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个人简介

Mar. 2000 Undergraduate School of Industrial Chemistry, Faculty of Engineering, Kyoto University, JAPAN Mar. 2002 M.S. course, Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, JAPAN Mar. 2005 Ph.D. course, Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, JAPAN May. 2005 Ph.D.(Eng.) degree Apr. 2005 – Feb. 2006 Postdoctoral Resarcher of CREST project at Japan Science and Technology Agency, JAPAN Mar. 2006 – Mar. 2008 Assistant Professor, Institute for Materials Chemistry and Engineering, Kyushu University, JAPAN Apr. 2008 – Mar. 2013 Group Leader, ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST) Apr. 2013 – Oct. 2015 Program-Specific Associate Professor, The Institute for Integrated Cell-Material Sciences, Kyoto University, JAPAN Nov. 2015 – Mar. 2017 Professor, Department of Chemical and Biological Engineering, Graduate School of Engineering, Nagoya University, JAPAN Apr. 2017 - Present Professor, Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, JAPAN Other posts Jun. 2007 – Mar. 2010 Visiting Researcher, Japan Synchrotron Radiation Research Institute (JASRI) Apr. 2008 – Mar. 2013 Designated Associate Professor , The Institute for Integrated Cell-Material Sciences, Kyoto University, JAPAN Apr. 2008 – Mar. 2014 Visiting Researcher, Spatial Order Research Team, Quantum Order Research Group, RIKEN SPring-8 Center Nov. 2015 – Mar. 2018 Visiting Professor, The Institute for Integrated Cell-Material Sciences, Kyoto University, JAPAN Apr. 2014 – Present Visiting Researcher, Photon Science Research Division, RIKEN SPring-8 Center Jan. 2018 – Present Visiting Professor, Dalian University of Technology, China Apr. 2019 - Present Professor, Institute for Advanced Research, Nagoya University, JAPAN Apr. 2019 - Present Visiting Professor, Institute for Integrated Cell-Material Sciences, Kyoto University, JAPAN

研究领域

Design of nanospace of metal organic framework for molecular recognition and separation The nanospace of metal organic frameworks can be structurally and functionally tuned by their building blocks. In our laboratory, we focus on creation of nanospace which can recognize specific molecules leading efficient gas separation functions. Study on molecular and framework dynamics toward energy conversion materials One of the most interesting properties of MOFs compared to the other porous materials is framework flexibility. It is known that adsorbed molecules and ligands composed of framework highly dynamic in the nanospace. We are focusing on flexible MOFs which can convert adsorption/desorption or chemical reaction energy to available energy. Development of inorganic-MOF hybrid membrane We are working on the hybridization of macroporous inorganic material and microporous materials with high density which make possible to effective molecular separation in non-equilibrium system. Elucidation of molecular events in the nanospace of MOFs Molecular events in the nanospace are totally different from those in our meter sized world. To elucidate such events, we have developed our original measurement systems. In addition, we also utilize state-of-the art technologies such as X-ray free electron laser combined with gas adsorption equipment.

