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Organic Chemistry

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Unbiased rotational motions of an ellipsoidal guest in a tight yet pliable host, Sun, Z.; Mio, T.; Okada, T.; Matsuno, T.; Sato, S.; Kono, H.; Isobe, H. Angew. Chem. Int. Ed. published online. (https://doi.org/10.1002/anie.201812771) Neutron scattering reveals water confined in a watertight bilayer vesicle, Abuillan, W.; Becker, A.S.; Demé, B.; Homma, T.; Isobe, H.; Harano, K.; Nakamura, E.; Tanaka, M. J. Am. Chem. Soc. 2018, 140 (36) 11261-11266. (https://doi.org/10.1021/jacs.8b04066) Concyclic CH-π arrays for single-axis rotations of a bowl in a tube, Matsuno, T.; Fujita, M.; Fukunaga, K.; Sato, S.; Isobe, H. Nat. Commun. 2018, 9, 3779. (https://doi.org/10.1038/s41467-018-06270-6) Triazole linking for preparation of a next-generation sequencing library from single-stranded DNA, Miura, F.; Fujino, T.; Kogashi, T.; Shibata, Y.; Miura, M.; Isobe, H.; Ito, T. Nucl. Acids Res. 2018, 46 (16), e95. (https://doi.org/10.1093/nar/gky452) Fluctuating carbonaceous networks with a persistent molecular shape: A saddle-shaped geodesic framework of 1,3,5-trisubstituted benzene (phenine), Ikemoto, K.; Lin, J.; Kobayashi, R.; Sato, S.; Isobe, H. Angew. Chem. Int. Ed. 2018, 57 (28), 8555-8559. (https://doi.org/10.1002/anie.201803984) Ratchet-free solid-state inertial rotation of a guest ball in a tight tubular host, Matsuno, T.; Nakai, Y.; Sato, S.; Maniwa, Y.; Isobe, H. Nat. Commun. 2018, 9, 1907. (https://doi.org/10.1038/s41467-018-04325-2) Magneto-electroluminescence effects in the single-layer organic light-emitting devices with macrocyclic aromatic hydrocarbons, Pham, S.-T.; Ikemoto, K.; Suzuki, K.Z.; Izumi, T.; Taka, H.; Kita, H.; Sato, S.; Isobe, H.; Mizukami, S. APL Mater. 2018, 6, 026103. (Selected as Editor’s pick) (https://doi.org/10.1063/1.5021711) Chiral intertwined spirals and magnetic transition dipole moments dictated by cylinder helicity, Sato, S.; Yoshii, A.; Takahashi, S.; Furumi, S.; Takeuchi, M.; Isobe, H. Proc. Natl. Acad. Sci. U.S.A. 2017, 114 (50), 13097-13101. (http://dx.doi.org/10.1073/pnas.1717524114) Enhanced yet inverted effects of π-extension in self-assembly of curved π-systems with helicity, Matsuno, T.; Kogashi, K.; Sato, S.; Isobe, H. Org. Lett. 2017, 19 (23), 6456-6459. (http://dx.doi.org/10.1021/acs.orglett.7b03534) Assembly, thermodynamics and structure of a two-wheeled composite of a dumbbell-shaped molecule and cylindrical molecules with different edges, Matsuno, T.; Kamata, S.; Sato, S.; Yokoyama, A.; Sarkar, P.; Isobe, H. Angew. Chem. Int. Ed. 2017, 56 (47), 15020-15024. (http://dx.doi.org/10.1002/anie.201709442) Synthesis of 9,10-diarylanthracenes via Mg(TMP)2·2LiCl-mediated benzyne generation/[4+2]cycloaddition and deoxygenation of 9,10-epoxyanthracene intermediates, Miyamoto, N.; Nakazawa, Y.; Nakamura, T.; Okano, K.; Sato, S.; Sun, Z.; Isobe, H.; Tokuyama, H. Synlett 2018, 29, 513-519. (http://dx.doi.org/10.1055/s-0036-1591510) Pentagon-embedded cycloarylenes with cylindrical shapes, Hitosugi, S.; Sato, S.; Matsuno, T.; Koretsune, T.; Arita, R.; Isobe, H. Angew. Chem. Int. Ed. 2017, 56 (31), 9106-9110. (http://dx.doi.org/10.1002/anie.201704676) [n]Cyclo-3,6-phenanthrenylenes: Synthesis, structure and fluorescence, Tian, Y.; Ikemoto, K.; Sato, S.; Isobe, H. Chem. Asian J. 2017, 12 (16) 2093-2097. (http://dx.doi.org/10.1002/asia.201700563) Entropy-driven ball-in-bowl assembly of fullerene and geodesic phenylene bowl, Ikemoto, K.; Kobayashi, R.; Sato, S.; Isobe, H. Org. Lett. 2017, 19 (9), 2362-2365. (http://dx.doi.org/10.1021/acs.orglett.7b00899) Synthesis and bowl-in-bowl assembly of a geodesic phenylene bowl, Ikemoto, K.; Kobayashi, R.; Sato, S.; Isobe, H. Angew. Chem. Int. Ed. 2017, 56 (23), 6511-6514. (http://dx.doi.org/10.1002/anie.201702063) Room temperature magnetoresistance in an organic spin valve with an aromatic hydrocarbon macrocycle, Suzuki, K.Z.; Izumi, T.; Zhang, X.; Sugihara, A.; Pham, S.-T.; Taka, H.; Sato, S.; Isobe, H.; Mizukami, S. APL Mater. 2017, 5, 046101. (http://dx.doi.org/10.1063/1.4979548) An isolable potassium salt of a borasilene-chloride adduct, Suzuki, Y.; Ishida, S.; Sato, S.; Isobe, H.; Iwamoto, T. Angew. Chem. Int. Ed. 2017, 56 (16), 4593-4597. (http://dx.doi.org/10.1002/anie.201612545) Efficient blue electroluminescence from a single-layer organic device composed solely of hydrocarbons, Izumi, T.; Tian, Y.; Ikemoto, K.; Yoshii, A.; Koretsune, T.; Arita, R.; Kita, H.; Taka, H.; Sato, S.; Isobe, H. Chem. Asian J. 2017, 12 (7), 730-733. (http://dx.doi.org/10.1002/asia.201700198) Structural modulation of macrocyclic materials for charge carrier transport layers in organic light-emitting devices, Yoshii, A.; Ikemoto, K.; Izumi, T.; Kita, H.; Taka, H.; Koretsune, T.; Arita, R.; Sato, S.; Isobe, H. ECS J. Solid State Sci. Technol. (Sir Harold Kroto Special Issue), 2017, 6 (6), M3065-M3067. (http://dx.doi.org/10.1149/2.0111706jss) Crystal structure of 7,15-bis(4-tert-butylphenyl)-1,9-dimethyl-heptazethrene, Kamata, S.; Sato, S.; Wu, J.; Isobe, H. Acta Cryst. 2017, E73, 99-102. (http://dx.doi.org/10.1107/S2056989016020247)

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