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Sha Wang,† Linhong Long,† Xiaoyu Zhang, Liang Ling, Hui Chen,* and Xiaoming Zeng* Chemoselective Three-Component Geminal Cross Couplings of Dihaloalkanes with Cr Catalysis: Rapid Access to Tertiary and Quaternary Alkanes via a Metal–Carbene Intermediate Angew. Chem. Int. Ed. DOI:10.1002/anie.202312856.
Chao Li,† Shangru Yang,† and Xiaoming Zeng* Cross-Electrophile Silylation of Aryl Carboxylic Esters with Hydrochlorosilanes by SiH-Directed and Cr-Catalyzed Couplings ACS Catal. DOI: 10.1021/acscatal.3c02852.
Fei Fan,† Linhong Long,† Liang Ling, Chao Li, Meiming Luo,* Hui Chen,* and Xiaoming Zeng* Chemoselective chromium catalysed cross-coupling enables three-component tertiary alkane synthesis Nat. Synth. DOI: 10.1038/s44160-023-00364-w.
Changpeng Chen, Zhijun Wang, Sha Wang, Liang Xu,* and Xiaoming Zeng* Chromium-Catalyzed Diastereoselective Synthesis of Conformationally Constrained Spirotetrahydroquinolines Org. Lett. 2023, 25 (23), 4241–4246.
Sha Wang, Changpeng Chen, and Xiaoming Zeng* Bipyridine Ligand-Promoted cis-Selective Hydroboration of Al- kynes with Chromium Catalysis Chin. J. Org. Chem. 2023, 43(7), 2447–2453 (Invited paper).
Fangyan Yuan, Chao Li, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Carbony-Carbonyl Deoxygenative Couplings of Ketones to Tetrasubstituted Olefins Acta Chim. Sinica 2023, 81(5), 456–460 (Invited paper).
Ya Xiong, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Three-Component Synthesis of Monofluoroalkenes from gem-Difluoroalkenes via C−O/C−H and C−F Bond Activation Org. Lett. 2023, 25, 3120−3125.
Liang Ling, Chenyang Hu, Linhong Long, Xue Zhang, Lixing Zhao, Liu Leo Liu, Hui Chen*, Meiming Luo,* and Xiaoming Zeng* Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands Nat. Commun. 2023, 14, 990.
Chao Li, Liang Ling, Zheng Luo, Sha Wang, Xiaoyu Zhang, and Xiaoming Zeng* Deoxygenative Cross-Coupling of C(aryl)–O and C(amide)=O Electrophiles Enabled by Chromium Catalysis Using Bipyridine Ligand ACS Catal. 2023, 13, 3120–3130.
Lixing Zhao, and Xiaoming Zeng* Transition metal-catalyzed reactions promoted by cyclic (alkyl or aryl)(amino)carbene ligands Chem 2022, 8(8), 2082–2113.
Haohao Zeng, Shangru Yang, Chao Li, Fei Fan, Liang Ling, Meiming Luo* and Xiaoming Zeng* Chromium-catalyzed couplings of C(aryl)–SMe bonds in accessing arylated and alkylated benzaldehyde derivatives
Chem. Commun. 2022, 58(50), 7094–7097.
Li Gong,† Chao Li,† Fangyan Yuan, Senlin Liu, and Xiaoming Zeng* Chromium-Catalyzed Selective Borylation of Vinyl Triflates and Unactivated Aryl Carboxylic Esters with Pinacolborane
Org. Lett. 2022, 24 (17), 3227–3231.
Jinghua Tang,† Liang Ling,† Shuqing Yuan, Meiming Luo,* and Xiaoming Zeng* Catalytic Cleavage of Unactivated C(aryl)−P Bonds by Chromium Org. Lett. 2022, 24(8), 1581−1586.
Fei Fan,† Lixing Zhao,† Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Selective Cross-Electrophile Coupling between Unactivated C(aryl)–F and C(aryl)–O Bonds Organometallics 2022, 41(5), 561−568.
Junyao Xie, Xiaoming Zeng, Meiming Luo* Ni-Catalysed Regioselective α,β-Diarylation of α,β-Unsaturated Aldehydes Acta Chim. Sinica 2021, 79(9), 1118–1122.
