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DYNAMIC KINETIC RESOLUTION BIOMIMETIC OXIDATION ORGANO-METALLIC TRANSFORMATIONS DIRECTED EVOLUTION

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A. Guðmundsson and J.-E. Bäckvall, “On the Use of Iron in Organic Chemistry ” Molecules, 2020, 25(6), 1349. C. Zhu, J. Liu, B. K. Mai and J.-E. Bäckvall, ”Efficient Stereoselective Carbocyclization to cis-1,4-Disubstituted Heterocycles Enabled by Dual Pd/Electron Transfer Mediator (ETM) Catalysis” J. Am. Chem. Soc., 2020, Accepted Article (26 February 2020), “DOI: 10.1021/jacs.9b13700”. A.Guðmundsson, K. E. Schlipköter and J.-E. Bäckvall, ”Iron(II)-Catalyzed Aerobic Biomimetic Oxidation of Alcohols” Angew. Chem. Int. Ed. , 2020, 59, Accepted Article (30 January 2020), “DOI: 10.1002/anie.202000054”. M.-B. Li, Y. Yang, A. A. Rafi, M. Oschmann, E. Svensson Grape, A. K. Inge, A.Córdova, and J.-E. Bäckvall, ”Silver Triggering Activity of Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions”, submitted for publication. C. Zhu, J. Liu, B. Khanh Mai, F. Himo, and J.-E. Bäckvall, ”Pd/ETM-Cocatalyzed Stereoselective Carbocyclization of Dienallenes in Aerobic Oxidation”, submitted for publication. V. R. Naidu and J.-E. Bäckvall, ”Synthesis of Cross-Conjugated Polyenes via Palladium-Catalyzed Oxidative C-C Bond Forming Cascade Reactions of Allenes”, submitted for publication. M.-B. Li, D. Posevins, A. Geoffroy, C. Zhu, and J.-E. Bäckvall, “Efficient Heterogeneous Palladium-Catalyzed Oxidative Cascade Reactions of Enallenols to Furan and Oxaborole Derivatives” Angew. Chem. Int. Ed., 2020, 59, 1992. D. Posevins, M.-B. Li, E. Svensson Grape, A. K. Inge, Y. Qiu, and J.-E. Bäckvall, “Highly Diastereoselective Palladium-Catalyzed Oxidative Cascade Carbonylative Carbocyclization of Enallenols” Org. Lett., 2020, 22, 417. C. Zhu, J. Liu, M.-B. Li, and J.-E. Bäckvall, “Palladium-Catalyzed Oxidative Dehydrogenative Carbonylation Reactions Using Carbon Monoxide and Mechanistic Overviews” Chem. Soc. Rev., 2020, 49, 341. K. P. J. Gustafson, A. Guðmundsson, E. Bajnóczi, Ning Yuan, X. Zhou, I. Persson and J.-E. Bäckvall, ”In Situ Structural Determination of a Homogeneous Ruthenium-Catalyst and its Activated Intermediates using X-ray Absorption Spectroscopy” Chem. Eur. J., 2020, 26, Accepted Article (24 January 2020), “DOI: 10.1002/chem.201905479”. M. Diéguez, J.-E. Bäckvall, O. Pámies, Science of Synthesis: Dual Catalysis in Organic Synthesis” Chem. Eur. J., 2019, 2, 161. C. Zhu and J.-E. Bäckvall, “An Efficient Approach to Regio- and Stereodefined Fully-Substituted Alkenylsilanes via Pd-Catalyzed Allenic C(sp3)–H Oxidation” Chem. Eur. J., 2019, 25, 11566. M. Oschmann, C. Placais, A. Nagendiran, J.-E. Bäckvall, O. Verho, “Efficient 1,3-oxazolidin-2-one synthesis through heterogeneous Pd(II)-catalyzed intramolecular hydroamination of propargylic carbamates” Chem. Eur. J., 2019, 25, 6295. M.-B. Li, E. Svensson Grape, and J.-E. Bäckvall, “Palladium-Catalyzed Stereospecific Oxidative Cascade Reaction of Allenes for the Construction of Pyrrole Rings: Control of Reactivity and Selectivity” ACS Catal., 2019, 9, 5184. K. P. J. Gustafson, T. Görbe, G. De Gonzalo, N. Yuan, C. Schreiber, A. Shchukarev, C-W. Tai, I. Persson, X. Zhou, and J.-E. Bäckvall, “Chemoenzymatic Dynamic Kinetic Resolution of Primary Benzylic Amines using Pd0‐CalB CLEA as a Biohybrid Catalyst” Chem. Eur. J., 2019, 25, 9174. J. Löfgren, T. Görbe, M. Oschmann, M. S. Humble, J.-E. Bäckvall, “Transesterification of a tertiary alcohol by engineered Candida antarctica lipase A” ChemBioChem, 2019, 20, 1438. A. Guðmundsson, K. P. J. Gustafson, B. Khanh Mai, B. Yang, F. Himo, and J.-E. Bäckvall, “Diastereoselective Synthesis of N-Protected 2,3-Dihydropyrroles via Iron-Catalyzed Cycloisomerization of α-Allenic Sulfonamides” ACS Catal., 2019, 9, 1733. M.-B. Li, D. Posevins, K. P. J. Gustafson, C.-W. Tai, A. Shchukarev, Y. Qiu, and J.-E. Bäckvall, “Diastereoselective Cyclobutenol Synthesis: A Heterogeneous Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenols” Chem. Eur. J., 2019, 25, 210. J. Liu, A. Ricke, B. Yang and J.-E. Bäckvall, “Efficient Palladium-Catalyzed Aerobic Arylative Carbocyclization of Enallenynes” Angew. Chem. Int. Ed., 2018, 57, 16842. M.-B. Li, A. K. Inge, D. Posevins, K. P. J. Gustafson, Y. Qiu, and J.-E. Bäckvall, “Chemodivergent and Diastereoselective Synthesis of γ-Lactones and γ-Lactams: A Heterogeneous Palladium-Catalyzed Oxidative Tandem Process” J. Am. Chem. Soc., 2018, 140, 14604. M. Diéguez, J.-E. Bäckvall, and O. Pàmies (Editors), “Artificial Metalloenzymes and MetalloDNAzymes in Catalysis” Wiley-VCH, 2018, ISBN: 978-3-527-34178-8.

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