研究领域

Organic Synthesis

Development of catalytic asymmetric reactions keyword : Asymmetric synthesis, asymmetric oxidation, hydrogen peroxide 2008.01.

近期论文

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Kazuhiro Matsumoto, Chao Feng, Satoshi Handa, Takuya Oguma, Tsutomu Katsuki,Asymmetric epoxidation of (Z)-enol esters catalyzed by titanium(salalen) complex with aqueous hydrogen peroxide,Tetrahedron,Vol.67,pp.6474–6478,2011.06. Konstanze K. Gruner, Thomas Hopfmann, Kazuhiro Matsumoto, Anne Jäger, Tsutomu Katsuki and Hans-Joachim Knölker,Efficient iron-mediated approach to pyrano[3,2-a]carbazole alkaloids–first total syntheses of O-methylmurrayamine A and 7-methoxymurrayacine, first asymmetric synthesis and assignment of the absolute configuration of (–)-trans-dihydroxygirinimbine,Organic & Biomolecular Chemistry,Vol.9,No.7,pp.2057 - 2061,2011.05. Junichi Fujisaki, Kenji Matsumoto, Kasuhiro Matsumoto and Tsutomu Katsuki,Catalytic Asymmetric Oxidation of Cyclic Dithioacetals: Highly Diastereo- and Enantioselective Synthesis of the S-Oxides by a Chiral Aluminum(salalen) Complex,Journal of the American Chemical Society,Vol.133,pp.56 - 61,2011.01. Yoshifumi Sakai, Junko Mitote, Kazuhiro Matsumoto and Tsutomu Katsuki,Room-temperature synthesis of enantioenriched non-protected cyanohydrins using vanadium(salalen) catalyst,Chemical Communications,Vol.46,No.31,pp.5787 - 5789,2010.07. Keitaro Suyama, Yoshifumi Sakai, Kazuhiro Matsumoto, Bunnai Saito and Tsutomu Katsuki,Highly Enantioselective Hydrophosphonylation of Aldehydes: Base-Enhanced Aluminum-salalen Catalysis,Angewandte Chemie International Edition,Vol.48,No.4,pp.797-799,2010.01. Kazuhiro Matsumoto, Takuya Oguma and Tsutomu Katsuki,Highly Enantioselective Epoxidation of Styrenes Catalyzed by Proline-Derived C1-Symmetric Titanium(Salan) Complexes,Angewandte Chemie International Edition,Vol.48,No.40,pp.7432-7435,2009.09. Kazuhiro Matsumoto, Takuya Kubo and Tsutomu Katsuki,Highly Enantioselective Epoxidation of cis-Alkenylsilanes,Chemistry - A European Journal,Vol. 15, No. 15, 6573-6575.,2009.06. Keitaro Suyama, Kazuhiro Matsumoto and Tsutomu Katsuki,Asymmetric Lewis Acid Catalysis of Aluminum (Salalen) Complexes: Friedel-Crafts Reaction of Indole,Heterocycles,Vol. 77, No. 2, 817-824.,2009.02. Shoich Kondo, Kowichiro Saruhashi, Kenichi Seki, Koutatsu Matsubara, Katsuski Miyaji, Takuya Kubo, Kazuhiro Matsumoto and Tsutomu Katsuki,A μ-oxo-μ-η2:η2-Peroxo Titanium Complex as a Reservior of Active Species in Asymmetric Epoxidation Using Hydrogen Peroxide,Angewandte Chemie International Edition,Vol. 47, No. 52, 10195-10198.,2008.12. Kazuhiro Matsumoto, Tetsufumi Yamaguchi and Tsutomu Katsuki,Asymmetric Oxidation of Cyclic Sulfides Catalyzed by an Aluminum(salalen) Complex as the Catalyst,Heterocycles,Vol. 76, No. 1, 191-196.,2008.09. Junko Takaki, Hiromichi Egami, Kazuhiro Matsumoto, Bunnai Saito and Tsutomu Katsuki,Vanadium-Catalyzed Asymmetric Transcycnation of Aliphatic Aldehydes with Acetone Cyanohydrin,Chemistry Letters,Vol. 37, No. 5, 502-503,2008.04. Kazuhiro Matsumoto, Tetsufumi Yamaguchi and Tsutomu Katsuki,Asymmetric Oxidation of Sulfides under Solvent-Free or Highly Concentrated Conditions,Chemical Communications,No. 14, 1704-1706,2008.04. Kazuhiro Matsumoto, Tetsufumi Yamaguchi, Junichi Fujisaki, Bunnai Saito and Tsutomu Katsuki,Aluminum oxidation catalysis under aqueous conditions: highly enantioselective sulfur oxidation catalyzed by Al(salalen) complexes,Chemistry - An Asian Journal,3, 351-358,2008.02. Yuya Shimada, Shoichi Kondo, Yoshio Ohara, Kazuhiro Matsumoto and Tsutomu Katsuki,Titanium-catalyzed asymmetric epoxidation of olefins with aqueous hydrogen peroxide: remarkable effect of phosphate buffer on epoxide yield,Synlett,2445-2447,2007.08. Tetsufumi Yamaguchi, Kazuhiro Matsumoto, Bunnai Saito and Tsutomu Katsuki,Asymmetric oxidation catalysis by a chiral Al(salalen) complex: highly enantioselective oxidation of sulfides with aqueous hydrogen peroxide,Angewandte Chemie International Edition ,46, 4729-4731,2007.06. Yuji Sawada, Kazuhiro Matsumoto and Tsutomu Katsuki,Titanium-catalyzed asymmetric epoxidation of non-activated olefins with hydrogen peroxide,Angewandte Chemie International Edition ,46, 4559-4561,2007.06. Shigefumi Kanchiku, Hidehiro Suematsu, Kazuhiro Matsumoto, Tatsuya Uchida and Tsutomu Katsuki,Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations,Angewandte Chemie International Edition ,46, 3889-3891,2007.05. Yukie Nakamura, Hiromichi Egami, Kazuhiro Matsumoto, Tatsuya Uchida and Tsutomu Katsuki,Aerobic oxidative kinetic resolution of racemic alcohols with bidentate ligand-binding Ru(salen) complexes as catalyst,Tetrahedron,63, 6383-6387.,2007.07. Kazuhiro Matsumoto, Yuji Sawada and Tsutomu Katsuki,Catalytic enantioselective epoxidation of unfunctionalized olefins: utility of a Ti(OiPr)4-Salan-H2O2 system,Synlett,3545-3547,2006.12. Yuji Sawada, Kazuhiro Matsumoto, Shoichi Kondo, Hisayuki Watanabe, Tomoyuki Ozawa, Kenji Suzuki, Bunnai Saito and Tsutomu Katsuki,Titanium-salan-catalyzed asymmetric epoxidation with aqueous hydrogen peroixde as the oxidant,Angewandte Chemie International Edition ,45, 3478-3480,2006.05.