个人简介

2012 ~ Professor of NTHU 2008 ~ 2012 Associate Professor of NTHU 2003 ~ 2008 Assistant Professor of NTHU 2001 ~ 2003 Postdoctoral Research, California Institute of Technology

研究领域

Inorganic & Organic Synthesis; Catalysis

Our research is currently focused on the assembly of reactive polynuclear metal complexes. We have successfully prepared many reactive dinuclear complexes featuring metal-metal multiple bonding. We aim to use the synthesized metal complexes to effect novel chemical transformations, such as activation of N2, CO2, CO, NO, organic catalysis, and modeling metalloenzymes in biological systems. Physical property study of polynuclear metal complexes is also one of our current interests. Students in our group focus in synthetic organic and organometallic chemistry, and characterize new organic and organometallic compounds using multiple techniques such as multinuclear NMR spectroscopy, EPR, magnetism, X-ray crystallography, IR, Raman, UV-vis, and Cyclic Voltammetry. In certain cases, we have explored our systems with the aid of high level DFT methods for the understanding of structures, bonding, and reactions.

近期论文

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1.Chang, K.-C.; Lu, C.-F.; Wang, P.-Y.; Lu, D.-Y.; Chen, H.-Z.; Kuo, T.-S.; Tsai, Y.-C. “Ligand-controlled synthesis of vanadium(I) b-diketiminates and their catalysis in cyclotrimerization of alkynes” Dalton Trans. 2011, 40, 2324. 2.Lin, K.-M.; Wang, P.-Y.; Shieh, Y.-J.; Chen, H.-Z.; Kuo, T.-S.; Tsai, Y.-C.* “Reductive N–N bondcleavage and coupling of organic azides mediated by chromium(I) and vanadium(I) b-diketiminate”New. J. Chem. 2010, 34, 1737. 3.Tsai, Y.-C.*; Chen, H.-Z.; Chang, C.-C.; Yu, J.-S. K. ; Lee, G.-H. ; Wang, Yu ; Kuo, T.-S. “Journey from Mo–Mo Quadruple Bonds to Quintuple Bonds” J. Am. Chem. Soc. 2009, 131,12534. 4.Hsu, C.-W.; Yu, J.-S. K.; Lee, G.-H.; Wang, Y.; Tsai, Y.-C.* “Quintuply-Bonded Dichromium(I) Complexes Featuring Metal-Metal Bond Lengths of 1.74 Å” Angew. Chem. Int. Ed. 2008, 47, 9933. 5.Tsai, Y.-C.*; Hsu, C.-W.; Yu, J.-S. K.; Lee, G.-H.; Wang, Y.; Kuo, T. S.“RemarkablyShort Metal-Metal Bonds: A Lantern-Type of Quintuply-Bonded Dichromium(I) Complex” Angew. Chem. Int. Ed. 2008, 47, 7250-7253. Reported by Nature “Photo finish for shortest metal-metal bond”doi:10.1038/news.2008.1042, highlighted by Nature Chemistry“Metal-metal bonds: Shorter andshorter” doi:10.1038/nchem.54, and by Science “Gold for the shortest bond” in the section of Editor’sChoice 2008, 321,1134. 6.Tsai, Y.-C.*; Wang, P.-Y.; Lin, K.-M.; Chen, S.-A.; Chen, J.-M. “Synthesis and Reactions of b-Diketiminato Divanadium(I) Inverted-Sandwich Complexes” Chem. Commun. 2008, 205-207. 7.Tsai, Y.-C.*; Lu, D.-Y; Lin, Y.-M.; Yu, J.-S. K. Hwang, J.-K. “Structural Transformations in Dinuclear Zinc Complexes Involving Zn-Zn Bonds” Chem. Commun. 2007, 4125. 8.Tsai, Y.-C.*; Wang, P.-Y.; Chen, S.-A.; Chen, J.-M. “Inverted-Sandwich Dichromium(I) Complexes Supported by two b-Diketiminates: A Multi-Electron Reductant and Syntheses of Chromium Dioxo and Imido” J. Am. Chem. Soc. 2007, 129, 8066. 9.Tsai, Y.-C.*; Lin, Y.-M.; Yu, J.-S. K. Hwang, J.-K. “A Three-Coordinate and Quadruply-Bonded Mo−Mo Complex” J. Am. Chem. Soc. 2006, 128, 13980.