个人简介
Andreas Hirsch received his Ph.D. in 1990 from the University of Tübingen. From 1990 to 1991 he was a postdoctoral fellow at the Institute for Polymers and Organic Solids in Santa Barbara, California in the group of Prof. Wudl. He subsequently returned to Tübingen as a research associate at the Institute for Organic Chemistry. Upon receiving his Dr. Habilitus in 1994, for which he was honored with a variety of prizes and awards including the Otto -Röhm Research Award (1994) and the ADUC Award für Habilitanden (1994) he joined the Chemistry Faculty at the University of Karlsruhe as a Professor of Organic Chemistry. Since October 1995, he has been chaired Full Professor of Organic Chemistry at the University of Erlangen-Nürnberg. In 2004 he became Adjunct Professor at Rice University in Houston. He was Visiting Professor at the University of Nikosia in Cyprus (2006) and the University of Padova in Italy (2011). He is coordinator of the Graduate School Molecular Science (GSMS), the Interdisciplinary Center for Molecular Materials (ICMM) and the Collaborative Research Center “Synthetic Carbon Allotropes” (SFB 953) in Erlangen. He is on the Board of Directors of the Cluster of Excellence “Engineering of Advanced Materials” (EAM) in Erlangen and the Central Institute for Materials and Processes (ZMP) in Fürth. In 2006 he received the Elhuyar-Goldschmidt-Prize of the Spanish and German Chemical Societies. In 2007 he was elected Professor of the Year (Unicum, Beruf, Germany). In 2010 he received an ERC Advanced Grant and in 2012 he received the Max Grundig Award and the Medal of the Organic Institute of the Academy of Sciences of the Czech Republic. Hirsch’s laboratory has been pioneering and is at the forefront of carbon allotrope chemistry and is well known for the investigations of basic principles for the functionalization of the 0-dimensional fullerenes, the 1-dimensional carbon nanotubes and the 2-dimensional graphene, which lead to synthesis of numerous examples of derivatives with tailor made structural-, electronic-, photophysical- and biomedical properties.
研究领域
Organic Chemistry
Wir beschäftigen uns mit der Konzeption von neuen Materialien, die wir aus der Kombination verschiedener molekularer Bausteine wie Fullerene, Kohlenstoffnanoröhren, Porphyrine, Dendrimere, Calixarene und Acetylenverbindungen aufbauen. Diese Funktionseinheiten werden gezielt durch kovalente Bindungen oder supramolekulare Organisation miteinander verknüpft. Dabei sind Zielstrukturen von Interesse, die zum Beispiel Modelle für Redoxenzyme darstellen, einen gerichteten photoinduzierten Elektronen- oder Energietransfer ermöglichen, neue mizellare Container für die Aufnahme von Gastmolekülen bilden können, für den Einsatz in der molekularen Elektronik geeignet sind oder als neue redoxaktive Wirkstoffe verwendet werden können. Das Fundament für die erfolgreiche Realisierung solch komplexer Architekturen bilden a) die Entwicklung neuer Synthesemethoden zum Beispiel für chirale und amphiphile Funktionseinheiten sowie für derivatisierte kohlenstoffreiche Moleküle, b) die systematische Erforschung des Selbstaufbaus achiraler und chiraler supramolekularer Überstrukturen, sowie c) die Berechnung von Moleküleigenschaften mit quantenmechanischen Methoden.
