Duttwyler, Simon Lukas - 浙江大学

个人简介

教育经历： 2013年9月：浙江大学化学系任特聘研究员。 2010-2013年：耶鲁大学博士后研究。Rh-介导的C-H活化用于氮杂环化合物的合成。导师: Prof. Jonathan A. Ellman。 2007-2008年：加州大学湖滨分校科学研究。碳硼烷及其活性中间体的合成。导师: Prof. Christopher A. Reed。 2005-2010年：苏黎世大学博士研究生学习。新型硅正离子的发展和应用。导师：Prof. Jay S. Siegel。 2000-2005年：苏黎世大学本科学习。

近期论文

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"Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation" F. Lin,‡ J.-L. Yu,‡ Y. Shen,‡ S.-Q. Zhang, B. Spingler, J. Liu, X. Hong*, Simon Duttwyler* J. Am. Chem. Soc. 2018, DOI: 10.1021/jacs.8b07872. "Rhodium(III)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B–H activation" X. Liang, Y. Shen, K. Zhang, J. Liu, S. Duttwyler* Chem. Commun. 2018, DOI: 10.1039/C8CC05983G. "Rh(III)-Catalyzed Functionalization of closo-Dodecaborates via Selective B–H Activation: Bypassing Competitive C–H Activation " Y. Zhang, T. Wang, L. Wang, Y. Sun, F. Lin, J. Liu, S. Duttwyler* Chem. Eur. J. 2018, DOI: 10.1002/chem.201803455. "Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB11H11]–" Yunjun Shen,‡ Kai Zheng,‡ Rakesh Dontha, Yani Pan, Jiyong Liu and Simon Duttwyler* RSC Adv. 2018, 8, 22447–22451. "The closo-Dodecaborate Dianion Fused with Oxazoles Provides 3D Diboraheterocycles with Selective Antimicrobial Activity" Y. Sun, J. Zhang, Y. Zhang, J. Liu, S. van der Veen*, S. Duttwyler* Chem. Eur. J. 2018, 24, 10364–10371. "Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis" S. Duttwyler* Pure Appl. Chem. 2018, 90, 733–744. "Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks" K. Zhang, Y. Shen, Y. Sun, J. Liu, B. Spingler, S. Duttwyler* Chem. Commun. 2018, 54, 1698–1701. "Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of Isocoumarins via Regioselective B–H Activation" F. Lin, Y. Shen, Y. Zhang, Y. Sun, J. Liu, S. Duttwyler* Chem. Eur. J. 2018, 24, 551–555. "Transition Metal Complexes of a Monocarba-closo-dodecaborate Ligand via B–H Activation" Y. Shen, J. Liu, T. Sattasathuchana, K. K. Baldridge*, S. Duttwyler* Eur. J. Inorg. Chem. 2017, 2017, 4420–4424. "Efficient Bronsted Acid-Catalyzed Deuteration of Arenes and Their Transformation to Functionalized Deuterated Products" X. Liang, S. Duttwyler* Asian J. Org. Chem. 2017, 6, 1063–1071. "B–H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis" Y. Shen, Y. Pan, K. Zhang, X. Liang, J. Liu, B. Spingler, S. Duttwyler* Dalton Trans. 2017, 46, 3135–3140. "Synthesis and Full Characterization of an Iridium B–H Activation Intermediate of the Monocarba-closo-dodecaborate Anion" Y. Shen, Y. Pan, J. Liu, T. Sattasathuchana, K. K. Baldridge*, S. Duttwyler* Chem. Commun. 