Zaworotko, Michael J. - University of Limerick - Department of Chemical Sciences

个人简介

Prof. Mike Zaworotko was born in Wales in 1956 and received his B.Sc.and Ph.D. degrees from Imperial College (1977) and the University of Alabama (1982), respectively. He served as a faculty member at Saint Mary’s University, Nova Scotia, Canada, from 1985-1998, at University of Winnipeg, Canada from 1998-99 and at the University of South Florida, USA, from 1999-2013. In 2013 he joined the University of Limerick, Ireland, where he currently serves as Bernal Chair of Crystal Engineering, Science Foundation of Ireland Research Professor and co-director of the Synthesis and Solid-State Pharmaceutical Centre.

研究领域

Research activities have focused upon fundamental and applied aspects of crystal engineering since 1990. Currently, metal-organic materials (MOMs), especially microporous and ultramicroporous sorbents, and multi-component pharmaceutical materials (MPMs) such as cocrystals, hydrates and ionic cocrystals are of particular interest. These new materials are aimed at addressing global challenges such as carbon capture, water purification and better medicines. He is a Fellow of the Royal Society of Chemistry, the Learned Society of Wales and the Institute of Chemistry of Ireland. He is also a Member of the Royal Irish Academy.

近期论文

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An overview on trace CO2 removal by advanced physisorbent materials Majeda Khraisheh, Soumya Mukherjee, Amrit Kumar, Fares Al Momani, Gavin Walker, Michael J Zaworotko. Journal of Environmental Management 255, 109874. https://doi.org/10.1016/j.jenvman.2019.109874 Cu (4-phenylpyridine) 4 (trifluoromethanesulfonate) 2], a Werner complex that exhibits high selectivity for o-xylene.Adrianna M Kałuża, Soumya Mukherjee, Shi-Qiang Wang, Daniel J O'Hearn, Michael J Zaworotko. Chem Commun (Camb). 2020 Feb 13;56(13):1940-1943. doi: 10.1039/c9cc09525j. A Gadolinium(III) Zeolite-like Metal-Organic-Framework-Based Magnetic Resonance Thermometer Shi-Yuan Zhang, Zhong-Yan Wang, Jie Gao, Kunyu Wang, Eliana Gianolio, Silvio Aime, Wei Shi, Zhen Zhou, Peng Cheng, Michael J Zaworotko. Chem, 2019, 5, 1609-1618. A Soft Porous Crystal based upon Organic Cages that Exhibits Guest-Induced Breathing and Selective Gas Separation Zhifang Wang, Nivedita Sikdar, Shi-Qiang Wang, Xia Li, Meihui Yu, Xian-He Bu, Ze Chang, Xiaolong Zou, Yao Chen, Peng Cheng, Kuang Yu, Michael J Zaworotko, Zhenjie Zhang. Journal of the American Chemical Society, 2019, 141, 9408-9414. Benchmark selectivity p-xylene separation by a non-porous molecular solid through liquid or vapor extraction Na Sun, Shi-Qiang Wang, Ruqiang Zou, Wen-Gang Cui, Anqi Zhang, Tianzhen Zhang, Qi Li, Zhan-Zhong Zhuang, Ying-Hui Zhang, Jialiang Xu, Michael J Zaworotko, Xian-He Bu. Chemical Science, 2019, 10, 8850-8854. Cleaving Carboxyls: Understanding Thermally Triggered Hierarchical Pores in the Metal–Organic Framework MIL-121 Shoushun Chen, Soumya Mukherjee, Bryan EG Lucier, Ying Guo, YT Angel Wong, Victor V Terskikh, Michael J Zaworotko, Yining Huang. Journal of the American Chemical Society, 2019, 141, 14257-14271. Comparison of mechanochemistry vs solution methods for synthesis of 4,4′-bipyridine based coordination polymers Shaza Darwish,† Shi-Qiang Wang,† Denise M. Croker, Gavin M. Walker and Michael J. Zaworotko. ACS Sustain. Chem. Eng., 2019, 7, 19505-19512. Highly selective CO 2 removal for one-step liquefied natural gas processing by physisorbents David G Madden, Daniel O’Nolan, Kai-Jie Chen, Carol Hua, Amrit Kumar, Tony Pham, Katherine A Forrest, Brian Space, John J Perry, Majeda Khraisheh, Michael J Zaworotko. Chemical Communications, 