谢劲 - 南京大学 - 配位化学国家重点实验室

个人简介

2020/01 - Present Professor School of Chemistry & Chemical Engineering, Nanjing University 2017/07 - 2019/12 Associate Professor School of Chemistry & Chemical Engineering, Nanjing University 2014/03 - 2017/03 Postdoctoral research associate Organisch-Chemisches Institut, Heidelberg University (With Prof. A. Stephen K. Hashmi) 2013/06 - 2014/02 Research associate School of Chemistry & Chemical Engineering, Nanjing University (With Prof. Chengjian Zhu) 2011/06 - 2013/06 PhD School of Chemistry & Chemical Engineering, Nanjing University (Supervisor: Prof. Chengjian Zhu) 2008/09 - 2011/05 Master study (without degree) School of Chemistry & Chemical Engineering, Nanjing University (Supervisor: Prof. Zhizhen Huang) 2004/09 - 2008/09 Bachelor Material Science & Engineering College, Northeast Forestry University

研究领域

Own group aims to construct molecular structure and discover their reactivity that can contribute to interdisciplinary solutions for the important challenges in science. We have a fundamental interest in developing innovative synthetic strategies for potential applications. Particularly, we focus on efficient & green synthetic methodology development, complex molecule synthesis, and mechanistic studies to develop practical access to molecules of interest in catalysis, medicine, and organic materials. Currently, we are interested in developing synergistic catalysis effect in organic synthesis. It represents a rationally design innovative catalytic solutions to improve our access to molecular sciences.

近期论文

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Siyu Xia, Weipeng Li, Hongliang Chen, Chengjian Zhu, Jie Han, Jin Xie*, Gold-Manganese Bimetallic Redox Coupling with Light. J. Am. Chem. Soc. 2023, ASAP Jun Huang,‡ Qi Gao,‡ Tao Zhong, Shuai Chen, Wei Lin, Jie Han*, Jin Xie*, Photoinduced Copper-Catalyzed C–N Coupling with Trifluoromethylated Arenes.Nat. Commun. 2023, Accepted. Meiling Ding,Sitian Zhou, Shunruo Yao, Chengjian Zhu, Weipeng Li,* and Jin Xie*,, Decarboxylative amination with nitroarenes via synergistic catalysis. Chin. J. Chem. 2023, ASAP. Duan-Yang Liu,† Jie Han,† Kai Liu, Yaohang Cheng, Hairen Tan, Xiaoliang Yang, Weipeng Li, Jin Xie*, Dinuclear Gold-Catalyzed para-Selective C-H Arylation of Undirected Arenes by Noncovalent Interactions.Angew. Chem. Int. Ed. Under Revision. Chuan-Gang Zhao,† Chaoyu Du,† Zhenyu Guo, Weipeng Li, Jie Han, Jin Xie*, Merging Manganese and Iminium Catalysis: Selective Hydroalkenylation of Unsaturated Aldehydes and Ketones. Angew. Chem. Int. Ed. 2023, 62, e202312414. Jie Han, Jin Xie*, Inner-Sphere Single Electron Transfer in Polynuclear Gold Photocatalysis. ChemCatChem 2023, 15, e202300974. Tao Zhong, Chengyihan Gu, Yuhang Li, Jun Huang, Jian Han, Chengjian Zhu, Jie Han, Jin Xie*, Manganese/Cobalt Bimetallic Relay Catalysis for Divergent Dehydrogenative Difluoroalkylation of