Aiping Fu,† Lixing Zhao,† Chao Li, Meiming Luo, and Xiaoming Zeng* Chromium-Catalyzed Borylative Coupling of Aliphatic Bromides with Pinacolborane by Hydrogen Evolution
Organometallics 2021, 40(14), 2204−2208.
Shuqing Yuan, Liang Ling, Jinghua Tang, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Reductive Cleavage of Unactivated Aromatic and Benzylic C–O Bonds Synthesis 2021, 53(18), 3343–3350.
Xuefeng Cong, and Xiaoming Zeng* Chromium-Catalyzed Cross-Coupling Reactions by Selective Activation of Chemically Inert Aromatic C–O, C–N, and C–H Bonds Synlett 2021, 32(13), 1343–1353.
Xuefeng Cong, and Xiaoming Zeng* Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization Acc. Chem. Res. 2021, 54 (8), 2014–2026.
Changpeng Chen, Liang Ling, Meiming Luo, and Xiaoming Zeng* Chromium-Catalyzed Ligand-Free Amidation of Esters with Anilines Bull. Chem. Soc. Jpn. 2021, 94(3), 762–766. (Invited paper for celebration of 70th birthday of Professor Eiichi Nakamura)
Lixing Zhao,§ Chenyang Hu,§ Xuefeng Cong, Gongda Deng, Liu Leo Liu, Meiming Luo, and Xiaoming Zeng* Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications. J. Am. Chem. Soc. 2021, 143(3), 1618−1629. (§These authors contributed equally)
Jinghua Tang,† Fei Fan,† Xuefeng Cong,† Lixing Zhao, Meiming Luo, and Xiaoming Zeng* Reductive Cross-Coupling between Unactivated C(aryl)–N and C(aryl)–O Bonds by Chromium Catalysis Using a Bipyridyl Ligand J. Am. Chem. Soc. 2020, 142(29), 12834-12840. (†These authors contributed equally)
Jinghua Tang,† Liu Leo Liu,† Shangru Yang,† Xuefeng Cong, Meiming Luo, and Xiaoming Zeng* Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis J. Am. Chem. Soc. 2020, 142 (17), 7715–7720. (†These authors contributed equally)
Xiaoming Zeng* Recent Advances in Chromium-Catalyzed Organic Transformations Synlett 2020, 31 (3), 205–210.
Xue Zhang, Liang Ling, Meiming Luo, and Xiaoming Zeng* Accessing Equatorially Difluoromethylated and Trifluoromethylated cis-Cycloalkanes and Saturated Heterocycles by Preferential Hydrogen-Addition to the Substitution Sites for Dearomatization Angew. Chem. Int. Ed. 2019, 58 (47), 16785–16789.
Zhi Rong, Meiming Luo,* and Xiaoming Zeng* Modular Arene Difunctionalization by Sequential Cleavage of Unactivated C–O and C–H Bonds in One Pot with Chromium Catalysis Org. Lett. 2019, 21(17), 6869–6873.
Hong Meng, Sen Gao, Meiming Luo,* and Xiaoming Zeng* Iron and Phenol Co‐Catalysis for Rapid Synthesis of Nitriles under Mild Conditions Eur. J. Org. Chem. 2019, 2019 (28) 4617−4623.
Bo Han, Pengchen Ma, Xuefeng Cong, Hui Chen,* and Xiaoming Zeng* Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons: A Combined Experimental and Theoretical Study J. Am. Chem. Soc. 2019, 141 (22), 9018−9026.
Liang Ling, Yuan He, Xue Zhang, Meiming Luo, and Xiaoming Zeng* Hydrogenation of (Hetero)aryl Boronate Esters with a Cyclic (Alkyl)(amino)carbene-Rhodium Complex: Direct Access to cis-Substituted Borylated Cycloalkanes and Saturated Heterocycles Angew. Chem. Int. Ed. 2019, 58 (20), 6554–6558.
Liang Ling, Changpeng Chen, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Activation of Acyl C–O Bonds with Magnesium for Amidation of Esters with Nitroarenes Org. Lett. 2019, 21 (6), 1912–1916.
Jinghua Tang, Xuejiao J. Gao, Huarong Tang,* and Xiaoming Zeng* Dioxygen activation with stable N-heterocyclic carbenes Chem. Commun. 2019, 55(11), 1584–1587.
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