研究领域

Organic Chemistry

Carbon resource utilization using heterogeneous catalysts keyword : Heterogeneous catalysts, Gold, Organic Synthesis 2007.04～2012.12. Development of organic reactions using heterogeneous catalysts keyword : Heterogeneous catalysts, Gold, Organic Synthesis 2007.04～2012.12. Kinetic and theoretical study of kinetic resolution of recemic organic compounds keyword : kinetic resolution 1990.01. Asymmetric hydrolysis and alcoholysis by artificial catalysts keyword : Asymmetric hydrolysis 2002.04. Irreversible ester hydrolysis keyword : Irreversible ester hydrolysis 2005.07. Hydration and hydroalkoxylation of alkenes and alkynes keyword : Hydration 1997.04.

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Yamamoto, E.;Gokuden, D.; Nagai, A. Kamachi, T.; Yoshizawa, K.; Hamasaki, A.; Ishida, T.;Tokunaga, M. ,Hydrolytic Enantioselective Protonation of Cyclic Dienyl Esters and a -diketone with Chiral Phase-transfer Catalysts ,Org. Lett.,Vol.14,pp.61787-6181,2012.12. Hamasaki, A.; Maruta, S.; Nakamura, A.; Tokunaga, M. ,Palladium-catalyzed 1,4-Addition of Carboxylic Acids to Butadiene Monoxide ,Adv. Synth. Catal.,Vol.354,No.11-12,pp.2129-2134,2012.08. Ishida, T.; Watanabe, H.; Takei, T.; Hamasaki, A.; Tokunaga, M.; Haruta, M. ,Metal Oxide-Catalyzed Ammoxidation of Alcohols to Nitriles and Promotion Effect of Gold Nanoparticles for One-Pot Amide Synthesis ,Appl. Catal. A Gen., 2012, ,Vol.425-426,pp.85-90,2012.04. Hamasaki, A.; Kuwada, H.; Tokunaga, M. ,tert-Butylnitrite as a convenient and easy-removable oxidant for the conversion of benzylic alcohols to ketones and aldehydes ,Tetrahedron Lett.,Vol.53,No.811-814,2012.03. Hamasaki, A.; Muto, A.; Haraguchi, S.; Liu, X.; Sakakibara, T.; Yokoyama, T.; Tokunaga, M. ,Cobalt oxide supported gold nanoparticles as a stable and readily-prepared precursor for the in situ generation of cobalt carbonyl like species ,Tetrahedron Lett. ,Vol.52,pp.6869-6872,2011.03. Yamamoto, E.; Nagai, A. Hamasaki, A.; Tokunaga, M.,Catalytic Asymmetric Hydrolysis: Asymmetric Hydrolytic Protonation of Enolesters Catalyzed by Phase Transfer Catalysts,Chem. Eur. J.,2011.05. Liu, X.; Hamasaki, A.; Honma, T.; Tokunaga, M.,Anti-ASF distribution in Fischer-Tropsch Synthesis over Unsupported Cobalt Catalysts in a Batch Slurry Phase Reactor,Catal. Today,,2011.05. Nakamura, A.; Hamasaki, A.; Goto, S.; Utsunomiya, M.; Tokunaga, M.,Irreversible Catalytic Ester Hydrolysis of Allyl Esters to Give Acids and Aldehydes by Homogeneous Ruthenium and Ruthenium/Palladium Dual Catalyst Systems,Adv. Synth. Catal.,Vol.353,pp.973-984,2011.02. Liu, X., Tokunaga, M.,Controllable Fischer-Tropsch Synthesis by in situ Produced 1-Olefins,ChemCatChem,No.2,pp.1569-1572,2010.11. Hamasaki, A.; Yamamoto, A.; Ito, H, Tokunaga, M.,Highly Atom Efficient Catalytic Reactions Utilizing Water and Alcohols as Reagents,J. Organomet. Chem,No.696,pp.202-210.,2010.10. ang, L.; Kinoshita, S.; Yamada, T.; Kanda, S.; Kitagawa, H.; Tokunaga, M.; Ishimoto , T.; Ogura, T.; Nagumo, R.; Miyamoto, A.; Koyama, M.,A Metal-Organic Framework as An Electrocatalyst for Ethanol Oxidation,Angew. Chem. Int Ed.,No.49,pp.5348-5351,2010.07. Hirai, T.; Hamasaki, A.; Nakamura, A.; Tokunaga, M.,Enhancement of Reaction Efficiency by Functionalyzed Alcohols on Gold(I) Catalyzed Intermolecular Hydroalkoxylation of Unactivated Olefins,Org. Lett.,2009.11. Yamane, Y.; Liu, X.; Hamasaki, A.; Ishida, T.; Haruta, M.; Yokoyama, T.; Tokunaga, M.,One-Pot Synthesis of Indoles and Aniline Derivatives from Nitroarenes under Hydrogenation Condition with Supported Gold Nanoparticles,Org. Lett.,2009, 11, 5162-5165,2009.11. Liu, X.; Hu, B.; Fujimoto, K.; Haruta, M.; Tokunaga, M.,Hydroformylation of Olefins by Au/Co3O4 Catalysts.,Appl. Catal. B,2009, 92, 411-421.,2009.10. Fujihara, T.; Kubouchi, S.; Obora, Y.; Tokunaga, M.; Takenaka, K.; Tsuji, Y.,ynthesis and Structural Characterization of a Series of Mono-O-(diphenylphosphinobenzyl)calix[6]arenes with and without tert-Butyl Moieties at the Upper Rim.,Bull. Chem. Soc. Jpn.,2009, 82, 1187-1193.,2009.09. Itoh, H.; Yamamoto, E.; Masaoka, S.; Sakai, K.; Tokunaga, M.,Kinetic Resolution of P-Chirogenic Compounds by Pd-catalyzed Alcoholysis of Vinyl Ethers,Adv. Synth. Cat.,,351, 1796-1800.,2009.08. Hamasaki, A.; Liu, X.; Tokunaga, M.,Amidocarbonylation of Aldehydes Utilizing Cobalt Oxide Supported-Gold Nanoparticles as a Heterogeneous Catalyst.,Chem. Lett,,37, 1292-1293.,2008.12. Liu, X.; Haruta, M.; Tokunaga, M.,Coprecipitated Gold-Tricobalt Tetraoxide Catalyst for Heterogeneous Hydroformylation of Olefins.,Chem. Lett,,37, 1290-1291.,2008.12. Ohmura, N.; Nakamura, A.; Hamasaki, A.; Tokunaga, M.,Hydrolytic deallylation from N-allyl amides catalyzed by Pd(II) complexes.,Eur. J. Org. Chem.,5042-5045,2008.10. Sakuma, T.; Yamamoto, E.; Aoyama, H.; Obora, Y.; Tsuji, Y.; Tokunaga, M.,Kinetic resolution of phosphoryl and sulfonyl esters of 1,10-bi-2-naphthol via Pd-catalyzed alcoholysis of their vinyl ethers.,Tetrahedron: Asymmetry,2008,19,1593-1599. ,2008.07.