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个人简介

PhD (Inorganic Chemistry), Texas A&M University, USA, 2010 MS (Polymer Chemistry and Physics), Zhejiang University, China, 2006 BS (Polymer Materials and Engineering), Zhejiang University, China, 2003 Dr. Zhao obtained his PhD degree in Inorganic Chemistry under the supervision of Prof. Hong-Cai Joe Zhou at Texas A&M University in 2010. After finishing his postdoctoral training at Argonne National Laboratory, he joined the Department of Chemical & Biomolecular Engineering at National University of Singapore in July 2012 as an Assistant Professor, and was promoted to Associate Professor with tenure in July 2018. He started to serve as an Associate Editor of Industrial & Engineering Chemistry Research in June 2021. His research interests include advanced porous materials and hybrid membranes with the applications in clean energy and environmental sustainability.

研究领域

We are working on interdisciplinary areas including organic/inorganic/polymer chemistry, materials science, and chemical engineering. Our research focuses on the molecular-level design and synthesis of advanced porous materials and hybrid membranes, and their applications in clean energy and environmental sustainability such as storage, separation, sensing, and catalysis. Metal-Organic Frameworks (MOFs) Covalent Organic Frameworks (COFs) Porous Organic Polymers (POPs) Molecular Cages

近期论文

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Yang, F. X.; Cui, F. Y.; Yuan, Y. D.; Yu, X.; Zhao, D.* Mechanistic insights into the role of nanoparticles towards the enhanced performance of thin-film nanocomposite membranes. J. Membr. Sci. Lett. 2023, 100046. Zhang, Z. Q.; Deng, Z. Y.; Evans, H. A.; Mullangi, D.; Kang, C. J.; Peh, S. B.; Wang, Y. X.; Brown, C. M.; Wang, J.; Canepa, P.*; Cheetham, A. K.*; Zhao, D.* Exclusive recognition of CO2 from hydrocarbons by aluminum formate with hydrogen-confined pore cavities. J. Am. Chem. Soc. 2023, DOI: 10.1021/jacs.3c01705. Yang, H.; Xu, J. H.; Cao, H.; Wu, J.*; Zhao, D.* Recovery of homogeneous photocatalysts by covalent organic framework membranes. Nat. Commun. 2023, 14, 2726. Ying, Y. P.*; Wang, D. C.; Zhao, D.* Two-dimensional material-based membranes for gas separation: current status and future direction. Curr. Opin. Chem. Eng. 2023, 40, 100918. Mullangi, D.; Evans, H. A.*; Yildirim, T.; Wang, Y. X.; Deng, Z. Y.; Zhang, Z. Q.; Mai, T. T.; Wei, F. X.; Wang, J.; Hight Walker, A. R.; Brown, C. M.; Zhao, D.*; Canepa, P.*; Cheetham, A. K.* Noncryogenic air separation using aluminum formate Al(HCOO)3 (ALF). J. Am. Chem. Soc. 2023, DOI: 10.1021/jacs.3c02100. Kang, C. J.; Zhang, Z. Q.; Kusaka, S.; Negita, K.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Zou, X. D.; Huang, Z. H.*; Matsuda, R.*; Zhao, D.* Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities. Nat. Mater. 2023, DOI: 10.1038/s41563-023-01523-2. Pu, Y. C.; Zhao, M. G.; Liang, X.; Wang, S. Y.; Wang, H. J.; Zhu, Z. T.; Ren, Y. X.; Zhang, Z. M.; He, G. W.*; Zhao, D.*; Jiang, Z. Y.* Growing ZIF-8 seeds on charged COF substrates toward efficient propylene-propane separation membranes. Angew. Chem. Int. Ed. 2023, e202302355. Yang, Z. Q.; Wu, Z. J.; Peh, S. B.; Ying, Y. P.; Yang, H.; Zhao, D.* Mixed-matrix membranes containing porous materials for gas separation: from metal–organic frameworks to discrete molecular cages. Engineering 2023, DOI: 10.1016/j.eng.2022.07.022. Yuan, H. Y.*; Li, K. R.; Shi, D. C.; Yang, H.; Yu, X.; Fan, W. D.; Buenconsejo, P. J. S.; Zhao, D.* Large-area fabrication of ultrathin metal-organic framework membranes. Adv. Mater. 2023, 2211859. Kang, C. J.; Zhang, Z. Q.; Xi, S. B.; Li, H.