Alkenes. Angew. Chem. Int. Ed. 2023, 62, e202310762. Congjun Zhu, Shunruo Yao, Jin Xie*, Visible-light-enabled radical alkynylborylation of a,b-unsaturated alkenes. Synthesis 2023, Under Revision. Cheng-Long Ji, Xinyi Zhai, Qing-Yun Fang, Chengjian Zhu, Jie Han and Jin Xie*, Photoinduced Activation of Alkyl Chlorides. Chem. Soc. Rev. 2023, 52, 6120-6138. Yubo Pang,† Shuai Chen,† Jie Han,† Chengjian Zhu, Chuan-Gang Zhao and Jin Xie*, Dimeric Manganese-Catalyzed Hydroalkenylation of Alkynes with a Versatile Silicon-Based Directing Group. Angew. Chem. Int. Ed. 2023, 62, e202306922. Weipeng Li,‡ Yu Chen,‡ Yinghan Chen,‡ Siyu Xia, Wenju Chang, Chengjian Zhu, K. N. Houk,* Yong Liang* and Jin Xie*, Site-selective arylation of carboxamides from unprotected peptides. J. Am. Chem. Soc. Accepted Jiajun Li,‡ Xinyi Zhai,‡ Cheng-Long Ji, Weipeng Li, and Jin Xie*, Dinuclear gold-catalyzed cyclization of 1,7-enynes with alkyl bromides. Chem. Commun. 2023, DOI: 10.1039/D3CC02317F. Qing-Yun Fang,† Jie Han,† Mingzhe Qin, Weipeng Li, Chengjian Zhu, and Jin Xie*, Trinuclear Gold-Catalyzed 1,2-Difunctionalization of Alkenes. Angew. Chem. Int. Ed. 2023, 62, e202305121. Lili Zhang, Yuhang Li, Zhenyu Guo, Yantao Li, Nian Li, Weipeng Li*, Chengjian Zhu*, Jin Xie*, Photoredox Deoxygenative Allylation of Carboxylic Acids via Selective 1,6-Addition of Acyl Radicals to Electron-Deficient 1,3-Dienes.Chin. J. Catal. Accepted. Wenliang Wang, Meiling Ding, Chuan-Gang Zhao, Shuai Chen, Chengjian Zhu, Jie Han, Weipeng Li and Jin Xie*, Unlocking Migratory Insertion in Gold Redox Catalysis. Angew. Chem. Int. Ed. 2023, 62, e202304019. Shangwen Fang, Jie Han, Chengjian Zhu, Weipeng Li and Jin Xie*, Gold-Catalyzed Four-Component Multifunctionalization of Alkynes. Nat. Commun. 2023, 14, 3551. [s41467-023-39243-5.pdf] Tiantian Li,† Jian Xu,† Renxing Lin, Sam Teale, Hongjiang Li, Zhou Liu, Chenyang Duan, Qian Zhao, Ke Xiao, Pu Wu, Bin Chen, Sheng Jiang, Shaobing Xiong, Haowen Luo, Sushu Wan, Ludong Li, Qinye Bao, Yuxi Tian, Xueping Gao, Jin Xie, Edward H. Sargent* and Hairen Tan*, Inorganic wide-bandgap perovskite subcells with dipole bridge for all-perovskite tandems. Nat. Energy 2023, DOI:10.1038/s41560-023-01250-7. Mingfei Xiao, Xinglong Ren*, Kangyu Ji, Sein Chung, Xiaoyu Shi, Jie Han, Zefan Yao, Xudong Tao, Szymon J. Zelewski, Mark Nikolka, Youcheng Zhang, Zhilong Zhang, Zichen Wang, Nathan Jay, Ian Jacobs, Weijing Wu, Han Yu, Yarjan Abdul Samad, Sam Stranks, Boseok Kang, Kilwon Cho, Jin Xie, He Yan*, Shangshang Chen*, Henning Sirringhaus*, Achieving ideal transistor characteristics in conjugated polymer semiconductors. Sci. Adv. 2023, 9, eadg8659. Cheng-Long Ji,† Jie Han,† Tingrui Li, Chuan-Gang Zhao, Chengjian Zhu and Jin Xie*, Photoinduced Gold-Catalyzed Divergent Dechloroalkylation of gem-Dichloroalkanes. Nat. Catal. 