个人简介

Professor Fiedler received his Ph.D. degree in inorganic chemistry under the direction of Thomas Brunold at the University at Wisconsin-Madison in 2006. After graduating from Madison, he began an NIH postdoctoral fellowship in the laboratory of Prof. Larry Que, Jr. at the University of Minnesota, where synthesized and characterized high-valent iron complexes with relevance to oxygen activation in biological systems. He joined the faculty at Marquette University in August 2009. Professor Fiedler’s research interests are in the area of synthetic bioinorganic chemistry, spectroscopy, and computational methods.

研究领域

Inorganic Chemistry

My group's research falls within the general field of bio-inspired inorganic chemistry. The common theme is the synthesis and characterization of inorganic complexes that mimic the structure and/or function of metalloenzymes. All of our projects are multifaceted, combining inorganic coordination chemistry with mechanistic studies, spectroscopic characterization (UV-vis, EPR, MCD, X-ray absorption, resonance Raman), and computational (DFT) analysis.

近期论文

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Bittner, M.M.; Lindeman, S.V.; Popescu, C.V.;* Fiedler, A.T.* “Dioxygen Reactivity of Biomimetic Fe(II) Complexes with Noninnocent Catecholate, o-Aminophenolate, and o-Phenylenediamine Ligands.” Inorganic Chemistry 2014, 53, 4047-4061. Baum, A.E.; Lindeman, S.V.; Fiedler, A.T.* “Preparation of a Semiquinonate- Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures.” Chemical Communications 2013, 49, 6531-6533. Wang, D.; Lindeman, S.V., Fiedler, A.T.* “Intramolecular Hydrogen Bonding in Cu(II) Complexes with 2,6-Pyridinedicarboxamide Ligands: Synthesis, Structural Characterization, and Physical Properties.” European Journal of Inorganic Chemistry 2013, 4473-4484. Bittner, M.M.; Kraus, D.; Lindeman, S.V.; Popescu, C.V.;* Fiedler, A.T.* “Synthetic, Spectroscopic and DFT Studies of Iron Complexes with Iminobenzo(semi)quinone Ligands: Implications for o-Aminophenol Dioxygenases.” Chemistry – A European Journal 2013, 19, 9686-9698. Park, H.; Bittner, M.M.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.* “Fe(II) Complexes That Mimic the Active Site Structure of Acetylacetone Dioxygenase: O2 and NO Reactivity.” Inorganic Chemistry 2012, 51, 10279-10289. Baum, A.E.; Park, H.; Wang, D.; Lindeman, S.V.; Fiedler, A.T.* “Structural, Spectroscopic, and Electrochemical Properties of Nonheme Fe(II)-Hydroquinonate Complexes: Synthetic Models of Hydroquinone Dioxygenases.” Dalton Transactions 2012, 41, 12244-12253. Bittner, M.M.; Lindeman, S.V.; Fiedler, A.T.* “A Synthetic Model of the Putative Fe(II)-Iminobenzosemiquinonate Intermediate in the Catalytic Cycle of o-Aminophenol Dioxygenases.” Journal of the American Chemical Society 2012, 134, 5460-5463. (This paper was selected for the “Models of Metalloenzymes” virtual issue). Bittner, M.M.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.* “Synthesis and Structural Characterization of Iron(II) Complexes with Tris(imidazolyl)phosphane Ligands: A Platform for Modeling the 3-Histidine Facial Triad of Nonheme Fe Dioxygenases.” European Journal of Inorganic Chemistry 2012, 1848-1856. Park, H.; Baus, J.S.; Lindeman, S.V.; Fiedler, A.T.* “Synthesis and Characterization of Fe(II) b-Diketonate Complexes with Relevance to Acetylacetone Dioxygenase: Insights into the Electronic Properties of the 3-His Facial Triad.” Inorganic Chemistry 2011, 50, 11978–11989.