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Zhao, D.* Insertion of CO2 in metal ion-doped two-dimensional covalent organic frameworks. Proc. Natl. Acad. Sci. U. S. A. 2023, 120, e2217081120. Liu, Y. T.; Chen, L. Y.; Yang, L. F.; Lan, T. H.; Wang, H.; Hu, C. H.; Han, X.; Liu, Q. X.; Chen, J. F.; Feng, Z. M.; Cui, X. L.; Fang, Q. R.; Wang, H. L.; Li, L. B.*; Li, Y. W.*; Xing, H. B.*; Yang, S. H.*; Zhao, D.*; Li, J. P.* Porous framework materials for energy & environment relevant applications: a systematic review. Green Energy Environ. 2023, DOI: 10.1016/j.gee.2022.12.010. Yang, H.; Zhang, H. Y.; Zhao, D.* Functional covalent organic framework films based on surface and interfacial chemistry for molecular separations. Langmuir 2023, 39, 20-27. (Invited Perspective) Peh, S. B.; Farooq, S.*; Zhao, D.* Techno-economic analysis of MOF-based adsorption cycles for postcombustion CO2 capture from wet flue gas. Chem. Eng. Sci. 2023, 268, 118390. Liu, G. L.*; Cai, Y. H.; Yuan, H. Y.; Zhang, J. L.; Zhang, Z. M.*; Zhao, D.* Mesh membranes coated with zirconium metal-organic framework nanosheets of optimized morphology for oil-water separation. J. Membr. Sci. 2023, 668, 121077. Chen, F. Q.; Huang, X. L.; Yang, L.; Zhang, Z. G.; Yang, Q. W.; Yang, Y. W.; Zhao, D.*; Ren, Q. L.; Bao, Z. B.* Boosting xenon adsorption with record capacity in microporous carbon molecular sieves. Sci. China Chem. 2023, 66, 601-610. Zhang, B.; Chen, H. W.; Jiang, L. M.; Shen, Y. Q.; Zhao, D.; Zhou, Z. X.* A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning. Chin. J. Chem. Eng. 2022, 52, 95-102. Evans, H. A.; Mullangi, D.; Deng, Z. Y.; Wang, Y. X.; Peh, S. B.; Wei, F. X.; Wang, J.; Brown, C. M.; Zhao, D.*; Canepa, P.*; Cheetham, A. K.* Aluminum formate, Al(HCOO)3: an earth-abundant, scalable, and highly selective material for CO2 capture. Sci. Adv. 2022, 8, eade1473. Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Chai, K. G.; Wang, Y. X.; Zhao, D.* Tunable interlayer shifting in two-dimensional covalent organic frameworks triggered by CO2 sorption. J. Am. Chem. Soc. 2022, 144, 20363-20371. Hu, Z. G.*; Wang, Y. X.; Zhao, D.* Modulated hydrothermal chemistry of metal–organic frameworks. Acc. Mater. Res. 2022, 3, 1106-1114. (Supplementary Cover) Zhao, Y.; Ye, H. L.; Zhang, H. Y.; Zhao, D.; Huang, L. M.*; Lee, J. Y.* The beneficial effects of black phosphorous modification of the anode current collector in Li-metal free Li2S-based batteries. Mater. Today Energy 2022, 101179. Zhang, Z. Q.; Peh, S. B.; Kang, C. J.; Yu, K. X.; Zhao, D.* Efficient splitting of alkane isomers by a bismuth-based metal-organic framework with auxetic reentrant pore structures. Angew. Chem. Int. Ed. 2022, 61, e202211808. (Inside Back Cover, Hot Paper) Zhang, Z. Q.; Kang, C. J.; Peh, S. B.; Shi, D. C.; Yang, F. X.; Liu, Q. X.; Zhao, D.* Efficient adsorption of acetylene over CO2 in bioinspired covalent organic frameworks. J. Am. Chem. Soc. 2022, 144, 14992-14996. Dong, J. Q.*; Zhao, D.* Porous and permutable peptide frameworks. Nat. Chem. 2022, 14, 852-854. Dong, J. Q.*; Wee, V.; Zhao, D.* Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion. Nat. Mater. 2022, 21, 1334-1340. Chen, F. Q.; Huang, X. L.; Guo, K. Q.; Yang, L.; Sun, H. R.; Xia, W.; Zhang, Z. G.; Yang, Q. W.; Yang, Y. W.; Zhao, D.; Ren, Q. L.; Bao, Z. B.* Molecular sieving of propylene from propane in metal–organic framework-derived ultramicroporous carbon adsorbents. ACS Appl. Mater. Interfaces 2022, 14, 30443-30453. Yuan, Y. D.; Zhang, X. M.; Yang, Z. Q.; Zhao, D.* Metal–organic cage incorporating thin-film nanocomposite membranes with antifouling properties. Chem. Commun. 