2022, 5, 1098-1109 Tingrui Li, Yilitabaier Julaiti, Xiaopeng Wu, Jie Han, Jin Xie*, Gold-catalyzed Divergent Ring-Opening Rearrangement of Cyclopropenes Enabled by Dichotomous Gold-Carbenes.Chem. Eur. J. 2022, 28, e2022028 Siyu Xia and Jin Xie*, Energy transfer in gold photocatalysis. Gold Bulletin 2022, 55, 123-127. Nian Li, Yantao Li, Xiaopeng Wu, Chengjian Zhu and Jin Xie*, Radical deuteration. Chem. Soc. Rev. 2022, 51, 6291-6306. Xiaopeng Wu, Jinhang Li, Siyu Xia, Chengjian Zhu* and Jin Xie*, Nickel-Catalyzed Thioester Transfer Reaction with sp2-Hybridized Electrophiles. J. Org. Chem. 2022, 87, 10003-10017. Jin Wen, Yicheng Zhao, Zhou Liu, Han Gao, Renxing Lin, Sushu Wan, Chenglong Ji, Ke Xiao, Yuan Gao, Yuxi Tian, Jin Xie, Christoph J. Brabec and Hairen Tan*, Steric Engineering Enables Efficient and Photostable Wide-Bandgap Perovskites for All-Perovskite Tandem Solar Cells. Adv. Mat. 2022, 2110356. Jian Han,† Jie Han,† Shuai Chen, Tao Zhong, Yijie He, Xianli Yang, Guoqiang Wang, Chengjian Zhu and Jin Xie*, Photoinduced manganese-catalyzed hydrofluorocarbofunctionalization of alkenes. Nat. Synth. 2022, 1, 475-486. Nian Li, Jinhang Li, Mingzhe Qin, Jiajun Li, Jie Han, Chengjian Zhu* Weipeng Li,* and Jin Xie*, Highly Selective Single and Multiple Deuteration of Unactivated C(sp3)-H Bonds. Nat. Commun.2022, 13, 4424. Shuaishuai Wang, Tingrui Li, Chengyihan Gu, Jie Han, Chuan-Gang Zhao, Chengjian Zhu*, Hairen Tan and Jin Xie*, Decarboxylative Tandem C-N Coupling with Nitroarenes via SH2 Mechanism, Nat. Commun. 2022, 13, 2432 Chengyihan Gu, Shuaishuai Wang, Qingran Zhang and Jin Xie*, Visible-light-mediated amidation from carboxylic acids and tertiary amines via C-N cleavage, Chem. Commun.2022, 58, 5873-5876. Yijie He, Chaoyu Du, Jian Han, Jie Han, Chengjian Zhu and Jin Xie*, Manganese-Catalyzed Anti-Markovnikov Hydroarylation of Enamides: Modular Synthesis of Arylethylamines, Chin. J. Chem.2022, 13, 1546-1552. Chuan-Gang Zhao, Siyu Xia, Chenkun Wang, Wenliang Wang and Jin Xie*, Opportunities and Challenges of Visible Light-Driven Triple Synergistic Catalysis, Chem Catal. 2022, ASAP. Yantao Li, Qianzhen Shao, Hengchi He, Chengjian Zhu* Xiao-Song Xue* and Jin Xie*, Highly Selective Synthesis of All-Carbon Tetrasubstituted Alkenes by Deoxygenative Alkenylation of Carboxylic Acids, Nat. Commun. 2022, 13, 10. Xiaopeng Wu†, Jie Han†, Siyu Xia, Weipeng Li*, Chengjian Zhu* and Jin Xie*, Decarboxylative Acylation of Carboxylic Acids: Reaction Investigation and Mechanistic Study, CCS Chem. 2021, 3, 2581-2593 Lili Zhang, Shuai Chen, Hengchi He, Weipeng Li, Chengjian Zhu* and Jin Xie*, Photoredox/Nickel-Catalyzed Hydroacylation of Ethylene with Aromatic Acids. Chem. Commun.2021, 57, 9064-9067. Yunyun Ning, Shuaishuai Wang, Muzi Li, Jie Han, Chengjian Zhu, Jin Xie*, Site-Specific Umpolung Amidation of Carboxylic Acids via Triplet Synergistic Catalysis, Nat. Commun. 