Tsogoeva, Svetlana - Friedrich-Alexander-Universität Erlangen-Nürnberg

个人简介

Svetlana B. Tsogoeva is Professor of Organic Chemistry at the Friedrich-Alexander-University of Erlangen-Nuremberg, Germany, since February 2007. She studied chemistry at St. Petersburg State University, where she completed her doctoral thesis supported by Procter & Gamble on the “Synthesis of Modified Analogues of Steroid Estrogens” in 1998. Then, she moved to the Johann Wolfgang Goethe-University Frankfurt am Main, Germany, for a postdoctoral project under the sponsorship of the DFG (Graduate School "Chemische und Biologische Synthese von Wirkstoffen"), where she was dealing with the synthesis of chiral amidinium ions and their application as catalysts for the preparation of (+)-estrone derivatives using Diels-Alder reactions. In July 2000 she joined the Degussa AG Fine Chemicals Division in Hanau-Wolfgang, Germany as a research scientist, where she has been working on the synthesis and the application of new catalysts for the enantioselective Julia-Colonna asymmetric epoxidation of olefins. In January 2002 she was appointed a First Junior Professor in Germany at the Georg-August-University of Göttingen, where she established her own research group supported by BMBF, DFG, FCI and Degussa AG. Her research is currently focused on asymmetric organocatalysis, organo-autocatalysis, asymmetric oxidations with non-heme iron complexes, as well as synthesis of natural product hybrids for medicinal chemistry.

研究领域

Asymmetric Organocatalysis and Organo-Autocatalysis, Asymmetric Oxidations with Redox-Active Metal Complexes, Natural Product Hybrids for Medicinal Chemistry