2022, 58, 6865-6868. (Invited Contribution in the Themed Collection “2022 Pioneering Investigators”) El-Sayed, E.-S. M.; Yuan, Y. D.; Zhao, D.*; Yuan, D. Q.* Zirconium metal–organic cages: synthesis and applications. Acc. Chem. Res. 2022, 55, 1546-1560. (Supplementary Cover) Kang, C. J.; Yang, K. W.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, Y. X.; Jiang, J. W.; Zou, X. D.; Huang, Z. H.*; Zhao, D.* Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study. Nat. Commun. 2022, 13, 1370. Yang, Z. Q.; Ying, Y. P.; Pu, Y. C.; Wang, D. C.; Yang, H.; Zhao, D.* Poly(ionic liquid)-functionalized UiO-66-(OH)2: improved interfacial compatibility and separation ability in mixed matrix membranes for CO2 separation. Ind. Eng. Chem. Res. 2022, 61, 7626-7633. (Special Issue: Jim Yang Lee Festschrift) Zhao, J.; Ying, Y. P.; Wang, G. L.*; Hu, K. D.; Yuan, Y. D.; Ye, H. L.; Liu, Z. L.; Lee, J. Y.*; Zhao, D.* Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries. Energy Storage Mater. 2022, 48, 82-89. Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Yu, K. X.; Wang, Y. X.; Zhao, D.* Aggregated structures of two-dimensional covalent organic frameworks. J. Am. Chem. Soc. 2022, 144, 3192-3199. Dong, J. Q.*; Pan, Y. T.; Yang, K. W.; Yuan, Y. D.; Wee, V.; Xu, S. D.; Wang, Y. X.; Jiang, J. W.*; Liu, B.*; Zhao, D.* Enhanced biological imaging via aggregation-induced emission active porous organic cages. ACS Nano 2022, 16, 2355-2368. Wang, D. C.; Ying, Y. P.; Zheng, Y. P.; Pu, Y. C.; Yang, Z. Q.; Zhao, D.* Induced polymer crystallinity in mixed matrix membranes by metal-organic framework nanosheets for gas separation. J. Membr. Sci. Lett. 2022, 2, 100017. Martín-Illán, J. Á.; Suárez, J. A.; Gómez-Herrero, J.; Ares, P.; Gallego-Fuente, D.; Cheng, Y. D.; Zhao, D.; Maspoch, D.; Zamora, F.* Ultralarge free-standing imine-based covalent organic framework membranes fabricated via compression. Adv. Sci. 2022, 9, 2104643. Yu, X.; Fan, W. D.; Wee, V.; Shi, D. C.; Yuan, H. Y.; Ying, Y. P.; Yuan, Y. D.; Yang, Z. Q.; Feng, Y.; Sun, D. F.; Zhao, D.* Polycrystalline Iron(III) metal-organic framework membranes for organic solvent nanofiltration with high permeance. J. Membr. Sci. 2022, 644, 120130. Pu, Y. C.; Yang, Z. Q.; Wee, V.; Wu, Z. J.; Jiang, Z. Y.*; Zhao, D.* Amino-functionalized NUS-8 nanosheets as fillers in PIM-1 mixed matrix membranes for CO2 separations. J. Membr. Sci. 2022, 641, 119912. Peh, S. B.; Farooq, S.*; Zhao, D.* A metal-organic framework (MOF)-based temperature swing adsorption cycle for postcombustion CO2 capture from wet flue gas. Chem. Eng. Sci. 2022, 250, 117399. Wang, Y. X.; Kang, C. J.; Zhang, Z. Q.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Yuan, Y. D.; Zhao, D.* Evaluation of Schiff-base covalent organic frameworks for CO2 capture: structure–performance relationships, stability, and performance under wet conditions. ACS Sustainable Chem. Eng. 2022, 10, 332-341. Rouhani, H.; Ying, Y. P.; Zhao, D.* Smart two-dimensional membranes for molecular separations. ChemNanoMat 2022, 8, e202100377. Yuan, H. Y.*; Li, N. X.; Fan, W. D.; Cai, H.; Zhao, D.* Metal-organic framework based gas sensors. Adv. Sci. 2022, 9, 2104374. Ying, Y. P.; Peh, S. B.; Yang, H.; Yang, Z. Q.; Zhao, D.* Ultrathin covalent organic framework membranes via a multi-interfacial engineering strategy for gas separation. Adv. Mater. 2022, 34, 2104946. (Back Cover, Editor’s Choice, Invited Contribution in the Special Issue “Materials Science in Singapore”) Zhao, D.*; Feng, X. L.* A special collection on 2D materials and their applications. Chem.-Asian J. 2021, 16, 4009-4009. Fan, W. D.; Ying, Y. P.; Peh, S. B.; Yuan, H. Y.; Yang, Z. Q.; Yuan, Y. D.; Shi, D. C.; Yu, X.; Kang, C. J.; Zhao, D.