Mankad, Neal - The University of Illinois at Chicago

研究领域

Inorganic and Organometallic Chemistry

近期论文

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Johnson, M. W.; Bagley, S. W.; Mankad, N. P.; Bergman, R. G.; Mascitti, V.; Toste, F. D. “Application of Fundamental Organometallic Chemistry to the Development of Gold-Catalyzed Synthesis of Sulfinate Derivatives.” Angew. Chem., Int. Ed. 2014, 53(17), 4404-4407. Mankad, N. P.; Toste, F. D. “C(sp3)-F Reductive Elimination from Alkylgold(III) Complexes.” Chem. Sci. 2012, 3, 72-76. Tkatchouk, E.; Mankad, N. P.; Benitez, D.; Goddard, W. A., III; Toste, F. D. “Two Metals Are Better Than One in the Gold Catalyzed Oxidative Heteroarylation of Alkenes.” J. Am. Chem. Soc. 2011, 133(36), 14293-14300. Takaoka, A.; Mankad, N. P.; Peters, J. C. “Dinitrogen Complexes of Sulfur-Ligated Iron.” J. Am. Chem. Soc. 2011, 133(22), 8440-8443. Tsay, C.; Mankad, N. P.; Peters, J. C. “Four-coordinate, trigonal pyramidal Pt(II) and Pd(II) complexes.” J. Am. Chem. Soc. 2010, 132(40), 13975-13977. Mankad, N. P.; Toste, F. D. “C-C Coupling Reactivity of an Alkylgold(III) Fluoride Complex with Arylboronic Acids.” J. Am. Chem. Soc. 2010, 132(37), 12859-12861. Lee, Y.; Mankad, N. P.; Peters, J. C. “Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron.” Nature Chem. 2010, 2(7), 558-565. Mankad, N. P.; Müller, P.; Peters, J. C. “Catalytic N-N Coupling of Aryl Azides to Yield Azoarenes via Trigonal Bipyramidal Iron-Nitrene Intermediates.” J. Am. Chem. Soc. 2010, 132(12), 4083-4085. Mankad, N. P.; Harkins, S. B.; Antholine, W. E.; Peters, J. C. “Multifrequency EPR Studies of [Cu1.5Cu1.5]+ for Cu2(µ-NR2)2 and Cu2(µ-PR2)2 Diamond Cores.” Inorg. Chem. 2009, 48(15), 7026-7032. Mankad, N. P.; Antholine, W. E.; Szilagyi, R. K.; Peters, J. C. “Three-Coordinate Copper(I) Amido and Aminyl Radical Complexes.” J. Am. Chem. Soc. 2009, 131(11), 3878-3880. Whited, M. T.; Mankad, N. P.; Lee, Y.; Oblad, P. F.; Peters, J. C. “Dinitrogen complexes supported by tris(phosphino)silyl ligands.” Inorg. Chem. 2009, 48(6), 2507-2517. Harkins, S. B.; Mankad, N. P.; Miller, A. J. M.; Szilagyi, R. K.; Peters, J. C. “Probing the Electronic Structures of [Cu2(µ-XR2)2]n+ Diamond Cores as a Function of the Bridging X atom (X = N or P) and Charge (n = 0, 1, 2).” J. Am. Chem. Soc. 2008, 130(11), 3478-3485. Mankad, N. P.; Peters, J. C. “Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph2BPtBu2]Cu(eta1-N2CR2), [Ph2BPtBu2]Cu(CPh2), and [Ph2BPtBu2]Cu-N(CPh2)(NCPh2).” Chem. Commun. 2008, (9), 1061-1063. Mankad, N. P.; Whited, M. T.; Peters, J. C. “Terminal FeI-N2 and FeII···H-C Interactions Supported by Tris(phosphino)silyl ligands.” Angew. Chem., Int. Ed. 2007, 46(30), 5768-5771. Thomas, C. M.; Mankad, N. P.; Peters, J. C. “Characterization of the Terminal Iron(IV) Imides {[PhBPtBu2(pz’)]FeIV≣NAd}+.” J. Am. Chem. Soc. 2006, 128(15), 4956-4957. Mankad, N. P.; Rivard, E.; Harkins, S. B.; Peters, J. C. “Structural Snapshots of a Flexible Cu2P2 Core that Accommodates the Oxidation States CuICuI, Cu1.5Cu1.5, CuIICuII.” J. Am. Chem. Soc. 2005, 127(46), 16032-16033. Rieth, R. D.; Mankad, N. P.; Calimano, E.; Sadighi, J. P. “Palladium-catalyzed cross-coupling of pyrrole anions with aryl chlorides, bromides, and iodides.” Org. Lett. 2004, 6(22), 3981-3983. Mankad, N. P.; Laitar, D. S.; Sadighi, J. P. “Synthesis, Structure, and Alkyne Reactivity of a Dimeric (Carbene)copper(I) Hydride.” Organometallics 2004, 23(14), 3369-3371. Mankad, N. P.; Gray, T. G.; Laitar, D. S.; Sadighi, J. P. “Synthesis, Structure, and CO2 Reactivity of a Two-Coordinate (Carbene)copper(I) Methyl Complex.” Organometallics 2004, 23(6), 1191-1193. Mazzacano, T. J.; Mankad, N. P. “Base Metal Catalysts for Photochemical C-H Borylation That Utilize Metal-Metal Cooperativity.” J. Am. Chem. Soc. 2013, 135(46), 17258-17261 Mankad, N. P. “Non-Precious Metal Catalysts for C–H Borylation Enabled by Metal-Metal Cooperativity.” Synlett 2014, 25(09), 1197-1201 Jayarathne, U.; Parmelee, S. R.; Mankad, N. P. “Small Molecule Activation Chemistry of Cu-Fe Heterobimetallic Complexes Toward CS2 and N2O.” Inorg. Chem. 2014, 53(14), 7730-7737 Karunananda, M. K.; Vazquez, F. X.; Alp, E. E.; Bi, W.; Chattopadhyay, S.; Shibata, T.; Mankad, N. P. “Experimental Determination of Redox Cooperativity and Electronic Structure in Catalytically Active Cu-Fe and Zn-Fe Heterobimetallic Complexes.” Dalton Trans. 2014, 43(36), 13361-3671 Johnson, B. J.; Lindeman, S. V.; Mankad, N. P. “Assembly, Structure, and Reactivity of Cu4S and Cu3S Models for the Nitrous Oxide Reductase Active Site, CuZ*.” Inorg. Chem. 2014, 53(19), 10611-10619 Banerjee, S.; Karunananda, M. K.; Bagherzadeh, S.; Jayarathne, U.; Parmelee, S. R.; Waldhart, G. W.; Mankad, N. P. “Synthesis and Characterization of Heterobimetallic Complexes with Direct Cu–M Bonds (M = Cr, Mn, Co, Mo, Ru, W) Supported by N-Heterocyclic Carbene Ligands: A Toolkit for Catalytic Reaction Discovery.” Inorg. Chem. 2014, 53(20), 11307-11315 Mazzacano, T. J.; Mankad, N. P. “Thermal C-H borylation using a CO-free iron boryl complex.” Chem. Commun. 2015, 51, 5379-5382 Waldhart, G. W.; Mankad, N. P. “Photochemical Heck Benzylation of Styrenes Catalyzed by Na[FeCp(CO)2].” J. Organomet. Chem., Accepted Manuscript, doi: 10.1016/j.organchem.2014.12.033 Waldhart, G. W.; Mankad, N. P. “trans-Tetracarbonylbis(triphenylphosphane-kP)molybdenum(0).” Acta Cryst. 2014, E70, m35