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个人简介

Hong-Cai “Joe” Zhou obtained his Ph.D. in 2000 from Texas A&M University under the supervision of F. A. Cotton. After a postdoctoral stint at Harvard University with R. H. Holm, he joined the faculty of Miami University, Oxford in 2002. He was promoted to a full professor within six years by working on the preparation and application of Metal-Organic Frameworks (MOFs), a field he had had no prior experience in as a graduate student or postdoctoral fellow. He moved to Texas A&M University in 2008, was promoted to a Davidson Professor of Science in 2014, and was appointed the Robert A. Welch Chair in Chemistry in 2015. In June 2013, he started to serve as an associate editor for Inorganic Chemistry (ACS). In 2014, he received a JSPS Invitation Fellowship. In 2014, 2015, and 2016, he was listed as a Highly Cited Researcher by Thomson Reuters, and in 2016 he was elected a fellow of the AAAS, ACS, and RSC. In 2017 he was given the Distinguished Achievement award in research by TAMU's Association of Former Students. He was honored with the Humboldt Foundation's Carl Friedrich Von Siemens Research Award in 2022. Education 1989 Beijing Normal University, Beijing, China, BS and MS 2000 Texas A&M University, College Station, PhD (Advisor: F. A. Cotton) Professional Experience 2015-present Robert A. Welch Chair, Dept. of Chem. Texas A&M University, College Station, TX 2014 – 2015 Davidson Professor, Dept. of Chem. Texas A&M University, College Station, TX 2008 - Present Professor, Dept. of Chem. Texas A&M University, College Station, TX 2007 - 08 Associate Professor, Dept. of Chem. and Biochem. Miami University, Oxford, OH 2002 - 07 Assistant Professor, Dept. of Chem. and Biochem. Miami University, Oxford, OH 2000 - 02 Postdoctoral Fellow, Advisor: R. H. Holm, Dept. of Chem./Chem. Biol. Harvard University, Cambridge, MA 1996 - 00 Research Assistant, Dept. of Chem. Texas A&M University, College Station, TX 1994 - 96 Lecturer, Dept. of Chem. Beijing Normal University, Beijing, P. R. China 1989 - 94 Teaching Assistant, Dept. of Chem. Beijing Normal University, Beijing, P. R. China

研究领域

Gas Storage Gas Separation Catalysis Biological Integration Developing a Synthetic Toolkit for Porous Materials Large Scale Application of Porous Materials

近期论文

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Integrating Photoactive Ligands into Crystalline Ultrathin 2D Metal–Organic Framework Nanosheets for Efficient Photoinduced Energy Transfer Lin, H.; Yang, Y.; Diamond, B. G.; Yan, T.-H.; Bakhmutov, V. I.; Festus, K. W.; Cai, P.; Xiao, Z.; Leng, M.; Afolabi, I.; Day, G. S.; Fang, L.; Hendon, C. H.; and Zhou, H.-C., J. Am. Chem. Soc., 2024, 146 (2), 1491-1500. DOI: 10.1021/jacs.3c10917 Bridging Homogeneous and Heterogeneous Catalysis: Phosphine-Functionalized Metal-Organic Frameworks Chen, W.; Cai, P.; Zhou, H.