* Multivariate polycrystalline metal–organic framework membranes for CO2/CH4 separation. J. Am. Chem. Soc. 2021, 143, 17716-17723. (Front Cover) Zhang, B.; Chen, H. W.; Hu, Q. H.; Jiang, L. M.; Shen, Y. Q.; Zhao, D.; Zhou, Z. X.* CelluMOFs: green, facile, and flexible metal-organic frameworks for versatile applications. Adv. Funct. Mater. 2021, 31, 2105395. Yang, Z. Q.; Liu, G. L.; Yuan, Y. D.; Peh, S. B.; Ying, Y. P.; Fan, W. D.; Yu, X.; Yang, H.; Wu, Z. J.; Zhao, D.* Homoporous hybrid membranes containing metal-organic cages for gas separation. J. Membr. Sci. 2021, 636, 119564. Chen, H. W.; Chen, H. Q.; Zhang, B.; Jiang, L. M.; Shen, Y. Q.; Fu, E. G.; Zhao, D.; Zhou, Z. X.* Tuning the release rate of volatile molecules by pore surface engineering in metal-organic frameworks. Chin. Chem. Lett. 2021, 32, 1988-1992. Li, N. X.; Yuan, H. Y.; Xu, L. F.; Zeng, Y. Q.; Qiang, B.; Wang, Q. J.; Zheng, S. N.; Cai, H.*; Lee, L. Y. T.; Singh, N.; Zhao, D.* Tailorable infrared emission of microelectromechanical system-based thermal emitters with NiO films for gas sensing. Opt. Express 2021, 29, 19084-19093. Yuan, H. Y.; Liu, G. L.; Qiao, Z. W.; Li, N. X.; Buenconsejo, P. J. S.; Xi, S. B.; Karmakar, A.; Li, M. S.; Cai, H.; Pennycook, S. J.; Zhao, D.* Solution-processable metal–organic framework nanosheets with variable functionalities. Adv. Mater. 2021, 33, 2101257. (Frontispiece) Zhang, Z. Q.; Peh, S. B.; Krishna, R.; Kang, C. J.; Chai, K. G.; Wang, Y. X.; Shi, D. C.; Zhao, D.* Optimal pore chemistry in an ultramicroporous metal–organic framework for benchmark inverse CO2/C2H2 separation. Angew. Chem. Int. Ed. 2021, 60, 17198-17204. Liu, G. L.; Yang, Z. Q.; Zhou, M.; Wang, Y. X.; Yuan, D. Q.*; Zhao, D.* Heterogeneous postassembly modification of zirconium metal–organic cages in supramolecular frameworks. Chem. Commun. 2021, 57, 6276-6279. Fan, W. D.; Peh, S. B.; Zhang, Z. Q.; Yuan, H. Y.; Yang, Z. Q.; Wang, Y. X.; Chai, K. G.; Sun, D. F.; Zhao, D.* Tetrazole-functionalized zirconium metal-organic cages for efficient C2H2/C2H4 and C2H2/CO2 separations. Angew. Chem. Int. Ed. 2021, 60, 17338-17343. (Frontispiece) Zhao, J.; Yuan, H. Y.; Wang, G. L.*; Lim, X. F.; Ye, H. L.; Wee, V.; Fang, Y. Z.; Lee, J. Y.*; Zhao, D.* Stabilization of lithium metal anodes by conductive metal–organic framework architectures. J. Mater. Chem. A 2021, 9, 12099-12108. Ying, Y. P.; Yang, Z. Q.; Shi, D. C.; Peh, S. B.; Wang, Y. X.; Yu, X.; Yang, H.; Chai, K. G.; Zhao, D.* Ultrathin covalent organic framework film as membrane gutter layer for high-permeance CO2 capture. J. Membr. Sci. 2021, 632, 119384. Zhao, Y. J.; Liu, P.; Ying, Y. P.*; Wei, K. P.; Zhao, D.; Liu, D. H.* Heating-driven assembly of covalent organic framework nanosheets for gas separation. J. Membr. Sci. 2021, 632, 119326. Zhang, Z. Q.; Peh, S. B.; Kang, C. J.; Chai, K. G.; Zhao, D.* Metal-organic frameworks for C6–C8 hydrocarbon separations. EnergyChem 2021, 3, 100057. Shi, D. C.; Yu, X.; Fan, W. D.; Wee, V.; Zhao, D.* Polycrystalline zeolite and metal-organic framework membranes for molecular separations. Coord. Chem. Rev. 2021, 437, 213794. Dong, J. Q.; Wee, V.; Peh, S. B.; Zhao, D.* Molecular-rotor-driven advanced porous materials. Angew. Chem. Int. Ed. 2021, 60, 16279-16292. Fan, D.; Ozcan, A.; Ramsahye, N. A.; Zhao, D.; Maurin, G.; Semino, R.* Is porosity at the MOF/polymer interface necessarily an obstacle to optimal gas-separation performances in mixed matrix membranes? ACS Materials Lett. 2021, 3, 344-350. Hu, Z. G.*; Wang, Y. X.; Zhao, D.* The chemistry and applications of hafnium and cerium(IV) metal–organic frameworks. Chem. Soc. Rev. 2021, 50, 4629-4683. Ying, Y. P.; Zhang, Z. Q.; Peh, S. B.; Karmakar, A.; Cheng, Y. D.; Zhang, J.; Xi, L. F.; Boothroyd, C.; Lam, Y. M.; Zhong, C. L.