近期论文

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Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: Towards sustainability. A. Fingerhut, O. V. Serdyuk, S. B. Tsogoeva. Green Chem. (Invited Critical Review), 2015, 17, 2042-2058 (View Most Read Articles). Michael Addition of N-unprotected 2-Oxindoles to Nitrostyrene Catalyzed by Bifunctional Tertiary Amines: Crucial role of dispersion interactions. C. Reiter, S. López-Molina, B. Schmid, C. Neiss, A. Görling, S. B. Tsogoeva. ChemCatChem, 2014, 6, 1324-1332. (Featured in Chem. Eur. J. 2014, 19, 7542-7545, SPOTLIGHTS, Highlighted in ChemInform, 2014, Vol. 45, Issue 40). One-pot synthesis of (R)-convolutamydine A involving in situ chiral organocatalyst formation. S.-W. Wei, B. Schmid, F. Z. Macaev, S. N. Curlat, A. V. Malkov, S. B. Tsogoeva. Asymmetric Catal. 2014, 1, 40-45. Synthesis and study of cytotoxic activity of 1,2,4-trioxane- and egonol-derived hybrid molecules against Plasmodium falciparum and multidrug-resistant human leukemia cells. C. Reiter, A. Çapci Karagöz, T. Fröhlich, V. Klein, M. Zeino, K. Viertel, J. Held, B. Mordmüller, S. Emirdağ Öztürk, H. Anil, T. Efferth, S. B. Tsogoeva. Eur. J. Med. Chem., 2014, 75, 403-412 (Among TOP20 Articles in the Domain of Article 24561670, since 2014, BioMedLib), View AudioSlides. One-Pot Route to beta-Adrenergic Blockers via Enantioselective Organocatalysed Epoxidation of Terminal Alkenes as a Key Step. F. E. Held, S.-W. Wei, K. Eder, S. B. Tsogoeva. RSC Advances, 2014, 4, 32796-32801 (Highlighted in ChemInform, 2015, Vol. 46, Issue 8). α-Nitro Epoxides in Organic Synthesis: Development of a One-Pot Organocatalytic Strategy for the Synthesis of Quinoxalines. M. M. Ibrahim, D. Grau, F. Hampel, S. B. Tsogoeva. Eur. J. Org. Chem., 2014, 1401-1405 (Highlighted in ChemInform, 2014, Vol. 45, Issue 48). Bifunctional Primary Amine-Thioureas in Asymmetric Organocatalysis. O. V. Serdyuk, C. M. Heckel, S. B. Tsogoeva. Org. Biomol. Chem. (Invited Perspective) 2013, 11, 7051-7071 (Most accessed 10/2013; Highlighted in ChemInform, 2013, Vol. 44, Issue 52; Among TOP20 Articles in the Domain of Article 24057617, since 2013, BioMedLib). Combining in situ Generated Chiral Silicon Lewis Acid and Chiral Brønsted Acid Catalysts for [3+2] Cycloadditions: Cooperative Catalysis as a Convenient Enantioselective Route to Pyrazolidines. O. V. Serdyuk, A. Zamfir, F. Hampel, S. B. Tsogoeva. Adv. Synth. Catal., 2012, 354, 3115-3121 (Most accessed 10/2012; Highlighted in ChemInform, 2013, Vol. 44, Issue 15). Insights into the spontaneous emergence of enantioselectivity in an asymmetric Mannich reaction carried out without external catalyst. F. E. Held, A. Fingerhut, S. B. Tsogoeva. Tetrahedron: Asymmetry, 2012, 23, 1663-1669 (Most accessed 03/2013). Synthesis and evaluation of new guanidine-thiourea organocatalyst for the nitro-Michael reaction: Theoretical studies on mechanism and enantioselectivity. T. E. Shubina, M. Freund, S. Schenker, T. Clark, S. B. Tsogoeva. Beilstein J. Org. Chem. (Invited Article: Thematic Series "Organocatalysis" edited by B. List), 2012, 8, 1485-1498. Convenient One-Pot Two-Step Synthesis of 1,3-Thiazoles via Organocatalyzed Epoxidation of Nitroolefins. S.-W. Wei, K. M. Weiß, S. B. Tsogoeva, Synthesis (Invited Article: Practical Synthetic Procedures), 2012, 44, 3441-3446. (Highlighted in ChemInform, 2013, Vol. 44, Issue 13). New artesunic acid homodimers: potent reversal agents of multidrug resistance in leukemia cells. C. Reiter, A. Herrmann, A. Çapci, T. Efferth, S. B. Tsogoeva. Bioorg. Med. Chem. 2012, 20, 5637-5641. Asymmetric Vanadium- and Iron-Catalyzed Oxidations: New Mild (R)-Modafinil Synthesis and Formation of Epoxides using aqueous H2O2 as a terminal oxidant. K. A. Stingl, K. M. Weiß, S. B. Tsogoeva, Tetrahedron, 2012, 68, 8493-8501. Asymmetric Synthesis of beta-Adrenergic Blockers via Multi-step One-Pot Transformations involving in situ Chiral Organocatalyst Formation. S.-W. Wei, R. Messerer, S. B. Tsogoeva. Chem. Eur. J. 2011, 17, 14380-14384. (Highlighted in Noteworthy Chemistry, weekly feature by ACS, January 9, 2012; Highlighted in SYNFACTS, 2012 , 8, 238). Assessment of Popular DFT and Semiempirical Molecular Orbital Techniques for Calculating Relative Transition State Energies and Kinetic Product Distributions in Enantioselective Organocatalytic Reactions. S. Schenker, C. Schneider, S. B. Tsogoeva, T. Clark, J. Chem. Theor. Comput., 2011, 7, 3586-3595. L-Proline Catalyzed Asymmetric Michael Addition of 2-Oxindoles to Enones: A Convenient Access to Oxindoles with a Quaternary Stereocenter. M. H. Freund, S. B. Tsogoeva. Synlett: Cluster (Invited Article), 2011, 503-507. Enantioselective Epoxidation of Electron-Deficient Olefins: An Organocatalytic Approach. K. M. Weiß and S. B. Tsogoeva. The Chemical Record (Invited Perspective. Dedicated to Prof. Andreas Hirsch on the occasion of his 50th birthday), 2011, 11, 18-39. (Among Hottest articles in Organic Chemistry. Most accessed 3/2011-11/2012; Highlighted in ChemInform, 2011, Vol. 42, Issue 32; Highlighted in the Editorial: Beyond Borders, Beyond Reviews). Binaphthyl-Derived Mono-, Bi- and Multi-functional Lewis and Brønsted Base Organocatalysts: A New Vista for Asymmetric Synthesis. M. Freund, S. Schenker, A. Zamfir and S. B. Tsogoeva. Curr. Org. Chem. (Invited Review in a Special Issue “Fundamentals in Organocatalysis. Past, Present and Future”), 2011, 15, 2282-2310. "Life’s Single Chirality: Origin of Symmetry Breaking in Biomolecules." M. Mauksch and S. B. Tsogoeva. (Book Chapter in "Biomimetic Organic Synthesis," E. Poupon / B. Nay (Eds.), WILEY-VCH, 2011, Vol. 2, 823-846. Silicon Lewis Acid Catalyzed [3+2] Cycloaddition Reactions of Hydrazones/Cyclopentadiene: Novel Mild Access to Pyrazolidine Derivatives. A. Zamfir, S. Schenker, W. Bauer, T. Clark and S. B. Tsogoeva. Eur. J. Org. Chem., (Invited Communication in a Special Issue: Women in Chemistry, Profiles), 2011, 3706-3709. (Highlighted in ChemInform, 2011, Vol. 42, Issue 49).