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个人简介

2017.05—至今 四川大学化学学院从事教学与科研工作,教授、博士生导师 2012.01—2017.04 西安交通大学前沿科学技术研究院从事科研工作,教授、博士生导师 2010.04—2011.12 东京大学化学系,JSPS研究员,合作导师:Eiichi Nakamura 教授 2007.09—2009.09 加州大学河滨分校化学系,联合培养博士,导师:Guy Bertrand 教授 2004.09—2009.12 四川大学化学学院有机化学专业攻读博士学位,导师:罗美明教授 2002.09—2004.07 广东省新兴县华侨中学从事高中化学教学工作 1998.09—2002.07 四川师范大学化学学院应用化学专业本科学习 学术任职:任Elsevier数据库旗下期刊Heliyon的国际编委。

研究领域

基于铬金属有机催化多局限于中高价态金属催化的研究现状,实验室聚焦构建铬低价金属催化体系,围绕“铬-底物/配体配位与控制反应选择性的关系”等问题展开研究,针对“铬金属催化活性低、较难发生双电子转移基元反应”的领域挑战、以及合成化学中存在的“惰性碳-杂键活化与不饱和键转化的选择性”难题,利用底物或配体的电子及位阻效应调节铬金属中心的催化性质,实现了一些惰性碳-杂键转化及不饱和键加氢的选择性控制。

