研究领域

Inorganic & Materials Chemistry/Organic Chemistry

Our group has research interests in chemistry to build nanoscale materials with applications to fundamentally interesting, yet critical problems, including: solar energy transduction, photocatalysis, molecular electronics, chemical sensing and proton coupled electron transfer. Such constructs resemble components of natural biological systems that carry out the same energy related processes. Thus, biology can provide inspiration and fundamental design parameters for building new technologies. Conversely, artificial systems offer opportunities to better understand the detailed mechanisms of their biological counterparts.

近期论文

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Cedeno, D.; Krawicz, A.; Doak, P.; Yu, M.; Neaton, J. B.; Moore, G. F. Using Molecular Design to Control the Performance of Hydrogen- Producing Polymer-Brush-Modified Photocathodes. J. Phys. Chem. Lett. 2014, 5, 3222-3226. Krawicz, A.; Cedeno, D.; Moore, G. F. Energetics and Efficiency Analysis of a Cobaloxime-Modified Semiconductor at Simulated Air Mass 1.5 Illumination. Phys. Chem. Chem. Phys. 2014, 16, 15818-15824 Krawicz, A.; Yang, J.; Anzenberg, E.; Yano, J.; Sharp, I. D.; Moore, G. F. Photofunctional Construct That Interfaces Molecular Cobalt-Based Catalysts for H2 Production to a Visible-Light-Absorbing Semiconductor. J. Am. Chem. Soc. 2013, 135, 11861-11868. Faunce, T. A.; Lubitz, W.; Rutherford, A. W.; MacFarlane D.; Moore, G. F.; Yang, P.; Nocera, D. G.; Moore, T. A.; Gregory, D. H.; Fukuzumi, S.; Yoon, K. B.; Armstrong, F. A.; Wasielewski, M. R. Energy and Environment Policy Case for a Global Project on Artificial Photosynthesis. Energy Environ. Sci. 2013, 6, 695-698. Moore, G. F.; Sharp, I. D. A Noble-Metal-Free Hydrogen Evolution Catalyst Grafted to Visible Light-Absorbing Semiconductors. J. Phys. Chem. Lett. 2013, 13, 568-572. Najafpour, M. M.; Shen, J-R.; Barber, J.; Moore, G. F.; Govindjee Running on Sun. Chemistry World 2012, November, 43. Ugeda, M.; Yu, M.; Bradley, A.; Doak, P.; Liu, W.; Moore, G. F.; Sharp, I.; Tilley, T. D.; Neaton, J.; Crommie, M. Adsorption and Stability of π-Bonded Ethylene on GaP(110). J. Phys. Chem. C. 2013, 117, 26091-26096. Moore, G. F. Molecular and Nanoscale Interfaces for a Global Scale Challenge. European Photochemical Society Newsletter 2013, July, 91-92 Krawicz, A.; Moore, G. F. GATR-FTIR Characterization of Cobaloxime Modified P-Type Gallium Phosphide Cathodes. Prepr. Pap.-Am. Chem. Soc., Div. Energy Fuels 2013, 58 (2), 177-178. Milot, R. L.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Electron Injection Dynamics from Photoexcited Porphyrin Dyes into SnO2 and TiO2 Nanoparticles. J. Phys. Chem. C. 2013,117, 21662-21670. Martini, A. L.; Moore, G. F. Milot, R. L.; Cai, L. Z.; Sheehan, S. W.; Schmuttenmaer, C. A.; Brudvig, G. W.; Crabtree, R. H. Modular Assembly of High-Potential Zinc Porphyrin Photosensitizers Attached to TiO2 with a Series of Anchoring Groups. J. Phys. Chem. Lett. 2013, 117, 14526-14533. Milot, Rebecca L.; Moore, G. F.; Richter, C.; Martini, A. L.; Negre, C. A.; Batista, V. S.