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Ligand-Controlled Regiodivergent Ring Expansion of Benzosilacyclobutenes with Alkynes en Route to Axially Chiral Silacyclohexenyl Arenes Tang, X X ; Tang, Y L ; Peng, J ; Du, H M ; Huang, L Y ; Gao, J H ; Liu, S Y ; Wang, D X ; Wang, W S ; Gao, L ; Lan, Y *; Song, Z L * J Am Chem Soc 2024, 146, 39, 26639–26648
Lewis Base-Catalyzed Dynamic Kinetic Asymmetric Transformation of Racemic Chlorosilanes en Route to Si-Stereogenic Silylethers. Hu, T B ; Zhang, Y ; Wang, W S ; Li, Q ; Huang, L Y ; Gao, J H ; Kuang, Y Z ; Zhao, C ; Zhou, S ; Gao, L ; Su, Z S *; Song, Z L * J Am Chem Soc 2024, 146(33), 23092-23102
Controllable Si–C Bond Formation from Trihydrosilanes En Route to Synthesis of 1,4-Azasilinanes with Diverse Silyl Functionalities Guo, J W ; Liu, S F ; Jing, J ; Fan, Y ; Fu, Y D ; Liu, S Y ; Wang, W S ; Gao, L ; Song, Z L * Org Lett 2023, 25, 40, 7428-7433
Enantioconvergent construction of stereogenic silicon via Lewis base-catalyzed dynamic kinetic silyletherification of racemic chlorosilanes Hu, T B ; Zhao, C ; Zhang, Y ; Kuang, Y Z ; Gao, L ; Wang, W S ; Su Z S *; Song, Z L * Nat Commun , 2023, 14, 4900
Enantioselective Synthesis of 6/5-Spirosilafluorenes by Asymmetric Ring Expansion of 4/5-Spirosilafluorenes with Alkynes. Chen, H ; Zhang, H X ; Du, H M ; Kuang, Y Z ; Pang, Q J ; Gao, L ; Wang, W S *; Yang, C ; Song, Z L * Org Lett 2023, 25(9), 1558-1563
Intramolecular Ring Expansion of 3-Silaazetidine with Alkynes Enabled by Pd-Catalyzed Si–C Bond Activation Fan, Y ; Jing, J ; Tong, R Q ; Tu, X Y ; Gao, L ; Wang, W S *; Song, Z L * Org Lett 2023, 25(3), 455-460
3-Silyl-3-Borylhex-4-Enoate: A Chiral Reagent for Asymmetric Crotylboration of Aldehydes Tong, R Q ; Liu, S ; Zhao, C ; Jiang, D Y ; Gao, L ; Wang, W S ; Ye, B G *; Song, Z L * Org Lett 2022, 24(42), 7822-7827
Enantioselective Synthesis of Spirosilabicyclohexenes by Asymmetric Dual Ring Expansion of Spirosilabicyclobutane with Alkynes Chen, H ; Peng, J ; Pang, Q J ; Du, H M ; Huang, L Y ; Gao, L ; Lan, Y *; Yang, C *; Song, Z L * Angew Chem Int Ed 2022, 61, e202212889
(4 + 2) Annulation of Cl–NH3+CH2SiMe2CH2Cl and Propynones for the Synthesis of 1,3-Azasilinones. Ma, C ; Fan, Y ; Zheng, C M ; Gao, L ; Wang, W S ; Ke, B W *; Song, Z L * Org Lett 2022, 24(36), 6631-6636
(3+2)-Annulation of 1,3-N,Si-tetraorganosilanes Reagents TsHNCH2SiBnR1R2 with Arynes for Efficient Synthesis of 3-Silaindolines Cui, D Y ; Feng, Y ; Gan, Y ; Yin, J Q ; Wang, W S ; Fan, Y ; Gao, L ; Ke, B W *; Song, Z L * Org Chem Front , 2022, 9, 5453-5462
Trityl Cation-Catalyzed Hosomi-Sakurai Reaction of Allylsilane with β,γ-Unsaturated α-Ketoester to Form γ,γ-Disubstituted α-Ketoesters. Gan, Z B ; Cui, D Y ; Zhang, H Y ; Feng, Y ; Huang, L Y ; Gui, Y Y ; Gao, L *; Song, Z L * Molecules 2022, 27(15), 4730
Ring rearrangement of 1,3-azasilinyl-4-epoxides to synthesize 2silamorpolines by a Si-C bond migration/oxidation process Zhou, S ; Tu, X Y ; He, Y H ; Gao, L *; Song, Z L * Eur J Org Chem 2022, e202200766
Ring Expansion of Silacyclobutanes with Allenoates to Selectively Construct 2- or 3-(E)-Enoate-Substituted Silacyclohexenes Tang, X X ; Zhang, Y ; Tang, Y L ; Li, Y ; Zhou, J J ; Wang, D Y ; Gao, L ; Su Z S *; Song, Z L * ACS Catal 2022, 12, 5185–5196
Addition/Substitution Approach of TsNHCH2SiMe2CH2Cl with Isocyanates or Isothiocyanates To Construct 1,3,5-Diazasilinan-2-ones or 1,3,5-Thiazasilinan-2-imines Li, Y ; Hu, T B ; Gao, L *; Song, Z L * Synthesis, 2022, DOI: 10 1055 a-1748-6564