2019, 55, 3219-3222. Highly Selective, High‐Capacity Separation of o‐Xylene from C8 Aromatics by a Switching Adsorbent Layered Material Shi‐Qiang Wang, Soumya Mukherjee, Ewa Patyk‐Kaźmierczak, Shaza Darwish, Alankriti Bajpai, Qing‐Yuan Yang, Michael J Zaworotko. Angewandte Chemie International Edition, 2019, 58, 6630-6634. Metal-organic framework based carbon capture and purification technologies for clean environment Soumya Mukherjee, Amrit Kumar, Michael J Zaworotko. Metal-Organic Frameworks (MOFs) for Environmental Applications, 2019, 5-61. Pharmaceutical cocrystals: from serendipity to design to application Oisin N Kavanagh, Denise M Croker, Gavin M Walker, Michael J Zaworotko. Drug Discovery Today, 2019, 24, 796-804. Self-Healing Hyper-Cross-Linked Metal–Organic Polyhedra (HCMOPs) Membranes with Antimicrobial Activity and Highly Selective Separation Properties Jinjin Liu, Wenjie Duan, Jie Song, Xiuxiu Guo, Zhifang Wang, Xinlei Shi, Jiajie Liang, Juan Wang, Peng Cheng, Yao Chen, Michael J Zaworotko, Zhenjie Zhang. Journal of the American Chemical Society, 2019, 141, 12064-12070. Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks Rana Sanii, Carol Hua, Ewa Patyk-Kaźmierczak, Michael J Zaworotko. Chemical communications, 2019, 55, 1454-1457. Synergistic sorbent separation for one-step ethylene purification from a four-component mixture Chen, K.J.; Madden, D.G.; Mukherjee, S.; Pham, T.; Forrest, K.A.; Kumar, A.; Space, B.; Kong, J.; Zhang, Q.Y.; Zaworotko, M.J. “Synergistic sorbent separation for one-step ethylene purification from a four-component mixture”. Science, 366, 241-246, 2019 Trace CO2 capture by an ultramicroporous physisorbent with low water affinity Soumya Mukherjee, Nivedita Sikdar, Daniel O’Nolan, Douglas M Franz, Victoria Gascón, Amrit Kumar, Naveen Kumar, Hayley S Scott, David G Madden, Paul E Kruger, Brian Space, Michael J Zaworotko. Science Advances, 2019, 5, eaax9171. Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution Ai‐Xin Zhu, Qing‐Yuan Yang, Soumya Mukherjee, Amrit Kumar, Cheng‐Hua Deng, Andrey A. Bezrukov, Mohana Shivanna, Michael J. Zaworotko. Angewandte Chemie International Edition, 2019, 58, 18212-18217. A Coordination Network That Reversibly Switches between Two Nonporous Polymorphs and a High Surface Area Porous Phase (C) Zhu, A.-X.; Yang, Q.-Y.; Kumar, A.; Crowley, C.; Mukherjee, S.; Chen, K.-J.; Wang, S.-Q.; O′Nolan, D.; Shivanna, M.; Zaworotko, M. J., " A Coordination Network That Reversibly Switches between Two Nonporous Polymorphs and a High Surface Area Porous Phase" J. Am. Chem. Soc., 2018, 140 (46), 15572-15576. A dynamic and multi-responsive porous flexible metal–organic material (C) Shivanna, M.; Yang, Q.-Y.; Bajpai, A.; Patyk-Kazmierczak, E.; Zaworotko, M. J., "A dynamic and multi-responsive porous flexible metal–organic material" Nat. Commun., 2018, 9 (1), 3080 Copper Sulfide (CuxS) Nanowire-in-Carbon Composites Formed from Direct Sulfurization of the Metal-Organic Framework HKUST-1 and Their Use as Li-Ion Battery Cathodes (C) Foley, S.; Geaney, H.; Bree, G.; Stokes, K.; Connolly, S.; Zaworotko, M. J.; Ryan, K. M., "Copper Sulfide (CuxS) Nanowire-in-Carbon Composites Formed from Direct Sulfurization of the Metal-Organic Framework HKUST-1 and Their Use as Li-Ion Battery Cathodes" Adv. Funct. Mater., 2018, 28 (19):1800587 Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands (C) Hayley S. Scott, Soumya Mukherjee, David R. Turner, Matthew I. J. Polson, Michael J. Zaworotko, and Paul E. Kruger. “Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands”. CrystEngComm, 2018, 20, 1193-1197 Efficient CO2 Removal for Ultra-Pure CO Production by Two Hybrid Ultramicroporous Materials (C) Chen, K.