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Using time-resolved THz spectroscopy to study carrier dynamics and solar energy conversion in TiO2 nanotubes and other nanostructured materials. Abstracts of Papers, 246th ACS National Meeting & Exposition, 2013, pp COLL-421. Moore, GF; Konezny, SJ; Song, H.; Milot, RL; Blakemore, JD; Lee, ML; Batista, VS; Schmuttenmaer, CA; Crabtree, RH; Brudvig, GW Bioinspired High-Potential Porphyrin Photoanodes . J. Phys . Chem. C 2012 , 116 , 4892-4902. Moore, G. F.; Ananyev, G. M.; Govindjee Young Research Investigators Honored at 2012 Gordon Research Conference on Photosynthesis. Photosynth. Res. 2012, 114, 137-142. Moore, GF; Megiatto, JD; Hambourger, M .; Gervaldo, M .; Kodis, G .; Gust, D .; Moore, TA; Moore, AL Optical and Electrochemical Properties of Hydrogen-Bonded Phenol-pyrrolidino [60] fullerenes . Photochem. Photobiol. Sci. 2012 6.1018 to 1025. Moore, GF; Blakemore, JD; Milot, RL; Hull, J .; Song, H; Cai, L; Schmuttenmaer, CA; Crabtree, RH; Brudvig, GW A Visible Light Water Splitting Cell with a Photoanode Formed by Code Position of a High-Potential Porphyrin and a Homogeneous Iridium Water Oxidation Catalyst . Energy Environ. Sci., 2011 , 4 , 2389-2892. Milot, Rebecca L.; Richter, C.; Moore, G. F.; Crabtree, R. H.; Brudvig, G. W.; Schmuttenmaer, C. A. Time Resolved THz Spectroscopy to Study Carrier Injection and Dynamics in TiO2 and SnO2. Abstracts of Papers, 243rd ACS National Meeting & Exposition, 2012, pp FUEL-466. Moore, G. F.; Brudvig, G. W. Energy Conversion in Photosynthesis: A Paradigm for Solar Fuel Production. Annu. Rev.: Condensed Matter Physics. 2011, 2, 303- 327. Schmuttenmaer, C. A.; Richter, C.; Milot, R. L.; Moore, G. F.; Brudvig, G. W. Using Time Resolved THz Spectroscopy to Study Carrier Injection and Dynamics in TiO2 and SnO2. Abstracts of Papers, 242nd ACS National Meeting 2011, pp COMP-69. Moore, G. F.; Hambourger, M.; Kodis, G.; Michl, W.; Gust, D.; Moore, T. A.; Moore, A. L. Effects of Protonation State on a Tyrosine-Histidine Bioinspired Mediator. J. Phys. Chem. B. 2010, 114, 14450-14457. Hambourger, M.; Kodis, G.; Vaugnh, M.; Moore, G. F.; Gust, D.; Moore, A. L.; Moore, T. A. Solar Energy Conversion in a Photoelectrochemical Biofuel Cell. Dalton Transactions. 2009, 45, 9979-9989. Moore, G. F.; Hambourger, M.; Gervaldo, M.; Poluektov, O. G.; Rajh, T.; Gust, D.; Moore, T. A.; Moore, A. L. A Bioinspired Construct that Mimics the Proton Coupled Electron Transfer between P680 and the TyrZ-His190 Pair of Photosystem II. J. Am. Chem. Soc. 2008, 130, 10466-10467. Rizzi, A., van Gastel, M., Liddell, PA, Palacios, RE, Moore, GF, Codice, G., Moore, AL, Moore, TA, GUST, D., Braslavsky, SE anthropogenic changes control the load separation process in triads mimicking photosynthetic load separation . J. Phys. Chem. A. 2008, 112, 4215-4223. Moore, T. A.; Moore, A. L.; Gust, D.; Hambourger, M.; Moore, G. F.; Keirstead, A.; Gervaldo, M. Artificial photosynthesis: Combining Technology with Biology for Efficient Solar Energy Conversion. Abstracts of Papers, 235th ACS National Meeting, 2008; pp IEC-011. Moore, AL, Moore, GF; Hambourger, M.; Kodis, G.; Gervaldo, M.; Liddell, PA, Gust, D., Moore, TA Bioinspired Energy Conversion Schemes . Abstracts of Papers, 233rd ACS National Meeting, 2007 ; pp INOR-088th Berera, R., Moore, GF, or Stokkum, IHM; Kodis, G., Liddell, PA; Gervaldo, M.; or Grondelle, R., Knowledge, JTM, Gust, D., Moore, TA, Moore, AL C harge Separation and Energy Transfer in a Caroteno-C60 dyad: Photoinduced Electron Transfer From the carotenoid Excited States . Photochem. Photobiol. Sci. 2006, 5, 1142-1149 Moore, AL; Moore, TA; Gust, D .; Moore, GF; Kennis, J .; Hambourger, M .; Kodis, G .; Liddell, PA Energy Conversion Involving carotenoids Polyenes . Abstracts of Papers, 230th ACS National Meeting, 2005; pp PHYS-193rd Pessiki, P. J.; Moore, G. F. Synthesis and Photochemical Properties of Tetraphenylporphyrins Covalently Attached to Lichen Acids. Abstracts of Papers, 228th ACS National Meeting, 2004; pp ORGN-490.