-C.; and Madrahimov, S. T., Angew. Chem. Int. Ed., 2024, e202315375. DOI: 10.1002/anie.202315075 Investigating the Cell Entry Mechanism, Disassembly, and Toxicity of the Nanocage PCC-1: Insights into Its Potential as a Drug Delivery Vehicle Xiao, Z.; Lin, H.; Drake, H. F.; Diaz, J.; Zhou, H.-C.; and Pellois, J.-P., J. Am. Chem. Soc., 2023, 145 (50), 27690-27701 . DOI: 10.1021/jacs.3c09918 Surface-modified gold-coated superparamagnetic iron oxide nanoparticles promoting light-controlled drug release Yan, T.-H.; Yuan, M.; Nguyen, N.; Chen, J.; Feng, X.; Fan, T.; Harnett, M. C.; Xiao, Z.; Li, Y.; Pellois, J.-P.; Zhou, H.-C.; and Wang, Y., Adv Compos Hybrid Mater, 2023, 6, 226. DOI: 10.1007/s42114-023-00811-4 Diversity Oriented Synthesis of Metal-Organic Frameworks Hsu, Y.-C.; Wang, K.-Y.; Tan, K.; Powell, J. A.; and Zhou, H.-C., Adv. Mats. for Multidisciplinary Apps., 2023, 191-211. DOI: 10.1007/978-3-031-39404-1_7 Interaction of methanol with a layered α-Sn(IV) phosphate on its surface: A solid-state NMR study Bakhmutov, V. I.; Elliott, D. W.; Lin, H.; and Zhou, H.-C., Science Direct, 2023, 555, 121597. DOI: 10.1016/j.ica.2023.121597 Designing multivariate porphyrin-based metal-organic frameworks with Ni/Co dual-metal atom sites for cooperative NO2 capture and NO retention Shang, S.; Yang, C.; Tian, Y.; Tao, Z.; Smith, M.; Zhang, H.; Zhangh, L.; Li, L.; Gu, Q.; Zhou, H.-C.; Ok, Y. S.; and Shang, J., Science Direct, 2023, 320, 124080. DOI: 10.1016/j.seppur.2023.124080 Aluminum metal–organic frameworks: From structures to applications Fan, W.; Wang, K.-Y.; Welton, C.; Feng, L.; Wang, X.; Liu, X.; Li, Y.; Kang, Z.; Zhou, H.-C.; Wang, R.; and Sun, D., Science Direct, 2023, 489, 215175. DOI: 10.1016/j.ccr.2023.215175 Exploitation of MOF decomposition mechanisms to tailor MOF-derived carbon structure in mono- and multimetallic PCN-250 Powell, J. A.; Lin, H.; Hsu, Y.-C.; Young, D. E.; and Zhou, H.-C., Chem Rxiv, 2023. DOI: 10.26434/chemrxiv-2023-gx55c-v3 Magnetically Induced Binary Ferrocene with Oxidized Iron Ullah, S.; Jensen, S.; Liu, Y.; Tan, K.; Drake, H.; Zhang, G.; Huang, J.; Klimes, J.; Driscoll, D. M.; Hermann, R. P.; Zhou, H.-C.; and Thonhauser, T., J. Am. Chem. Soc., 2023, 145 (32), 18029-18035. DOI: 10.1021/jacs.3c05754 Modeling the Enzyme Specificity by Molecular Cages through Regulating Reactive Oxygen Species Evolution Yuan, J.-P.; Guan, Z.-J.; Lin, H.-Y.; Yan, B.; Liu, K.-K.; Zhou, H.-C.; and Fang, Y., Angew. Chem. Int. Ed., 2023, 62 (31), e202303896. DOI: 10.1002/anie.202303896 Yolk–Shell and Hollow Zr/Ce-UiO-66 for Manipulating Selectivity in Tandem Reactions and Photoreactions He, H.-H.; Yuan, J.-P.; Cai, P.-Y.; Wang, K.-Y.; Feng, L.; Kirchon, A.; Li, J.; Zhang, L.-L.; Zhou, H.-C.; and Fang, Y., J. Am. Chem. Soc., 2023,145 (31), 17164-17175. DOI: 10.1021/jacs.3c03883 Spin diffusion in the Phosphorus-31 NMR relaxation in a layered crystalline α-Sn(IV) phosphate contaminated by paramagnetic impurities Bakhmutov, V. I.; Elliott, D. W.; Bhuvanesh, N.; Zhou, H.