近期论文
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C. D. Wessendorf, R. Eigler, S. Eigler, J. Hanisch, A. Hirsch, E. Ahlswede Investigation of pentaarylazafullerenes as acceptor systems for bulk-heterojunction organic solar cells Sol. Energ. Mat. Sol. C. 2015, 132, 450-454
J. Schönamsgruber, A. Hirsch Benz-Bisimidazole-Bridged Perylenes - Linearly Expanded Chromophores European Journal of Organic Chemistry 2015, n/a-n/a
S. Eigler, A. Hirsch Chemistry with Graphene and Graphene Oxide - Challenges for Synthetic Chemists Angewandte Chemie International Edition 2014, 53, 7720-7738
Z. Wang, J. Kirschner, S. Eigler, H. P. Steinrück, C. Jäger, A. Hirsch, T. Clark, M. Halik Driving forces for the self-assembly of graphene oxide on organic monolayers Nanoscale 2014, 6, 11344-11350
L. Wasserthal, B. Schade, K. Ludwig, C. Böttcher, A. Hirsch Hierarchically Ordered Self-Assembly of Amphiphilic Bifullerenes Chem. Eur. J. 2014, 20, 5961-5966
M. Marcia, P. Singh, F. Hauke, M. Maggini, A. Hirsch Novel EDTA-ligands containing an integral perylene bisimide (PBI) core as an optical reporter unit Organic and Biomolecular Chemistry 2014, 12, 7045-7058
A. N. Khlobystov, A. Hirsch Organometallic and coordination chemistry of carbon nanomaterials Dalton Transactions 2014, 43, 7345
S. Eigler, F. Hof, M. Enzelberger-Heim, S. Grimm, P. Müller, A. Hirsch Statistical raman microscopy and atomic force microscopy on heterogeneous graphene obtained after reduction of graphene oxide Journal of Physical Chemistry C 2014, 118, 7698-7704
F. Hof, F. Hauke, A. Hirsch Brominated single walled carbon nanotubes as versatile precursors for covalent sidewall functionalization Chemical Communications 2014, 50, 6582-6584
S. Eigler, A. Hirsch Chemie mit Graphen und Graphenoxid - Eine Herausforderung für Synthesechemiker Angewandte Chemie 2014, 126, 7852-7872
A. Hirsch, A. J. Kratzer, D. Lungerich, J. M. Englert, F. Heinemann, N. Jux FD173: Synthesis and First X-ray Structure of a Hexa-peri-hexabenzocoronene-Fullerene-Dyad: A Model for an Inter-Carbon-Allotrope Hybrid Faraday Discussions 2014, accepted
J. Schönamsgruber, H. Maid, W. Bauer, A. Hirsch Fused Perylene-Phthalocyanine Macrocycles: A New Family of {NIR}-Dyes with Pronounced Basicity Chemistry - A European Journal 2014, 20, 16969-16979
J. Schönamsgruber, L. Zeininger, A. Hirsch Grafting perylenes to ZnO nanoparticles Chemistry - A European Journal 2014, 20, 2529-2536
S. Eigler, S. Grimm, A. Hirsch Investigation of the Thermal Stability of the Carbon Framework of Graphene Oxide Chemistry - A European Journal 2014, 20, 984-989
F. Hof, R. A. Schäfer, C. Weiss, F. Hauke, A. Hirsch Novel $\uplambda$ 3 -Iodane-Based Functionalization of Synthetic Carbon Allotropes ({SCAs})-Common Concepts and Quantification of the Degree of Addition Chemistry - A European Journal 2014, 20, 16644-16651
R. Eigler, F. W. Heinemann, A. Hirsch Selective oxidative conversion of triaryldihydro[C59N]fullerenes: a model case for oxygenation of carbon allotropes Chem. Commun. 2014, 50, 2021-2023
B. Gharib, A. Hirsch Synthesis and characterization of new ferrocene-containing ionic liquids European Journal of Organic Chemistry 2014, 2014, 4123-4136
M. Klaumünzer, C. Münzel, A. Burger, M. Mačković, M. Voigt, E. Spiecker, A. Hirsch, W. Peukert An Effective Dialysis Method for Surface Funtionalization of Nanoparticles in Liquid Phase - Sample: Porphyrine derivatives @ ZnO-Nanorods in: Nanotechnology 2013: Advanced Materials, CNTs, Particles, Films and Composites (Volume 1); Nano Science and Technology Institute 2013, 690-691
S. Eigler, Y. Hu, Y. Ishii, A. Hirsch Controlled Functionalization of Graphene Oxide with Sodium Azide Nanoscale 2013, 5, 12136-12139
A. Gmehling, A. Hirsch Facile Access to Functional Building Blocks of C60 Involving C3-Symmetrical Addition Patterns European Journal of Organic Chemistry 2013, 2013, 5093-5105