*; Zhao, D.* Pressure-responsive two-dimensional metal–organic framework composite membranes for CO2 separation. Angew. Chem. Int. Ed. 2021, 60, 11318-11325. (Inside Back Cover) Wu, Z. J.; Wee, V.; Ma, X. B.*; Zhao, D.* Adsorbed natural gas storage for onboard applications. Adv. Sustainable Syst. 2021, 5, 2000200. Liu, G. L.; Zhang, X. M.; Yuan, Y. D.; Yuan, H. Y.; Li, N. X.; Ying, Y. P.; Peh, S. B.; Wang, Y. X.; Cheng, Y. D.; Cai, Y. H.; Gu, Z. H.; Cai, H.; Zhao, D.* Thin-film nanocomposite membranes containing water-stable zirconium metal–organic cages for desalination. ACS Materials Lett. 2021, 3, 268-274. Liu, X. M.; Lim, G. J. H.; Wang, Y. X.; Zhang, L.; Mullangi, D.; Wu, Y.; Zhao, D.; Ding, J.; Cheetham, A. K.; Wang, J.* Binder-free 3D printing of covalent organic framework (COF) monoliths for CO2 adsorption. Chem. Eng. J. 2021, 403, 126333. Hu, Z. G.*; Kundu, T.; Wang, Y. X.; Sun, Y.; Zeng, K. Y.; Zhao, D.* Modulated hydrothermal synthesis of highly stable MOF-808(Hf) for methane storage. ACS Sustainable Chem. Eng. 2020, 8, 17042-17053. Yuan, Y. D.; Dong, J. Q.; Liu, J.; Zhao, D. H.; Wu, H.; Zhou, W.; Gan, H. X.; Tong, Y. W.; Jiang, J. W.*; Zhao, D.* Porous organic cages as synthetic water channels. Nat. Commun. 2020, 11, 4927. (Behind the Paper) Cheng, Y. D.; Shi, D. C.; Yuan, Y. D.; Zhao, D.* Facile synthesis of a metal–organic framework for removal of methyl blue from water: first-year undergraduate teaching lab. J. Chem. Educ. 2020, 97, 4145-4151. Cai, Y. H.; Shi, D. C.; Liu, G. L.; Ying, Y. P.; Cheng, Y. D.; Wang, Y. X.; Chen, D. Y.; Lu, J. M.*; Zhao, D.* Polycrystalline zirconium metal-organic framework membranes supported on flexible carbon cloth for organic solvent nanofiltration. J. Membr. Sci. 2020, 615, 118551. Peh, S. B.; Zhao, D.* Tying amines down for stable CO2 capture. Science 2020, 369, 372-373. Zhang, Z. Q.; Peh, S. B.; Wang, Y. X.; Kang, C. J.; Fan, W. D.; Zhao, D.* Efficient trapping of trace acetylene from ethylene in an ultramicroporous metal–organic framework: synergistic effect of high-density open metal and electronegative sites. Angew. Chem. Int. Ed. 2020, 59, 18927-18932. (Front Cover, Hot Paper) Dong, J. Q.; Shen, P. C.; Ying, S. M.; Li, Z. J.; Yuan, Y. D.; Wang, Y. X.; Zheng, X. Y.; Peh, S. B.; Yuan, H. Y.; Liu, G. L.; Cheng, Y. D.; Pan, Y. T.; Shi, L. L.; Zhang, J.; Yuan, D. Q.; Liu, B.; Zhao, Z. J.*; Tang, B. Z.*; Zhao, D.* Aggregation-induced emission-responsive metal–organic frameworks. Chem. Mater. 2020, 32, 6706-6720. Yuan, H. Y.; Cui, J. Q.; Li, N. X.; Li, M. S.; Yu, X.; Fan, W. D.; Karmakar, A.; Dong, J. Q.; Pennycook, S. J.; Cai, H.*; Zhao, D.* On-chip template-directed conversion of metal hydroxides to metal–organic framework films with enhanced adhesion. ACS Appl. Mater. Interfaces 2020, 12, 36715-36722. Kang, C. J.; Zhang, Z. Q.; Wee, V.; Usadi, A. K.; Calabro, D. C.; Baugh, L. S.; Wang, S.; Wang, Y. X.; Zhao, D.* Interlayer shifting in two-dimensional covalent organic frameworks. J. Am. Chem. Soc. 2020, 142, 12995-13002. (Supplementary Cover) Zhang, Z. Q.; Ding, Q.; Peh, S. B.; Zhao, D.; Cui, J. Y.; Cui, X. L.*; Xing, H. B. Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture. Chem. Commun. 2020, 56, 7726-7729. Peh, S. B.; Xi, S. B.; Karmakar, A.; Yeo, J. Y.; Wang, Y. X.; Zhao, D.* Accelerated formation kinetics of a multicomponent metal–organic framework derived from preferential site occupancy. Inorg. Chem. 2020, 59, 9350-9355. Zhai, L. Z.; Yu, X.; Wang, Y. X.; Zhang, J.; Ying, Y. P.; Cheng, Y. D.; Peh, S. B.; Liu, G. L.; Wang, X. R.; Cai, Y. H.; Zhao, D.