研究领域
Analytical & physical chemistry, freeze-frame spectroscopy, catalytic reaction mechanisms
The primary goal of the Moore group research program is to gain a detailed understanding of catalytic reaction mechanisms involving various metallic and non-metallic nanoparticles (NPs). To achieve this, my lab is developing a new approach called “freeze-frame” spectroscopy, which involves the use of liquid helium nanodroplets to stabilize pre- and post-reactive complexes of free NPs with reactant molecules. These complexes are then probed using infrared spectroscopy, and structural assignment is achieved based on predictions from computational studies.
近期论文
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“IR-spectroscopic characterization of intermediates in a gas-phase ion-molecule reaction: the decarbonylation of acetophenone with Co+” R.C. Dunbar, D.T. Moore, J. Oomens; Int. J. Mass. Spec., in press.
“Infrared spectroscopy of hydrated sulfate dianions” J. Zhou, G. Santambrogio, M. Brümmer, D.T. Moore, L. Wöste, G. Meijer, D.M. Neumark, K.R. Asmis; J. Chem. Phys. 125, [2006] 111102.
“IR-spectroscopic characterization of acetophenone complexes with Fe+, Co+, and Ni+ using free-electron laser IRMPD” R.C. Dunbar, D.T. Moore, J. Oomens; J. Phys. Chem. A 110, [2006] 7243-7254.
“Vibrational spectroscopy of mass-selected [UO2(ligand)n]2+ complexes in the gas phase: Comparison with theory” G.S. Groenewold, A.K. Gianotto, K.C. Cossel, M.J. van Stipdonk, D.T. Moore, N. Polfer, J. Oomens, W.A. de Jong, L. Visscher; J. Am. Chem. Soc. 128, [2006] 4802-4813.
“Infrared Spectroscopy of Gas-Phase Cr+ Coordination Complexes: Determination of Binding Sites and Electronic States” D.T. Moore, J. Oomens, J.R. Eyler, G. von Helden, G. Meijer, R.C. Dunbar; J. Am. Chem. Soc. 127, [2005] 7243-7254.
“Structure of the acetylene-magnesium binary complex from infrared laser spectroscopy in helium nanodroplets” D.T. Moore, R.E. Miller; J. Phys. Chem. A 108, [2004] 9908-9915.
“Structures of HCN-Mgn (n=2-6) complexes from rotationally resolved vibrational spectroscopy and ab initio theory” P.L. Stiles, D.T. Moore, R.E. Miller; J. Chem. Phys. 121, [2004] 3130-3142.