-C., Solid State Nucl. Magn. Reson. Chem., 2023, 126, 101875. DOI: 10.1016/j.ssnmr.2023.101875 Tailoring chirality and porosity in metal-organic frameworks for efficient enantioselective recognition Han, Z.; Wang, K.-Y.; Wang, M; Sun, T.; Xu, J.; Zhou, H.-C.; Cheng, P.; Shi, W., Chem, 2023, 9(9), 2561-2572. DOI: 10.1016/j.chempr.2023.05.004 Engineered MOF-Enzyme Nanocomposites for Tumor Microenvironment-Activated Photodynamic Therapy with Self-Luminescence and Oxygen Self-Supply Hu, L.; Xiong, C.; Zou, J.-J.; Chen, J.; Lin, H.; Dalgarno, S. J.; Zhou, H.-C.; and Tian, J., ACS Appl. Mat. Inter., 2023, 15 (21), 25369-25381. DOI: 10.1021/acsami.3c02929 Preparation and Quantitative Analysis of Multicenter Luminescence Materials for Sensing Function Han, Z.; Wang, K.-Y.; Zhou, H.-C.; Cheng, P.; and Shi, W., Nat. Protoc., 2023,18, 1621–1640. DOI: 10.1038/s41596-023-00810-1 Ortho Effects of Tricarboxylate Linkers in Regulating Topologies of Rare-Earth Metal–Organic Frameworks Li, F.; Wang, K.-W.; Liu, Z.; Han, Z.; Kuai, D.; Fan, W.; Feng, L.; Wang, Y.; Wang, X.; Li, Y.; Yang, Z.; Wang, R.; Sun, D.; and Zhou, H.-C., JACS Au, 2023, 3 (5), 1337-1347. DOI: 10.1021/jacsau.2c00635 Facile and Scalable Synthesis of Metal- and Nitrogen-Doped Carbon Nanotubes for Efficient Electrochemical CO2 Reduction Gang, Y.; Pellessier, J.; Du, Z.; Fang, S.; Fang, L.; Pan, F.; Suarez, M.; Hambleton, K.; Chen, F.; Zhou, H.-C.; Li, T.; Hu, Y. H.; and Li, Y.; ACS Susta. Chem. Eng., 2023, 11 (18), 7231-7243. DOI: 10.1021/acssuschemeng.3c01222 Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis Wang, K.-Y.; Zhang, J.; Hsu, Y.-C.; Lin, H.; Han, Z.; Pang, J.; Yang, Z.; Liang, R.-R.; Shi, W.; and Zhou, H.-C., J. Am. Chem. Soc., 2023, 123 (9), 5347-5420. DOI: 10.1021/acs.chemrev.2c00879 Synthesis of Fluoro-Bridged Ho3+ and Gd3+ 1,3,5-Tris(4-carboxyphenyl)benzene Metal–Organic Frameworks from Perfluoroalkyl Substances Sheybani, S.; Abbas, M.; Firouzi, H. R.; Xiao, Z.; Zhou, H.-C. and Balkus, K. J. Jr, Inorg. Chem., 2023, 62 (10), 4314-4321. DOI: 10.1021/acs.inorgchem.2c04470 Monitoring the Activation of Open Metal Sites in [FexM3–x(μ3-O)] Cluster-Based Metal–Organic Frameworks by Single-Crystal X-ray Diffraction Chen, W.; Wang, Z.; Wang, Q.; El-Yanboui, K.; Tan, K.; Barkholtz, H. M.; Liu, D.-J.; Cai, P.; Feng, L.; Li, Y.; Qin, J.-S.; Yuan, S.; Sun, D.; and Zhou, H.-J., J. Am. Chem. Soc., 2023, 145 (8), 4736-4745. DOI:10.1021/jacs.2c13299 Metal-Organic Frameworks for Water Harvesting and Concurrent Carbon Capture: A Review for Hygroscopic Materials Lin, H.; Yang, Y.; Hsu, Y.-C.; Zhang, J.; Welton, C.; Afolabi, I.; Loo, M.; Zhou, H.-C., Adv. Mater., 2023, Accepted Article, e2209073. DOI:10.1002/adma.202209073 Revisiting Competitive Adsorption of Small Molecules in the Metal–Organic Framework Ni-MOF-74 Pandey, H.; Wang, H.; Feng, L.; Wang, K.-Y.; Zhou, H.-C.; Li, J.; Thonhauser, T.; Tan, K., Inorg. Chem., 2023, 62 (2), 950-956. DOI:10.1021/acs.inorgchem.2c03751 Creating Hierarchical Pores in Metal–Organic Frameworks via Postsynthetic Reactions Wang, K.