* Polycrystalline rare-earth metal-organic framework membranes with in-situ healing ability for efficient alcohol dehydration. J. Membr. Sci. 2020, 610, 118239. Yuan, H. Y.; Li, N. X.; Linghu, J. J.; Dong, J. Q.; Wang, Y. X.; Karmakar, A.; Yuan, J. R.; Li, M. S.; Buenconsejo, P. J. S.; Liu, G. L.; Cai, H.; Pennycook, S. J.; Singh, N.; Zhao, D.* Chip-level integration of covalent organic frameworks for trace benzene sensing. ACS Sens. 2020, 5, 1474-1481. Karmakar, A.; Prabakaran, V.; Zhao, D.; Chua, K. J.* A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications. Appl. Energy 2020, 269, 115070. Zhao, D.*; Cheetham, A.; Furukawa, S.; Kitagawa, S.; Xu, Q.; Zhang, W.; Zou, R. Q. Open framework materials for energy applications. APL Mater. 2020, 8, 040401. (Editorial in the Special Topic on Open Framework Materials for Energy Applications) Gu, Q. L.*; Ng, H. Y.; Zhao, D.; Wang, J.* Metal–organic frameworks (MOFs)-boosted filtration membrane technology for water sustainability. APL Mater. 2020, 8, 040902. Karmakar, A.; Mileo, P. G. M.; Bok, I.; Peh, S. B.; Zhang, J.; Yuan, H. Y.; Maurin, G.*; Zhao, D.* Thermo-responsive MOF/polymer composites for temperature mediated water capture and release. Angew. Chem. Int. Ed. 2020, 59, 11003-11009. (Back Cover) Ying, Y. P.; Tong, M. M.; Ning, S. C.; Ravi, S. K.; Peh, S. B.; Tan, S. C.; Pennycook, S. J.; Zhao, D.* Ultrathin two-dimensional membranes assembled by ionic covalent organic nanosheets with reduced apertures for gas separation. J. Am. Chem. Soc. 2020, 142, 4472-4480. (Front Cover) Cheng, Y. D.; Pu, Y. C.; Zhao, D.* Two-dimensional membranes: new paradigms for high-performance separation membranes. Chem.-Asian J. 2020, 15, 2241-2270. (Front Cover, Invited Review in the Special Issue “The Chemistry of 2D Materials Membranes”) Dong, J. Q.; Pan, Y. T.; Wang, H.; Yang, K. W.; Liu, L. M.; Qiao, Z. W.; Yuan, Y. D.; Peh, S. B.; Zhang, J.; Shi, L. L.; Liang, H.; Han, Y.; Li, X. P.; Jiang, J. W.; Liu, B.*; Zhao, D.* Self-assembly of highly stable zirconium(IV) coordination cages with aggregation induced emission molecular rotors for live-cell imaging. Angew. Chem. Int. Ed. 2020, 59, 10151-10159. (Dedicated to the 20 Anniversary of Aggregation Induced Emission) Wang, J.; Zhang, J.; Peh, S. B.; Liu, G. L.; Kundu, T.; Dong, J. Q.; Ying, Y. P.; Qian, Y. H.; Zhao, D.* Cobalt-containing covalent organic frameworks for visible light-driven hydrogen evolution. Sci. China Chem. 2020, 63, 192-197. Peh, S. B.; Karmakar, A.; Zhao, D.* Multiscale design of flexible metal–organic frameworks. Trends Chem. 2020, 2, 199-213. (Front Cover) Zhang, B.; Huang, J. X.; Liu, K. X.; Zhou, Z. X.*; Jiang, L. M.; Shen, Y. Q.; Zhao, D. Biocompatible cyclodextrin-based metal-organic frameworks for long-term sustained release of fragrances. Ind. Eng. Chem. Res. 2019, 58, 19767-19777. Wang, H.; Grabstanowicz, L. R.; Barkholtz, H. M.; Rebollar, D.; Kaiser, Z. B.; Zhao, D.; Chen, B. H.; Liu, D. J.* Impacts of imidazolate ligand on performance of zeolitic-imidazolate framework-derived oxygen reduction catalysts. ACS Energy Lett. 2019, 4, 2500-2507. Shah, B. B.; Kundu, T.; Zhao, D.* Mechanical properties of shaped metal–organic frameworks. Top. Curr. Chem. 2019, 377, 25. (Invited Review in the Topical Collection “Metal-Organic Framework: From Design to Applications”) Li, N. X.; Yuan, H. Y.; Xu, L. F.; Tao, J. F.; Ng, D. K. T.; Lee, L. Y. T.; Cheam, D. D.; Zeng, Y. Q.; Qiang, B.; Wang, Q. J.; Cai, H.*; Singh, N.; Zhao, D.* Radiation enhancement by graphene oxide on microelectromechanical system emitters for highly selective gas sensing. ACS Sens. 2019, 4, 2746-2753. (Supplementary Cover) Yilmaz, G.; Peh, S. B.; Zhao, D.; Ho, G. W.