个人简介
U.C. Davis (2006), Ph.D. Inorganic Chemistry
Postdoctoral Scholar, Lawrence Livermore National Lab (2006-2009)
研究领域
My research program is directed towards understanding reaction rates and pathways of 1) ligand substitution in oxo-centered transition metal clusters 2) growth and substitution of supramolecular metal assemblies and 3) metal complexation to solid surfaces and supports. Understanding the kinetics of ligand substitution, cluster formation, and metal complexation to solid surfaces has applications in catalysis as well as geoscience. These projects are exciting areas of research, particularly now that our nation is focused on developing energy efficient technologies and improving sustainability.
近期论文
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Jacqueline R. Houston, Robert S. Maxwell Susan A. Carroll (2009) Transformation of meta-stable calcium silicate hydrates to tobermorite: Reaction pathways from water chemistry, XRD, and NMR spectroscopy, Geochemical Transactions, 10:1
Jacqueline R. Houston, Julie L. Herberg, Robert S. Maxwell Susan A. Carroll (2008) Association of dissolved Al with silica: Connecting molecular structure to surface reactivity using NMR. Geochimica Cosmochimica Acta, 72, 3326-3337
Jacqueline R. Houston, David T. Richens and William H. Casey (2006) Distinct water-exchange mechanisms for trinuclear transition metal clusters. Inorganic Chemistry 45, 7962-7967.
Jacqueline R. Houston, Marilyn M. Olmstead and William H. Casey (2006) Substituent effects in five oxo-centered trinuclear rhodium(III) clusters. Inorganic Chemistry 45, 7799-7805.
Brian L. Phillips, Jacqueline R. Houston and William H. Casey (2006) Observation of solid-state 103Rh NMR by cross-polarization. Journal of the American Chemical Society, 128, 3912-3913.
Jacqueline R. Houston, Brian L. Phillips, and William H. Casey (2006) Residence times for protons bound to three oxygen sites in the AlO4Al12(OH)24(H2O)127+(aq) polyoxocation. Geochimica Cosmochimica Acta, 70, 1636-1643.
Jacqueline R. Houston and William H. Casey (2005) Proton exchange kinetics from the bound waters on the oxo-centered rhodium(III) trimer [Rh3(μ3-O)(μ-O2CCH3)6(OH2)3]+: A variable pH and temperature 1H NMR study. Dalton Transactions, 22, 3667–3671.
Jacqueline R. Houston, Ping Yu, and William H. Casey (2005) Water exchange from the oxo-centered rhodium(III) trimer [Rh3(μ3-O)(μ-O2CCH3)6(OH2)3]+: A high-pressure 17O NMR study. Inorganic Chemistry, 44, 5176-5182.
Kris A. Pineda, James C. Fettinger, Jacqueline R. Houston "Synthesis, structure, and substitution reactivity of a new bi-oxo capped molybdenum cluster: [Mo3(µ3-O)2(µ-O2CCH2Cl)6(H2O)2(OH)]+" Inorganic Chemistry Communications (2014) In Press
Jacqueline R. Houston and Andrew J. Burton "Solvent dependent mechanistic pathways for n-O2CCH3 from the Mo3(u3-O)2 anion" Inorganica Chimica Acta 407 (2013) 210-215.
Kris A. Pineda, James C. Fettinger, Jacqueline R. Houston " A new aqueous molybdenum cluster with a Mo3(u3-CCH3)(u3-O) trinuclear core" Inorganica Chimica Acta 392 (2012) 485–489