-Y.; Yang, Z.; Zhang, J.; Banerjee, S.; Joseph, E. A.; Hsu, Y.-C.; Yuan, S.; Feng, L.; Zhou, H.-C., Nat. Protoc., 2023, 18, 604-625. DOI:10.1038/s41596-022-00759-7 Acidic Centers on the Surface of a Crystalline α-Sn(IV) Phosphate Characterized by the Solid-State 1H, 2H, 31P, and 119Sn MAS NMR Techniques Bakhmutov, V. I.; Elliott, D. W.; Contreras-Ramirez, A.; Drake, H.; Zhou, H.-C., Inorg. Chem., 2022, 61 (44), 17759-17766. DOI:10.1021/acs.inorgchem.2c03047 Photoinduced Reversible Phase Transition in a Phenothiazine-Based Metal-Organic Framework Xiao, Z.; Drake, H. F.; Day, G. S.; Kuszynski, J. E.; Lin, H.; Xie, H.; Cai, P.; Ryder, M. R.; Zhou, H.-C., Cell Rep. Phys. Sci., 2022, 3 (10), 101074. DOI:10.1016/j.xcrp.2022.101074 Assembling Phenothiazine into a Porous Coordination Cage to Improve Its Photocatalytic Efficiency for Organic Transformations Lin, H.; Xiao, Z.; Le, K. N.; Yan, T.-H.; Cai, P. Yang, Y.; Day, G. S.; Drake, H. F.; Xie, H.; Bose, R.; Ryan, C. A.; Hendon, C. H.; Zhou, H.-C., Angew. Chem. Int. Ed., 2022, 61 (49), e202214055. DOI:10.1002/anie.202214055 Three-Dimensional Covalent Organic Frameworks with she Topology Xu, X.; Cai, P. Chen, H.; Zhou, H.-C.; Huang, N., J. Am. Chem. Soc., 2022, 144 (40), 18511-18517. DOI:10.1021/jacs.2c07733 On Phosphorus Chemical Shift Anisotropy in Metal (IV) Phosphates and Phosphonates: A 31P NMR Experimental Study Bakhmutov, V. I.; Contreras-Ramirez, A.; Drake, H.; Zhou, H.-C., Magn. Reson. Chem., 2022, 61 (1), 16-21. DOI:10.1002/mrc.5313 Organo-Macrocycle-Containing Hierarchical Metal–Organic Frameworks and Cages: Design, Structures, and Applications Liang, Y.; Li, E.; Wang, K.; Guan, Z.-J.; He, H.-h.; Zhang. L.; Zhou, H.-C.; Huang, F.; Fang, Y., Chem. Soc. Rev., 2022, 51 (19), 8378-8405. DOI:10.1039/D2CS00232A Competitive Adsorption of NH3 and H2O in Metal–Organic Framework Materials: MOF-74 Tan, K.; Ullah, S.; Pandey, H.; Cedeño-Morales, E. M.; Wang, H.; Wang, K.; Zhou, H.-C.; Li, J.; Thonhauser, T., Chem. Mater., 2022, 34 (17), 7906-7915. DOI:10.1021/acs.chemmater.2c01637 A Scalable Solid-State Nanoporous Network with Atomic-Level Interaction Design for Carbon Dioxide Capture Mao, H.; Tang, J.; Day, G. S.; Peng, Y.; Wang, H.; Xiao, X.; Yang, Y.; Jiang, Y.; Chen, S.; Halat, D. M.; Lund, A.; Lv, X.; Zhang, W.; Yang, C.; Lin, Z.; Zhou, H.-C.; Pines, A.; Cui, Y.; Reimer, J. A., Sci. Adv., 2022, 8 (31), 7906-7915. DOI:10.1126/sciadv.abo6849 Integrated Photocatalytic Reduction and Oxidation of Perfluorooctanoic Acid by Metal−Organic Frameworks: Key Insights into the Degradation Mechanisms Wen, Y.; Renteria-Gomez, A.; Day, G. S.; Smith, M. F.; Yan, T.-H.; Ozdemir, R.; Gutierrez, O.; Sharma, V. K.; Ma, X.; Zhou, H.-C., J. Am. Chem. Soc., 2022, 144 (26), 11840-11850. DOI:10.1021/jacs.2c04341 Linker Scissoring Strategy Enables Precise Shaping of Metal–Organic Frameworks for Chromatographic Separation Xu, M.; Cai, P.; Meng, S.-S.; Yang, Y.; Zheng, D.-S.; Zhang, Q.