* Atomic- and molecular-level design of functional metal–organic frameworks (MOFs) and derivatives for energy and environmental applications. Adv. Sci. 2019, 6, 1901129. (Top Downloaded Paper 2018-2019) Yuan, H. Y.; Tao, J. F.; Li, N. X.; Karmakar, A.; Tang, C. H.; Cai, H.*; Pennycook, S. J.; Singh, N.; Zhao, D.* On-chip tailorability of capacitive gas sensors integrated with metal-organic framework films. Angew. Chem. Int. Ed. 2019, 58, 14089-14094. (Front Cover, Very Important Paper) Dong, J. Q.; Qiao, Z. W.; Pan, Y. T.; Peh, S. B.; Yuan, Y. D.; Wang, Y. X.; Zhai, L. Z.; Yuan, H. Y.; Cheng, Y. D.; Liang, H.; Liu, B.*; Zhao, D.* Encapsulation and protection of ultrathin two-dimensional porous organic nanosheets within biocompatible metal-organic frameworks for live-cell imaging. Chem. Mater. 2019, 31, 4897-4912. Lim, G. J. H.; Wu, Y.*; Shah, B. B.; Koh, J. J.; Liu, C. K.; Zhao, D.; Cheetham, A. K.; Wang, J.*; Ding, J.* 3D-printing of pure metal-organic framework monoliths. ACS Materials Lett. 2019, 1, 147-153. Zhao, D.*; Thallapally, P. K.*; Petit, C.*; Gascon, J.* Advanced porous materials: design, synthesis, and applications in sustainability. ACS Sustainable Chem. Eng. 2019, 7, 7997-7998. (Editorial in the Thematic Issue “Advanced Porous Materials: Design, Synthesis and Application in Sustainability”) Qian, Y. H.; Liu, Q. T.; Sarnello, E.; Tang, C. H.; Chng, M. L.; Shui, J. L.; Li, T.; Pennycook, S. J.; Han, M.; Zhao, D.* MOF-derived carbon networks with atomically dispersed Fe–Nx sites for oxygen reduction reaction catalysis in acidic media. ACS Materials Lett. 2019, 1, 37-43. Wang, Y. X.; Peh, S. B.; Zhao, D.* Alternatives to cryogenic distillation: advanced porous materials in adsorptive light olefin/paraffin separations. Small 2019, 15, 1900058. Ying, Y. P.; Cheng, Y. D.; Peh, S. B.; Liu, G. L.; Shah, B. B.; Zhai, L. Z.; Zhao, D.* Plasticization resistance-enhanced CO2 separation at elevated pressures by mixed matrix membranes containing flexible metal-organic framework fillers. J. Membr. Sci. 2019, 582, 103-110. Zhang, J.; Peh, S. B.; Wang, J.; Du, Y. H.; Xi, S. B.; Dong, J. Q.; Karmakar, A.; Wang, Y. X.; Ying, Y. P.; Zhao, D.* Hybrid MOF-808-Tb nanospheres for highly sensitive and selective detection of acetone vapor and Fe3+ in aqueous solution. Chem. Commun. 2019, 55, 4727-4730. Kundu, T.; Wahiduzzaman, M.; Shah, B. B.; Maurin, G.; Zhao, D.* Solvent induced control over breathing behavior in flexible metal-organic frameworks for natural gas delivery. Angew. Chem. Int. Ed. 2019, 58, 8073-8077. (Very Important Paper) Kundu, T.; Shah, B. B.; Bolinois, L.; Zhao, D.* Functionalization induced breathing control in metal-organic frameworks for methane storage with high deliverable capacity. Chem. Mater. 2019, 31, 2842-2847. (Supplementary Cover) Wang, Y. X.; Yuan, S.; Hu, Z. G.; Kundu, T.; Zhang, J.; Peh, S. B.; Cheng, Y. D.; Dong, J. Q.; Yuan, D. Q.; Zhou, H. C.; Zhao, D.* Pore size reduction in zirconium metal-organic frameworks for ethylene/ethane separation. ACS Sustainable Chem. Eng. 2019, 7, 7118-7126. Li, H.; Wang, K. C.; Hu, Z. G.; Chen, Y. P.; Verdegaal, W.; Zhao, D.*; Zhou, H. C.* Harnessing solvent effect to integrate alkylamine into metal-organic frameworks for exceptionally high CO2 uptake. J. Mater. Chem. A 2019, 7, 7867-7874. Peh, S. B.; Cheng, Y. D.; Zhang, J.; Wang, Y. X.; Chan, G. H.; Wang, J.; Zhao, D.* Cluster nuclearity control and modulated hydrothermal synthesis of functionalized Zr12 metal-organic frameworks. Dalton Trans. 2019, 48, 7069-7073. (Back Cover, Invited Contribution in the Themed Issue “New Talent: Asia-Pacific”) Qian, Y. H.; An, T.; Sarnello, E.; Liu, Z. L.; Li, T.; Zhao, D.