个人简介

BS - Chemistry, Spring Hill College AM - Physical Chemistry, Harvard University PhD - Physical Chemistry, Harvard University

研究领域

Kinetics, Combustion

The efforts of our group focus on the quantitative kinetic characterization of reaction networks in a variety of systems of practical importance. These include the reactions that occur in high-temperature solid oxide fuel cells (SOFCs), the ignition kinetics and the catalytic reforming kinetics of fossil and renewable fuels, and the production of fuels and power from the thermochemical conversion of biomass. We focus on the systematic development of detailed kinetic mechanisms where the types of elementary reactions and their rate coefficients are guided by electronic structure calculations. Our approach is to calculate rate coefficients for a series of similar reactions with relatively small molecules (where higher levels of theory can be used) and then to use these results to generate rate rules that will be applicable to this reaction type involving larger species. We are especially interested in predicting the temperature and pressure dependence of the branching ratios of chemically-activated reactions. Our research efforts are funded by the Office of Naval Research, the Air Force Office of Scientific Research, Department of Energy, and the National Renewable Energy Lab.

近期论文

查看导师新发文章 （温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

"Impact Of Gas-Phase Reactions On SOFC Systems Operating On Diesel And Biomass-Derived Fuels" I. Kang, H-H. Carstensen and A. M. Dean, Materials Science Forum, 638-642,1118-1124 (2010). "Selective Removal of Ethylene, a Known Deposit Precursor, from a 'Dirty' Synthesis Gas Stream via Gas-Phase Partial Oxidation", S. M. Villano, J. Hoffmann, H-H. Carstensen, and A.M. Dean, J. Phys. Chem. A, 114, 6502-6514 (2010). "Expanding the Experimental Capabilities of the Ignition Quality Tester (IQT?) for Autoigniting Fuels", G. Bogin Jr, A. M. Dean, M. A. Ratcliff, J. Luecke, B. T. Zigler, SAE World Congress, 2010-01-0741. "Detailed Modeling of Low-temperature Propane Oxidation: 1. The Role of Propyl+O2 Reaction", L. K. Huynh, H-H Carstensen, A. M. Dean, J. Phys. Chem A, 114, 6594-6607 (2010). "Impact of Gas-Phase Reactions in the Mixing Region Upstream of a Diesel Fuel Autothermal Reformer", I. Kang, H-H. Carstensen, and A. M. Dean, J. Power Sources, 196, 2020-2026 (2011). "The Effects of Liquid-Fuel Physical Properties, Carrier-Gas Composition, and Pressure, on Strained Opposed-Flow Non-Premixed Flames", R. J. Kee, K. Yamashita, H. Zhu, and A. M. Dean, Combustion and Flame 158, 1129-1139 (2011). "Direct Detection of Products from the Pyrolysis of 2-Phenethyl Phenyl Ether", M. W. Jarvis, J. W. Daily, H-H. Carstensen, A.M. Dean, S. Sharma, D.C. Dayton, D. J. Robichaud, Mark R. Nimlos, J. Phys. Chem. A, 115, 428-438 (2011). "Kinetic Modeling of Ethane Pyrolysis at High Conversion", C. Xu, A.Shoaibi, C. Wang, H-H. Carstensen, and A. M. Dean, J. Phys. Chem. A, 115, 10470-10490 (2011). "A Quantitative Kinetic Analysis of CO Elimination from Phenoxy Radicals" H-H. Carstensen and A. M. Dean, Int. J. Chemical Kinetics, 44, 75-89 (2012). "High-Pressure Rate Rules for Alkyl + O2 Reactions: Part 1 - The Dissociation, Concerted Elimination, and Isomerization Channels of the Alkyl Peroxy Radical", S. M. Villano, L. K. Huynh, H-H. Carstensen, and A. M. Dean, J. Phys. Chem. A, 115, 13425-13442 (2011). "Effects of Fuel Physicochemical Properties on Autoignition in the Ignition Quality Tester (IQT)", G. E. Bogin Jr, A. DeFilippo, J.Y. Chen, G. Chin, J. Luecke, M. A. Ratcliff, B.T. Zigler, A. M. Dean, Energy Fuels, 25, 5562-5572. (2011). "RCARM: Reaction Classification Using Automated Reaction Mapping" T. M. Kouri, J. D. Crabtree, L. Huynh, A. M. Dean, and D. P. Mehta, Int. J. Chemical Kinetics (in press). "Investigation of Gas-Phase Reactions in the Mixing Region for Hydrocarbon Autothermal Reforming Applications", S. Kim, H-H. Carstensen, A. M. Dean, and J. Bae, Int. J. Hydrogen Energy, 37, 7545-7553 (2012). "High-Pressure Rate Rules for Alkyl + O2 Reactions: Part 2 - The Isomerization, Cyclic Ether Formation, and -Scission Reactions of Hydroperoxy Alkyl Radicals", S. M. Villano, L. K. Huynh, H-H. Carstensen, and A. M. Dean, J. Phys. Chem. A, 116, 5068-5089 (2012). "The effects of multicomponent fuel droplet evaporation on the kinetics of strained opposed-flow diffusion flames," C. Wang, A. M. Dean, H. Zhu, and R. J. Kee, Combust. Flame, 160, 265-275 (2013). "An Ignition Quality Tester (IQT) Investigation of the Negative Temperature Coefficient Region of Alkane Autoignition", Gregory Bogin, Jr., Eric Osecky, Matthew Ratcliff, Jon Luecke, Xin He, Bradley Zigler, and Anthony Dean, Energy Fuel, 27, 1632-1642 (2013). "Simulation Of N-Heptane And Surrogate Fuels For Advanced Combustion Engines (FACE) In A Single-Cylinder Compression Ignition Engine", (ICEF2013-19257) Joseph Taglialegami, Eric Osecky, Gregory Bogin Jr., Gregory Bogin Jr. Proceedings of the ASME 2013 Internal Combustion Engine Division Fall Technical Conference ICEF2013 October 13-16, 2013, Dearborn, Michigan. "Rate Rules, Branching Ratios, and Pressure Dependence of the HO2+Olefin Addition Channels", S. M. Villano, H-H. Carstensen, and A. M. Dean, J. Phys. Chem. A, 117, 6458-6473 (2013). "Insights into the Glycyl Radical Enzyme Active Site of Benzylsuccinate Synthase: A Computational Study", Vivek Bharadwaj, Anthony M. Dean, C. Mark Maupin, J. Am Chem. Soc., 135, 12279-12288 (2013). "Coupled transport and kinetics in the mixing region for hydrocarbon autothermal reforming applications", Sunyoung Kim, Anthony M. Dean, and Joongmyeon Bae, Int. J. Hydrogen Energy, (in press).