2021, 12, 4637. Muzi Li, Tao Liu, Jiajun Li, Hengchi He, Haotian Dai and Jin Xie*, Visible-Light-Mediated Deoxyalkynylation of Activated Tertiary Alcohols, J. Org. Chem. 2021, 86, 12386-12393 Kai Liu, Tingrui Li, Duan-Yang Liu, Weipeng Li, Jian Han, Chengjian Zhu, Jin Xie*, Dinuclear Gold-Catalyzed C-H Bond Functionalization of Cyclopropenes, Sci. China Chem. 2021, DOI: 10.1007/s11426-021-1031-x [s11426-021-1031-x.pdf] Nian Li, Yunyun Ning, Xiaopeng Wu, Jin Xie,* Weipeng Li* and Chengjian Zhu*, A Highly Selective Decarboxylative Deuteration of Carboxylic Acids, Chem. Sci. 2021, 12, 5505-5510 Wenliang Wang, Chenglong Ji, Kai Liu, Chuangang Zhao, Weipeng Li, Jin Xie*, Dinuclear Gold Catalysis, Chem. Soc. Rev. 2021, 50, 1874-1912 Sina Witzel, A. Stephen K. Hashmi, Jin Xie*, Light in Gold Catalysis, Chem. Rev. 2021, 121, 8868-8925 Jie Dong,†Xiang-Ai Yuan,†Zhongfei Yan,†Liying Mu,†Junyang Ma, Chengjian Zhu, Jin Xie*, Manganese-Catalyzed Divergent Silylation of Alkenes, Nature Chem. 2021, 13, 182-190. Dongping Wang, Yijie He, Haotian Dai, Congcong Huang, Xiang-Ai Yuan, Jin Xie*, Manganese-Catalyzed Hydrocarbofunctionalization of Internal Alkenes. Chin. J. Chem. 2020, 38, 1497-1502 Yubo Pang, Gengtu Liu, Congcong Huang, Xiang-Ai Yuan, Weipeng Li and Jin Xie*, A Highly Efficient Dimeric Manganese-Catalyzed Selective Hydroarylation of Internal Alkynes, Angew. Chem. Int. Ed. 2020, 59, 12789-12794 Wentao Xu, Muzi Li, Liancheng Qiao, Jin Xie*, Recent Advances of Dinuclear Nickel- and Palladium-Complexes in Homogeneous Catalysis, Chem. Commun. 2020, 56, 8524-8536 Rehanguli Ruzi,† Kai Liu,† Chengjian Zhu, Jin Xie*, Upgrading Ketone Synthesis Direct from Carboxylic Acids and Organohalides, Nature Commun. 2020, 11, 3312 Yuxia Sun, Xiaoshan Li, Miao Yang, Wentao Xu, Jin Xie and Mengning Ding*, Highly Selective Electrocatalytic Oxidation of Benzyl C–H Using Water as Safe and Sustainable Oxygen Source, Green Chem.2020, 22, 7543-7521. Wenliang Wang, Jin Xie*, Chiral Al-Complex Remote-Controlled Ni-Catalyzed Enantioselective Construction of Indenes, Chin. J. Org. Chem. 2020, 40, 1396-1397 (邀请亮点评述，原文链接） Jian Han, Jin Xie*, Tertiary Amine Synthesis by Radical Carbonyl Alkylative Amination, Chem, 2020, 6, 1053-1055. Qiaobo Liao,#,Wentao Xu,#, Xin Huang, Can Ke, Qi Zhang, Kai Xi*, Jin Xie*, Donor-acceptor Type [4+3] Covalent Organic Frameworks: Sub-stoichiometric Synthesis and Photocatalytic Application, Science China Chem. 2020,63 , 707-714 Congjun Zhu, Jie Dong, Xueting Liu, Liuzhou Gao, Yue Zhao, Jin Xie*, Shuhua Li*, and Chengjian Zhu* Photoredox Controlled β-Regioselective Radical Hydroboration of Activated Alkenes with NHC-Boranes, Angew. Chem. Int. Ed. 2020, 59, 12817-12821 Junyang Ma, Wentao Xu, Jin Xie*, Predictable Site-Selective Radical Fluorination of Tertiary Ethers, Science China Chem. 2020, 63, 187-191 Dongping Wang, Jie Dong, Wenjing Fan, Xiang-Ai Yuan, Jian Han, Jin Xie*, Dimeric Manganese-Catalyzed Hydroarylation and Hydroalkenylation of Unsaturated Amides, Angew. Chem. Int. Ed. 2020, 59, 8430-8434