* Janus electrocatalysts containing MOF-derived carbon networks and NiFe-LDH nanoplates for rechargeable Zn-air batteries. ACS Appl. Energy Mater. 2019, 2, 1784-1792. Cheng, Y. D.; Zhai, L. Z.; Ying, Y. P.; Wang, Y. X.; Liu, G. L.; Dong, J. Q.; Ng, D. Z. L.; Khan, S. A.; Zhao, D.* Highly efficient CO2 capture by mixed matrix membranes containing three-dimensional covalent organic framework fillers. J. Mater. Chem. A 2019, 7, 4549-4560. Yuan, H. Y.; Aljneibi, S. A. A. A.; Yuan, J. R.; Wang, Y. X.; Liu, H.; Fang, J.; Tang, C. H.; Yan, X. H.; Cai, H.; Gu, Y. D.; Pennycook, S. J.; Tao, J. F.*; Zhao, D.* ZnO nanosheets abundant in oxygen vacancies derived from metal-organic frameworks for ppb-level gas sensing. Adv. Mater. 2019, 31, 1807161. (Inside Front Cover, Highly Cited Paper in Web of Science Aug 2020) Peh, S. B.; Wang, Y. X.; Zhao, D.* Scalable and sustainable synthesis of advanced porous materials. ACS Sustainable Chem. Eng. 2019, 7, 3647-3670. (Invited Review in the Thematic Issue “Advanced Porous Materials: Design, Synthesis and Application in Sustainability”) Ibrahim, S.; Cheng, Y. D.; Zhao, D.*; Nadeem, M. A.* A new insight for photocatalytic hydrogen production by a Cu/Ni based cyanide bridged polymer as a co-catalyst on titania support in glycerol water mixture. Int. J. Hydrogen Energy 2019, 44, 2508-2518. Cheng, Y. D.; Zhai, L. Z.; Tong, M. M.; Kundu, T.; Liu, G. L.; Ying, Y. P.; Dong, J. Q.; Wang, Y. X.; Zhao, D.* Selective gas permeation in mixed matrix membranes accelerated by hollow ionic covalent organic polymers. ACS Sustainable Chem. Eng. 2019, 7, 1564-1573. Dong, J. Q.; Li, X.; Peh, S. B.; Yuan, Y. D.; Wang, Y. X.; Ji, D. X.; Peng, S. J.; Liu, G. L.; Ying, S. M.; Yuan, D. Q.; Jiang, J. W.; Ramakrishna, S.; Zhao, D.* Restriction of molecular rotors in ultrathin two-dimensional covalent organic framework nanosheets for sensing signal amplification. Chem. Mater. 2019, 31, 146-160. (Top Download in Dec 2018) Wang, J.; Zhang, J.; Peh, S. B.; Zhai, L. Z.; Ying, Y. P.; Liu, G. L.; Cheng, Y. D.; Zhao, D.* Dimensional impact of metal-organic frameworks in catalyzing photo-induced hydrogen evolution and cyanosilylation reactions. ACS Appl. Energy Mater. 2019, 2, 298-304. Ibrahim, S.; Majeed, I.; Hussain, E.; Badshah, A.; Qian, Y. H.; Zhao, D.*; Turner, D. R.*; Nadeem, M. A.* Novel photo-functional material based on homo-metallic cyanide bridged nickel coordination polymer and titania for hydrogen generation. Inorg. Chim. Acta 2019, 486, 684-693. Cheng, Y. D.; Ying, Y. P.; Zhai, L. Z.; Liu, G. L.; Dong, J. Q.; Wang, Y. X.; Christopher, M. P.; Long, S. C.; Wang, Y. X.; Zhao, D.* Mixed matrix membranes containing MOF@COF hybrid fillers for efficient CO2/CH4 separation. J. Membr. Sci. 2019, 573, 97-106. (Highly Cited Paper in Web of Science Aug 2020) Hu, Z. G.*; Wang, Y. X.; Shah, B. B.; Zhao, D.* CO2 capture in metal-organic framework adsorbents: an engineering perspective. Adv. Sustainable Syst. 2019, 3, 1800080. (Inside Back Cover, Highlighted on AdvancedScienceNews.com) Liu, Y. H.; Wang, Y. X.; Huang, J. X.; Zhou, Z. X.*; Zhao, D.; Jiang, L. M.; Shen, Y. Q. Encapsulation and controlled release of fragrances from functionalized porous metal-organic frameworks. AIChE J. 2019, 65, 491-499. (Top Downloaded Paper 2018-2019) Guan, C.*; Sumboja, A.; Zang, W. J.; Qian, Y. H.; Zhang, H.; Liu, X. M.; Liu, Z. L.*; Zhao, D.; Pennycook, S. J.; Wang, J.* Decorating Co/CoNx nanoparticles in nitrogen-doped carbon nanoarrays for flexible and rechargeable zinc-air batteries. Energy Storage Mater. 2019, 16, 243-250. (Highly Cited Paper in Web of Science Aug 2020)

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