-H.; Gu, L.; Zhou, H.-C.; Gu, Z.-Y., Angew. Chem. Int. Ed., 2022, Early View, e202207786. DOI:10.1002/anie.202207786 Structural Manipulation of a Zirconocene-Based Porous Coordination Cage Using External and Host–Guest Stimuli Xiao, Z.; Drake, H. F.; Rezenom, Y. H.; Cai, P.; Zhou, H.-C., Small Struct., 2022, Early View, 2100133. DOI:10.1002/sstr.202100133 Metal-Organic Framework-Based Nanoheater with Photo-Triggered Cascade Effects for On-Demand Suppression of Cellular Thermoresistance and Synergistic Cancer Therapy Zhu, Y.; Huang, Y.; Yan, T.-H.; Li, J.; Li, Y.; Drake, H. F.; Zhong, H.; Jin, Y.; Zhao, R.; Zhou, H.-C., Adv. Healthcare Mater., 2022, Early View, 2200004. DOI:10.1002/adhm.202200004 Superparamagnetic iron oxide-enclosed hollow gold nanostructure with tunable surface plasmon resonances to promote near-infrared photothermal conversion Yuan, M.; Feng, X.; Yan, T.-H.; Chen, J.; Ma, X.; Cunha, P.; Lan, S.; Li, Y.; Zhou, H.-C.; Wang, Y., Adv Compos Hybrid Mater, 2022. DOI:10.1007/s42114-022-00444-z Elucidating structure and dynamics of crystalline α-zirconium phosphates intercalated with water and methanol by multinuclear solid-state MAS NMR: A comprehensive NMR approach Bakhmutov, V. I.; Contreras-Ramirez, A.; Drake, H.; Zhou, H.-C., Magn Reson Chem, 2022, 60 (6), 541-553. DOI:10.1002/mrc.5262 Influence of Metal Identity on Light-Induced Switchable Adsorption in Azobenzene-Based Metal–Organic Frameworks Drake, H. F.; Xiao, Z.; Day, G. S.; Vali, S. W.; Daemen, L. L.; Cheng, Y.; Cai, P.; Kuszynski, J. E.; Lin, H.; Zhou, H.-C., ACS Appl. Mater., 2022, Article ASAP. DOI:10.1021/acsami.1c18266 Unexpected Structural/Motional Mode of Water Intercalated into an α-Crystalline Zirconium Phosphate Deduced by 31P and 2H Solid-State MAS NMR Spectra Bakhmutov, V. I.; Contreras-Ramirez, A.; Banerjee, S.; Zhou, H.-C., Magn Reson Chem., 2022, 60 (2), 189-195. DOI:10.1002/mrc.5225 Homogeneously Mixing Different Metal–Organic Framework Structures in Single Nanocrystals through Forming Solid Solutions Xu, M.; Meng, S.-S.; Cai, P.; Gu, Y.-H.; Yan T.-A.; Yan T.-H.; Zhang, Q.-H.; Gu, L.; Zhou, H.-C.; Gu, Z.-H., ACS Cent. Sci., 2022, 8 (2), 184-191. DOI:10.1021/acscentsci.1c01344 Enhancing the photothermal conversion of tetrathiafulvalene-based MOFs by redox doping and plasmon resonance Su, J.; Cai, P.; Yan T.; Yang, Z.-M.; Yuan, S.; Zuo, J.-L.; Zhou, H.-C., Chem. Sci., 2022, 13 (6), 1657-1664. DOI:10.1039/D1SC07001K Reactive High-Valent Iron Intermediates in Enhancing Treatment of Water by Ferrate Sharma, V. K.; Feng, M.; Dionysiou, D. D.; Zhou, H.-C.; Jinadatha, C.; Manoli, K.; Smith, M.; Luque, R.; Ma, X.; Huang, C.-H., Environ. Sci. Technol., 2022, 56 (1), 30-47. DOI:10.1021/acs.est.1c04616 Light-induced switchable adsorption in azobenzene- and stilbene-based porous materials Drake, H. F.; Day, G. S.; Xiao, Z.; Zhou, H.-C.; Ryder, M. R., Trends Chem., 2022, 4 (1), 32-47. DOI:10.1016/j.trechm.2021.11.003

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