Synthetic Approaches for the Construction of Five- and Six-Membered Silaazacycles Wang, W S ; Gao, L *; Song, Z L * Synthesis, 2022, DOI: 10 1055 a-1755-3832
Synthesis of Silacyclohexanones from Divinylsilanes and Allylamines by a Rh-Catalyzed Cyclization. Guo, J W ; Liu, S ; Pang, Q J ; Zhang, H Y ; Gao, L ; Chen, L *; Song, Z L * Org Lett 2022, 24, 726-730
Asymmetric total synthesis and antidepressant activity of (−)-sila-mesembranol bearing a silicon stereocenter. Luo, G ; Chen, L M ; Li, Y; Fan, Y; Wang, D Y ; Yang, Y F ; Gao, L ; Jiang, R T *; Song, Z L * Org Chem Front 2021, 8, 5941-5947
O2-Assisted Four-component Reaction of Vinyl Magnesium Bromide with Chiral N-tert-Butanesulfinyl Imines To Form syn-1, 3-Amino Alcohols Wang, R P ; Luo, J F ; Zheng, C M ; Zhang, H Y ; Gao, L ; Song, Z L * Angew Chem Int Ed 2021, 60, 24644-24649
3-Silaazetidine: An Unexplored yet Versatile Organosilane Species for Ring Expansion toward Silaazacycles. Wang, W S ; Zhou, S ; Li, L ; He, Y H ; Dong, X ; Gao, L ; Wang, Q T ; Song, Z L * J Am Chem Soc 2021, 143, 11141-11151
Diverse synthesis of the C ring fragment of bryostatins via Zn/Cu-promoted conjugate addition of α-hydroxy iodide with enone Chu, Z W ; Tong, R Q ; Yang, Y F ; Song, X Y ; Hu, T B ; Fan, Y ; Zhao, C ; Gao, L *; Song, Z L * Chin Chem Lett 32(1), 1-4
Intramolecular Sakurai Allylation of Geminal Bis(silyl) Enamide with Indolenine. A Diastereoselective Cyclization To Form Functionalized Hexahydropyrido[3,4-b]Indole Chen, Y ; Song, X Y ; Gao, L *; Song, Z L * Org Lett 2021, 23(1), 124-128
The Brook Rearrangement Gao, L , Yang, W Y , Wu, Y and Song, Z L (2020) Organic Reactions pp 1-612 doi:10 1002 0471264180 or102 01
ArNMeCH(SiMe3)2: a useful precursor of formal α-aminoalkyl diradicals in visible-light-mediated homo- and hetero-diaddition with alkenes Liu, S F ; Yang, Y F ; Gao, L *; Song, Z L * Chem Commun 2020, 56 (54), 7487-7490
Synthesis of Unsymmetrical Diarylmethanols via C-Si bond Bifunctionalization Enabled by Sequential [1,4]-Csp2 to O-Silyl Migration Hu, T B , Huang, L Y , Gao, L *; Song, Z L * Org Chem Front 2020, 5(13), 2035-2039
Study on Silyl-aza-Prins Cyclization of GeminalBis(silyl) Homoallylic Amines. Tang, Z X ; Song, X Y ; Zhou, J J ; Gao, L *; Song, Z L * Chinese Journal of Synthetic Chemistry, 2019, 27(8), 584-588
Synthesis of Novel Geminal Bis(silyl) Allenamines via A Cross/Coupling/Isomerization Process. Gui Y Y ; Chen Y ; Gao L *; Song Z L * Chinese Journal of Synthetic Chemistry, 2019, 27(3), 173-178
One-Pot Twofold Unsymmetrical C−Si Bond 2,6-Bifunctionalization of Arenes via Sequential [1,4]-Csp2 to O‑Silyl Migration Wang, K ; Li, L J ; Hu, T B ; Gao, L *; Song, Z L * J Org Chem 2019, 84, 12583-12595
Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon. Wu, Y ; Chen, H ; Yang, W Y ; Fan, Y ; Gao, L *; Su, Z S ; Hu, C W ; Song, Z L * RSC Adv 2019, 9, 26209-26213
Total Synthesis of Bryostatin 8 and (-)-Exiguolide: Applications of an Organosilane Strategy. Zhang, Y B ; Lu, J ; Li, H Z ; Sun, X W ; Gao, L ; Song, Z L * Synlett 2019, 30, 753-764
Rhodium-Catalyzed Reaction of Silacyclobutanes with Unactivated Alkynes to Afford Silacyclohexenes Chen, H ; Chen, Y ; Tang, X X ; Liu, S F ; Wang, R P ; Hu, T B ; Gao, L ; Song, Z L * Angew Chem Int Ed 2019, 58 (14), 4695-4699
Recent progress in transition metal-catalyzed activation of Si-Si bonds to form C-Si bonds Xiao, P H ; Gao, L *; Song, Z L * Chem-Eur J 2019, 25(10), 2407-2422