-J.; Yang, Q.-Y.; Sen, S.; Madden, D. G.; Kumar, A.; Pham, T.; Forrest, K. A.; Hosono, N.; Space, B.; Kitagawa, S.; Zaworotko, M. J., "Efficient CO2 Removal for Ultra-Pure CO Production by Two Hybrid Ultramicroporous Materials" Angew. Chem., Int. Ed. 2018, 57 (13), 3332-3336 Finding the Optimal Balance between the Pore Size and Pore Chemistry in Hybrid Ultramicroporous Materials for Trace Acetylene Capture (C) O'Nolan, D.; Kumar, A.; Chen, K.-J.; Mukherjee, S.; Madden, D. G.; Zaworotko, M. J., "Finding the Optimal Balance between the Pore Size and Pore Chemistry in Hybrid Ultramicroporous Materials for Trace Acetylene Capture" ACS Appl. Nano Mater., 2018, 1 (11), 6000-6004 High Yield, Low-Waste Synthesis of a Family of Pyridyl and Imidazolyl-Substituted Schiff Base Linker Ligands (C) Sanii R, Bajpai A, Patyk-Kaźmierczak E, et al. "High Yield, Low-Waste Synthesis of a Family of Pyridyl and Imidazolyl-Substituted Schiff Base Linker Ligands" ACS Sustain. Chem. Eng., 2018, 6(11): 14589-14598 Hygroscopicity of lithium coordination polymers and their solid solutions (C) Monica Lestari , Matteo Lusi , Aoife O'Leary , Daniel O'Nolan, and Michael J. Zaworotko. "Hygroscopicity of lithium coordination polymers and their solid solutions" CrystEngComm, 2018, 20, 5940-5944 Impact of partial interpenetration in a hybrid ultramicroporous material on C2H2/C2H4 separation performance (C) Daniel O’Nolan, David G. Madda, Amrit Kumar, Kai-Jie Chen a, Tony Pham, Katherine A. Forrest, Ewa Patyk-Kazmierczak, Qing-Yuan Yang, Claire A. Murray c, Chiu C. Tang c, Brian Space and Michael J. Zaworotko. “Impact of partial interpenetration in a hybrid ultramicroporous material on C2H2/C2H4 separation performance”. Chem. Commun., 2018, 54, 3488-3491 Layered Bimetallic Metal-Organic Material Derived Cu2SnS3/SnS2/C Composite for Anode Applications in Lithium-Ion Batteries (C) Foley, S.; Geaney, H.; Bree, G.; Mukherjee, S.; Zaworotko, M. J.; Ryan, K. M., "Layered Bimetallic Metal-Organic Material Derived Cu2SnS3/SnS2/C Composite for Anode Applications in Lithium-Ion Batteries" ChemElectroChem, 2018, 5(23), 3764-3770 Modulation of Water Vapor Sorption by a Fourth-Generation Metal–Organic Material with a Rigid Framework and Self-Switching Pores (C) Zhang, S.-Y.; Jensen, S.; Tan, K.; Wojtas, L.; Roveto, M.; Cure, J.; Thonhauser, T.; Chabal, Y. J.; Zaworotko, M. J., "Modulation of Water Vapor Sorption by a Fourth-Generation Metal–Organic Material with a Rigid Framework and Self-Switching Pores" J. Am. Chem. Soc., 2018, 140 (39), 12545-12552 Readily accessible shape-memory effect in a porous interpenetrated coordination network (C) Mohana Shivanna, Qing-Yuan Yang, Alankriti Bajpai, Susan Sen, Nobuhiko Hosono, Shinpei Kusaka, Tony Pham, Katherine A. Forrest, Brian Space, Susumu Kitagawa and Michael J. Zaworotko. “Readily accessible shape-memory effect in a porous interpenetrated coordination network” Sci. Adv., 2018, 4 (4): eaaq1636 Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network (C) Shi-Qiang Wang, Qing-Yuan Yang, Soumya Mukherjee, Daniel O’Nolan, Ewa Patyk-Kaźmierczak, Kai-Jie Chen, Mohana Shivanna, Claire Murray, Chiu C. Tang and Michael J. Zaworotko. "Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network" Chem. Commun., 2018, 54, 7042-7045 Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate‐Opening at Methane Storage Pressures (C) Qing‐Yuan, Y.; Prem, L.; Susan, S.; Matteo, L.; Kai‐Jie, C.; Wen‐Yang, G.; Mohana, S.; Tony, P.; Nobuhiko, H.; Shinpei, K.; J., P. J.; Shengqian, M.; Brian, S.; J., B. L.; Susumu, K.; J., Z. M., "Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate‐Opening at Methane Storage Pressures" Angew. Chem., Int. Ed., 2