近期论文

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Triplet Carbene with Highly Enhanced Thermal Stability in the Nanospace of a Metal–Organic Framework T. Nakajo, J. Kumagai, S. Kusaka, A. Hori, Y. Hijikata, J. Pirillo, Y. Ma, R. Matsuda* J. Am. Chem. Soc. , 2021 DOI: 10.1021/jacs.1c02430, in press An Open-shell, Luminescent, Two-Dimensional Coordination Polymer with a Honeycomb Lattice and Triangular Organic Radical S. Kimura, M. Uejima, W. Ota, T. Sato, S. Kusaka, R. Matsuda, H. Nishihara, T. Kusamoto J. Am. Chem. Soc. , 2021 , 11 , 4329-4338 DOI: 10.1021/jacs.0c13310, publication date: March 15, 2021 Modulation of Self-Assembly Enhances the Catalytic Activity of Iron Porphyrin for CO2 Reduction M. Tasaki, Y. Okabe, H. Iwami, C. Akatsuka, K. Kosugi, K. Negita, S. Kusaka, R. Matsuda, M. Kondo, S. Masaoka Small , 2021 DOI: 10.1002/smll.202006150, publication date: March 9, 2021 Tuning Gate-Opening of a Flexible Metal-Organic Framework for Ternary Gas Sieving Separation QB. Dong, X. Zhang, S. Liu, RB. Lin, YN. Guo, YS. Ma, A. Yonezu, R. Krishna, GP. Liu, JG. Duan, R. Matsuda, WQ. Jin, BL. Chen Angew. Chem. Int. Edit. , 2020 , 59 , 22756-22762 DOI: 10.1002/anie.202011802, publication date: December 7, 2020 Enhanced CO2 adsorption by insertion reaction in the nanospace of a porphyrin-based MOF M. Morita, S. Kusaka, A. Yonezu, Y. Ohara, H. Sakamoto R. Matsuda Chem. Lett. , 2020 , 50 , 640-643 DOI: 10.1246/cl.200785, publication date: December 18, 2020 Trapping and Releasing of Oxygen in Liquid by Metal-organic Framework with Light and Heat M. Fujimura, S. Kusaka, A. Masuda, A. Hori, Y. Hijikata, J. Pirillo, Y. Ma, R. Matsuda Small , 2020 DOI: 10.1002/smll.202004351, publication date: November 2, 2020 Molecular motion in the nanospace of MOFs upon gas adsorption investigated by in situ Raman spectroscopy S. Kusaka, Y. Nakajima, A. Hori, A. Yonezu, K. Kikushima, W. Kosaka, Y. Ma, R. Matsuda Faraday Discuss. , 2021, 225, 70-83 DOI: 10.1039/D0FD00002G, publication date: January 30, 2021 Molecular simulation study on the flexibility in the interpenetrated metal–organic framework LMOF-201 using reactive force field A. Agrawal, M. Agrawal, D. Suh, Y. Ma, R. Matsuda, A. Endo, W. L. Hsu, H. Daiguji J. Mater. Chem. A , 2020, 8, 16385-16391 DOI: 10.1039/C9TA12065C , publication date: July 22, 2020 Augmenting the Carbon Dioxide Uptake and Selectivity of Metal–Organic Frameworks by Metal Substitution: Molecular Simulations of LMOF-202 A. Agrawal, M. Agrawal, D. Suh, S. Fei, A. Alizadeh, Y. Ma, R. Matsuda, W. L. Hsu, H. Daiguji ACS Omega , 2020, 5, 17193-17198 DOI: 10.1021/acsomega.0c01267, publication date: July 9, 2020 Direct observation of dimethyl sulfide trapped by MOF proving efficient removal of sulfur impurities M. Morita, A. Yonezu, S. Kusaka, A. Hori, Y. Ma, R. Matsuda RSC Adv. , 2020, 10, 4710-4714 DOI: 10.1039/c9ra09702c, publication date: January 29, 2020 Accelerated C2H2/CO2 separation by a Se-functionalized porous coordination polymer with low binding energy Q. Dong, Y. Guo, H. Cao, S. Wang, R. Matsuda, J. Duan ACS Appl. Mater. Interfaces , 2020, 12, 3764-3772 DOI: 10.1021/acsami.9b20623, publication date: January 2, 2020 Pseudo Gated Adsorption with Negligible Volume Change Evoked by Halogen Bond Interaction in the Nanospace of MOFs P. Kanoo, R. Matsuda, H. Sato, L. Li, N. Hosono, S. Kitagawa Chem. Eur. J. , 2020, 26, 1-7 DOI: 10.1002/chem.201904703, publication date: November 22, 2019 Swift and Efficient Nuclear Spin Conversion of Molecular Hydrogen Confined in Prussian Blue Analogs Y. Ohtsubo, A. Mishima, A. Hori, R. Matsuda, R. Ohtani, M. Ohba Chem. Lett. , 2020, 49, 149-152 DOI: 10.1246/cl.190829, publication date: December 10, 2019 Kinetics of Water Vapor Adsorption and Desorption in MIL-101 Metal-Organic Frameworks K. Yanagita, J. Hwang, J. A. Shamim, W.-L. Hsu, R. Matsuda, A. Endo, J.-J. Delaunay, H. Daiguji J. Phys. Chem. C , 2019, 123, 387-398 DOI: 10.1021/acs.jpcc.8b08211, publication date: December 3, 2018 Dynamic topochemical reaction tuned by guest molecules in the nanospace of a metal-organic framework S. Kusaka, A. Kiyose, H. Sato, Y. Hijikata, A. Hori, Y. Ma, R. Matsuda J. Am. Chem. Soc. , 2019, 141, 15742-15746 DOI: 10.1021/jacs.9b07682, publication date: September 24, 2019 Reversible low-temperature redox activity and selective oxidation catalysis derived from the concerted activation of multiple metal species on Cr and Rh-incorporated ceria catalysts S. Ikemoto, X. Huang, S. Muratsugu, S. Nagase, T. Koitaya, H. Matsui, G. Yokota, T. Sudoh, A. Hashimoto, Y. Tan, S. Yamamoto, J. Tang, I. Matsuda, J. Yoshinobu, T. Yokoyama, S. Kusaka, R. Matsuda, M. Tada Phys.Chem.Chem.Phys. , 2019, 21, 20868-20877 DOI: 10.1039/C9CP04625A, publication date: September 13, 2019 Grafting Free Carboxylic Acid Groups onto the Pore Surface of 3D Porous Coordination Polymers for High Proton Conductivity Y. Tian, G. Liang, T. Fan, J. Shang, S. Shang, Y. Ma, R. Matsuda, M. Liu, M. Wang, L. Li, S. Kitagawa Chem. Mater. , 2019, 31, 8494-8503 DOI: 10.1021/acs.chemmater.9b02924, publication date: September 12, 2019 One-Step Synthesis of an Adaptive Nanographene MOF: Adsorbed Gas-Dependent Geometrical Diversity S. Suginome, H. Sato, A. Hori, A. Mishima, Y. Harada, S. Kusaka, R. Matsuda, J. Pirillo, Y. Hijikata, T. Aida J. Am. Chem. Soc. , 2019, 141, 15649-15655 DOI: 10.1021/jacs.9b07732, publication date: September 6, 2019 Microwave-Assisted Hydrothermal Synthesis of [Al(OH)(1,4-NDC)] Membranes with Superior Separation Performances Y. Liu, A. Hori, S. Kusaka, N. Hosono, M. Li, A. Guo, D. Du, Y. Li, W. Yang, Y. Ma, R. Matsuda Chem. Asian. J. , 2019, 14, 2072-2076 DOI: 10.1002/asia.201900152, publication date: May 8, 2019 Creation of MOFs with open metal sites by partial replacement of metal ions with different coordination numbers Y. Harada, Y. Hijikata, S. Kusaka, A. Hori, Y. S. Ma , R. Matsuda Dalton Trans. , 2019, 48, 2545-2548 DOI: 10.1039/C8DT04218G, publication date: December 12, 2018

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