SONG, Datong - University of Toronto - Department of Chemistry

个人简介

Biography Associate Professor 2011.7-present Toronto Assistant Professor 2006.7-2011.7 Toronto NSERC Postdoctoral Fellow 2004.10-2006.6 MIT Postdoctoral Fellow 2003.10-2004.9 Toronto Ph.D. 2000.9-2003.10 Queen's B.Sc. 1996.9-2000.6 Nankai Awards and Honors CNC-IUPAC Travel Award 2011 Ontario Early Researcher Award 2009 Connaught New Staff Matching Grant 2007 Connaught New Staff Award 2006 NSERC Postdoctoral Fellowship 2004-2006 Queen's Graduate Award 2000-2003 Nankai University Fellowship 1996-2000

研究领域

Small Molecule Activation and Catalyltic Conversion The efficient conversion of naturally abundant small molecules into value-added products is an elegant way of utilizing natural resources, exemplified by numerous enzymatic processes developed by nature.Our group is particularly interested in the activation and catalytic conversion of atmospheric small molecules such as N2, O2, and CO2. Base Metal Chemistry Replacing noble metal-based homogeneous catalysts with base metal counterparts is an attractive approach. In addition to the lower cost, base metal catalysts are more environmentally friendly than their noble metal counterparts. Moreover, the use of high-spin metal centers can potentially result in lower activation barriers and can invoke one-electron processes that are less prevalent in noble metal chemistry. Metal-Organic Frameworks (MOFs) We are also researching metal organic frameworks (MOFs) with a focus on sensing and gas adsorption. We have developed MOFs with sensing capabilities toward volatile oragnics (VOCs) and with selective gas adsorption properties.

近期论文

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"Constructing Reactive Fe and Co Complexes from Isolated Picolyl-Functionalized N-Heterocyclic Carbenes" Liang, Qiuming; Liu, Nina Jiabo; Song, Datong Dalton Transactions (2018), 47, Accepted Manuscript. "A Hydride-Shuttle Mechanism for the Catalytic Hydroboration of CO2" Li, Longfei; Zhu, Huajie; Liu, Li; Song, Datong; Lei, Ming Inorganic Chemistry (2018), 57, 3054-3060. "Unusual Rearrangement of an N-Donor-Functionalized N-Heterocyclic Carbene Ligand on Group 8 Metals" Liang, Qiuming; Salmon, Andrew; Kim, Patrick Jinhyung; Yan, Linfan; Song, Datong Journal of the American Chemical Society (2018), 140, 1263-1266. "1,1-Hydroboration and a Borane Adduct of Diphenyldiazomethane: A Potential Prelude to FLP-N2 Chemistry" Tang, Connie; Liang, Qiuming; Jupp, Andrew R.; Johnstone, Timothy C.; Neu, Rebecca C.; Song, Datong; Grimme, Stefan; Stephan, Douglas W. Angewandte Chemie, International Edition (2017), 56, 16588-16592. "Chemical reduction of CO2 facilitated by C-nucleophiles " Janes, Trevor; Yang, Yanxin; Song, Datong Chemical Communications (2017), 53, 11390-11398. "Reactivity of Fe and Ru Complexes of Picolyl-Substituted N-Heterocyclic Carbene Ligand: Diverse Coordination Modes and Small Molecule Binding" Liang, Qiuming; Song, Datong Inorganic Chemistry (2017), 56, 11956-11970. "Homoleptic iron(II) and cobalt(II) bis(phosphoranimide) complexes for the selective hydrofunctionalization of unsaturated molecules" Bai, Tao; Janes, Trevor; Song, Datong Dalton Transactions (2017), 46, 12408-12412. "Highly regio- and stereoselective palladium-catalyzed allene bifunctionalization cascade via pi-allyl intermediate" Bai, Tao; Yang, Yanhui; Janes, Trevor; Song, Datong; Guo, Zhigang Tetrahedron (2017), 73, 5784-5793. "Iron-Catalyzed gem-Specific Dimerization of Terminal Alkynes" Liang, Qiuming; Osten, Kimberly M.; Song, Datong Angewandte Chemie International Edition (2017), 56, 6317-6320. "Reactivity of heavy carbene analogues towards oxidants: redox active ligand-enabled isolation of a paramagnetic stannylene" Janes, Trevor; Zatsepin, Pavel; Song, Datong* Chemical Communications (2017), 53, 3090 - 3093. "Zwitterionic indenylammonium with carbon-centred reactivity toward reversible CO2 binding and catalytic reduction" Yang, Yanxin; Yan, Linfan; Xie, Qinyu; Liang, Qiuming; Song, Datong* Organic & Biomolecular Chemistry (2017), 15, 2240 - 2245. "A luminescent cationic metal-organic framework featuring [Cu-pyrazolate]3 units for volatile organic compound sensing" Kivi, Charlie E.; Song, Datong* Dalton Transactions (2016), 45, 17087 - 17090. "Iron Complexes of a Bidentate Picolyl-NHC Ligand: Synthesis, Structure and Reactivity" Liang, Qiuming; Janes, Trevor; Gjergji, Xhoana; Song, Datong* Dalton Transactions (2016), 45, 13872 - 13880. "Direct Synthesis of CdSe Nanocrystals with Electroactive Ligands" Hassan, Yasser; Janes, Trevor; Pensack, Ryan D.; Rafiq, Shahnawaz; Broderson, Peter M.; Winnik, Mitchell A.; Song, Datong; Scholes, Gregory D.* Chemistry of Materials (2016), 28, 4953 - 4961. "Synthesis and reactivity of Li and TaMe3 complexes supported by N,N'-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands" Janes, Trevor; Xu, Maotong; Song, Datong* Dalton Transactions (2016), 45, 10672-10680. "Insertion of CO2 into the Carbon-Boron Bond of a Boronic Ester Ligand" Janes, Trevor; Osten, Kimberly M; Pantaleo, Adam; Yan, Ellen; Yang, Yanxin; Song, Datong* Chemical Communications (2016), 52, 4148-4151. "Coordination chemistry and applications of versatile 4,5-diazafluorene derivatives" Annibale, Vincent T.; Song, Datong* Dalton Transactions (2016), 45, 32-49.