近期论文

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Sha Wang,† Linhong Long,† Xiaoyu Zhang, Liang Ling, Hui Chen,* and Xiaoming Zeng* Chemoselective Three-Component Geminal Cross Couplings of Dihaloalkanes with Cr Catalysis: Rapid Access to Tertiary and Quaternary Alkanes via a Metal–Carbene Intermediate Angew. Chem. Int. Ed. DOI:10.1002/anie.202312856. Chao Li,† Shangru Yang,† and Xiaoming Zeng* Cross-Electrophile Silylation of Aryl Carboxylic Esters with Hydrochlorosilanes by SiH-Directed and Cr-Catalyzed Couplings ACS Catal. DOI: 10.1021/acscatal.3c02852. Fei Fan,† Linhong Long,† Liang Ling, Chao Li, Meiming Luo,* Hui Chen,* and Xiaoming Zeng* Chemoselective chromium catalysed cross-coupling enables three-component tertiary alkane synthesis Nat. Synth. DOI: 10.1038/s44160-023-00364-w. Changpeng Chen, Zhijun Wang, Sha Wang, Liang Xu,* and Xiaoming Zeng* Chromium-Catalyzed Diastereoselective Synthesis of Conformationally Constrained Spirotetrahydroquinolines Org. Lett. 2023, 25 (23), 4241–4246. Sha Wang, Changpeng Chen, and Xiaoming Zeng* Bipyridine Ligand-Promoted cis-Selective Hydroboration of Al- kynes with Chromium Catalysis Chin. J. Org. Chem. 2023, 43(7), 2447–2453 (Invited paper). Fangyan Yuan, Chao Li, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Carbony-Carbonyl Deoxygenative Couplings of Ketones to Tetrasubstituted Olefins Acta Chim. Sinica 2023, 81(5), 456–460 (Invited paper). Ya Xiong, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Three-Component Synthesis of Monofluoroalkenes from gem-Difluoroalkenes via C−O/C−H and C−F Bond Activation Org. Lett. 2023, 25, 3120−3125. Liang Ling, Chenyang Hu, Linhong Long, Xue Zhang, Lixing Zhao, Liu Leo Liu, Hui Chen*, Meiming Luo,* and Xiaoming Zeng* Chromium-catalyzed stereodivergent E- and Z-selective alkyne hydrogenation controlled by cyclic (alkyl)(amino)carbene ligands Nat. Commun. 2023, 14, 990. Chao Li, Liang Ling, Zheng Luo, Sha Wang, Xiaoyu Zhang, and Xiaoming Zeng* Deoxygenative Cross-Coupling of C(aryl)–O and C(amide)=O Electrophiles Enabled by Chromium Catalysis Using Bipyridine Ligand ACS Catal. 2023, 13, 3120–3130. Lixing Zhao, and Xiaoming Zeng* Transition metal-catalyzed reactions promoted by cyclic (alkyl or aryl)(amino)carbene ligands Chem 2022, 8(8), 2082–2113. Haohao Zeng, Shangru Yang, Chao Li, Fei Fan, Liang Ling, Meiming Luo* and Xiaoming Zeng* Chromium-catalyzed couplings of C(aryl)–SMe bonds in accessing arylated and alkylated benzaldehyde derivatives 
 Chem. Commun. 2022, 58(50), 7094–7097. Li Gong,† Chao Li,† Fangyan Yuan, Senlin Liu, and Xiaoming Zeng* Chromium-Catalyzed Selective Borylation of Vinyl Triflates and Unactivated Aryl Carboxylic Esters with Pinacolborane 
 Org. Lett. 2022, 24 (17), 3227–3231. Jinghua Tang,† Liang Ling,† Shuqing Yuan, Meiming Luo,* and Xiaoming Zeng* Catalytic Cleavage of Unactivated C(aryl)−P Bonds by Chromium Org. Lett. 2022, 24(8), 1581−1586. Fei Fan,† Lixing Zhao,† Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Selective Cross-Electrophile Coupling between Unactivated C(aryl)–F and C(aryl)–O Bonds Organometallics 2022, 41(5), 561−568. Junyao Xie, Xiaoming Zeng, Meiming Luo* Ni-Catalysed Regioselective α,β-Diarylation of α,β-Unsaturated Aldehydes Acta Chim. Sinica 2021, 79(9), 1118–1122. Aiping Fu,† Lixing Zhao,† Chao Li, Meiming Luo, and Xiaoming Zeng* Chromium-Catalyzed Borylative Coupling of Aliphatic Bromides with Pinacolborane by Hydrogen Evolution
 Organometallics 2021, 40(14), 2204−2208. Shuqing Yuan, Liang Ling, Jinghua Tang, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Reductive Cleavage of Unactivated Aromatic and Benzylic C–O Bonds Synthesis 2021, 53(18), 3343–3350. Xuefeng Cong, and Xiaoming Zeng* Chromium-Catalyzed Cross-Coupling Reactions by Selective Activation of Chemically Inert Aromatic C–O, C–N, and C–H Bonds Synlett 2021, 32(13), 1343–1353. Xuefeng Cong, and Xiaoming Zeng* Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization Acc. Chem. Res. 2021, 54 (8), 2014–2026. Changpeng Chen, Liang Ling, Meiming Luo, and Xiaoming Zeng* Chromium-Catalyzed Ligand-Free Amidation of Esters with Anilines Bull. Chem. Soc. Jpn. 2021, 94(3), 762–766. (Invited paper for celebration of 70th birthday of Professor Eiichi Nakamura) Lixing Zhao,§ Chenyang Hu,§ Xuefeng Cong, Gongda Deng, Liu Leo Liu, Meiming Luo, and Xiaoming Zeng* Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications. J. Am. Chem. Soc. 2021, 143(3), 1618−1629. (§These authors contributed equally) Jinghua Tang,† Fei Fan,† Xuefeng Cong,† Lixing Zhao, Meiming Luo, and Xiaoming Zeng* Reductive Cross-Coupling between Unactivated C(aryl)–N and C(aryl)–O Bonds by Chromium Catalysis Using a Bipyridyl Ligand J. Am. Chem. Soc. 2020, 142(29), 12834-12840. (†These authors contributed equally) Jinghua Tang,† Liu Leo Liu,† Shangru Yang,† Xuefeng Cong, Meiming Luo, and Xiaoming Zeng* Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis J. Am. Chem. Soc. 2020, 142 (17), 7715–7720. (†These authors contributed equally) Xiaoming Zeng* Recent Advances in Chromium-Catalyzed Organic Transformations Synlett 2020, 31 (3), 205–210. Xue Zhang, Liang Ling, Meiming Luo, and Xiaoming Zeng* Accessing Equatorially Difluoromethylated and Trifluoromethylated cis-Cycloalkanes and Saturated Heterocycles by Preferential Hydrogen-Addition to the Substitution Sites for Dearomatization Angew. Chem. Int. Ed. 2019, 58 (47), 16785–16789. Zhi Rong, Meiming Luo,* and Xiaoming Zeng* Modular Arene Difunctionalization by Sequential Cleavage of Unactivated C–O and C–H Bonds in One Pot with Chromium Catalysis Org. Lett. 2019, 21(17), 6869–6873. Hong Meng, Sen Gao, Meiming Luo,* and Xiaoming Zeng* Iron and Phenol Co‐Catalysis for Rapid Synthesis of Nitriles under Mild Conditions Eur. J. Org. Chem. 2019, 2019 (28) 4617−4623. Bo Han, Pengchen Ma, Xuefeng Cong, Hui Chen,* and Xiaoming Zeng* Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons: A Combined Experimental and Theoretical Study J. Am. Chem. Soc. 2019, 141 (22), 9018−9026. Liang Ling, Yuan He, Xue Zhang, Meiming Luo, and Xiaoming Zeng* Hydrogenation of (Hetero)aryl Boronate Esters with a Cyclic (Alkyl)(amino)carbene-Rhodium Complex: Direct Access to cis-Substituted Borylated Cycloalkanes and Saturated Heterocycles Angew. Chem. Int. Ed. 2019, 58 (20), 6554–6558. Liang Ling, Changpeng Chen, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Activation of Acyl C–O Bonds with Magnesium for Amidation of Esters with Nitroarenes Org. Lett. 2019, 21 (6), 1912–1916. Jinghua Tang, Xuejiao J. Gao, Huarong Tang,* and Xiaoming Zeng* Dioxygen activation with stable N-heterocyclic carbenes Chem. Commun. 2019, 55(11), 1584–1587.

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