak B. Huple, Satish Ghorpade and Rai-ShungLiu,*Adv. Synth. Catal., 2016, 358, 1348. an invited review. 16.[3+2]-Annulations of N-HydroxyAllenylamines with Nitrosoarenes: One Pot Synthesis of Substituted Indole Products. Pankaj Sharma and Rai-ShungLiu,*Org. Lett., 2016, 18(3), 412. 17.Alkene-Directed N-Attack Chemoselectivity in the Gold-catalyzed [2+2+1]-Annulations of 1,6-Enynes with N-Hydroxyanilines.Deepak. B. Huple, Bhanudas D. Mokar and Rai-ShungLiu,*Angew. Chem. Int. Ed., 2015, 54, 14924. 18.Gold-catalyzed Formal [4+2]-Cycloadditions of Propiolate Derivatives with Unactivated Nitriles. Somnath Narayan Karad, Wei-Kang Chung and Rai-ShungLiu,*Chemical Science, 2015, 6(10), 5964. 19.Gold-catalyzed Cycloaddition Reactions of Ethyldiazoacetate, Nitrosoarenes and Vinyldiazo Carbonyl Compounds for the Synthesis of Isoxazolidine and Benzo[b]azepine Derivatives. Vinayak Vishnu Pagar and Rai-ShungLiu,*Angew. Chem. Int. Ed. 2015, 54,4923. 20.Zn(II)-catalyzed Intermolecular Hydrative Aldol Reactions of 2-En-1-ynamides with Aldehydes and Water to form Branched Aldol Products Regio- and Stereoselectively.AppasoMahadevJadhav, Vinayak Vishnu Pagar, Deepak B. Huple and Rai-ShungLiu,*Angew. Chem. Int. Ed.2015, 54,3812.