2017, 53, 176–179. "Rh(III)-Catalyzed Room Temperature Alkenylation–Annulation of closo-Dodecaborate Anions via Double B-H Activation" Y. Zhang, Y. Sun, F. Lin, J. Liu, S. Duttwyler* Angew. Chem. Int. Ed. 2016, 55, 15609–15614. "Facile synthesis of enantioenriched phenol-sulfoxides and their aluminum complexes" Y. Tang, Y. Sun, J. Liu, S. Duttwyler* Org. Biomol. Chem. 2016, 14, 5580–5585. "Synthesis and Structural Characterization of Ammonio/Hydroxo Undecachloro-closo-dodecaborates [B12Cl11(NH3)]–/[B12Cl11(OH)]2– and Their Derivatives" Y. Zhang, J. Liu, S. Duttwyler* Eur. J. Inorg. Chem. 2015, 2015, 5158. "Synthesis of ent-Ketorfanol via a C–H Alkenylation/Torquoselective 6pi Electrocyclization Cascade" E. M. Phillips, T. Mesganaw, A. Patel, S. Duttwyler, B. Q. Mercado, K. N. Houk*, J. A. Ellman* Angew. Chem. Int. Ed. 2015, 54, 12044–12048. "Cu(I) and Ag(I) Complexes of 7,10-bis-N-heterocycle-diazafluoranthenes: Programmed Molecular Grids?" N. Rahanyan, S. Duttwyler, A. Linden, K. Baldridge*, J. S. Siegel* Dalton Trans. 2014, 43, 11027. "Regio- and Stereoselective 1,2-Dihydropyridine Alkylation/Addition Sequence for the Synthesis of Piperidines with Quaternary Centers" S. Duttwyler, S. Chen, C. Lu, R. G. Bergman*, J. A. Ellman* Angew. Chem Int. Ed. 2014, 53, 3877. "Through-Space Interactions in Enshrouded meta-Terphenylsilanes" S. Duttwyler, P. Romanato, A. Linden, K. K. Baldridge*, J. S. Siegel* J. Phys. Org. Chem. 2014, 27, 277. "Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis" S. Duttwyler, S. Chen, M. K. Takase, K. B. Wiberg, R. G. Bergman* J. A. Ellman*, Science 2013, 339, 678. "Arenium Acid Catalyzed Deuteration of Aromatic Hydrocarbons" S. Duttwyler, A. Butterfield, J. S. Siegel* J. Org. Chem. 2013, 78, 2134. "Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade" S. Duttwyler, C. Lu, A. L. Rheingold, R. G. Bergman*, J. A. Ellman* J. Am. Chem. Soc. 2012, 134, 4064. "Competition Between π-Arene and Lone Pair-Halogen Coordination of Silylium Ions?" P. Romanato, S. Duttwyler, A. Linden, K. K. Baldridge*, J. S. Siegel* J. Am. Chem. Soc. 2011, 133, 11844. "Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes" O. Allemann, S. Duttwyler, P. Romanato, K. K. Baldridge*, J. S. Siegel* Science 2011, 332, 574. "C-F Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity" S. Duttwyler, C. Douvris, N. L. P. Fackler, F. S. Tham, C. A. Reed*, K. K. Baldridge*, J. S. Siegel* Angew. Chem. Int. Ed. 2010, 49, 7519. "Intramolecular Halogen Stabilization of Silylium Ions Directs Gearing Dynamics" P. Romanato, S. Duttwyler, A. Linden, K. K. Baldridge*, J. S. Siegel* J. Am. Chem. Soc. 2010, 132, 7828. "Synthesis and Crystal Structure of a Silyl-Stabilized Allyl Cation Formed by Disruption of an Arene by a Protonation-Hydrosilylation Sequence"S. Duttwyler, Y. Zhang, A. Linden, C. A. Reed, K. K. Baldridge*, J. S. Siegel* Angew. Chem. Int. Ed. 2009, 48, 3787. "Synthesis of 2,6-Diarylphenyldimethylsilyl Cations: Polar-p Distribution of Cationic Character"S. Duttwyler, Q. Do, A. Linden, K. K. Baldridge*, J. S. Siegel* Angew. Chem. Int. Ed. 2008, 47, 1719.

个人简介

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近期论文