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个人简介

Dr. Singer, a native of Nova Scotia, obtained his B.Sc. Honours (First Class) at Saint Mary's University in 1986. He went on to obtain a Ph.D. in Organic Chemistry with an NSERC PGS Award at Simon Fraser University under the supervision of Professor A. C. Oehlschlager. Upon a successful thesis defense in 1992, he took up an Alexander von Humboldt Fellowship at the Universität Marburg in Germany under the supervision of Professor Paul Knochel until September 1993 when he took up an Assistant Professor position at his alma mater. He is now a Full Professor and current Chair of the Department of Chemistry at Saint Mary's University. He has also served on the University's Academic Senate and Board of Governors.

研究领域

Catalysis in Ionic Liquids, Biomass Processing in Ionic Liquids, Green Chemistry, Ionic Liquids as Reaction Media Related to Organometallic Methodology, Asymmetric Synthesis

近期论文

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Leigh Ford,Kai E. O. Ylijoki,Robert D. Singer,Peter J. Scammells“Nitrogen Containing Ionic Liquids: Biodegradation Studies and Utility in Base Mediated Reactions” Aust. J. Chem. 2015, 68, 849. Kenson Ambrose, Bitu B. Hurisso, and Robert D. Singer* “Recyclable Ionic Liquid Tagged Co(Salen) Catalysts for the Oxidation of Lignin Model Compounds” Can. J. Chem., 2013, 91: 1258-1261. dx.doi.org/10.1139/cjc-2013-0336. Scott G. Harroun, Theodore J. Abraham, Christine Prudhoe, Yaoting Zhang, Peter J. Scammells, Christa L. Brosseau*, Cory C. Pye*, Robert D. Singer* “Electrochemical Surface-Enhanced Raman Spectroscopy (E-SERS) of Novel Biodegradable Ionic Liquids” Phys. Chem. Chem. Phys. (2013), 15, 19205-19212, DOI: 10.1039/c3cp52916a. Swapnil Sonar, Kenson Ambrose, Arthur D. Hendsbee, Jason D. Masuda, and Robert D. Singer* Can. J. Chem. 2012, 90(1): 60-70 “Synthesis and application of Co(salen) complexes containing proximal imidazolium ionic liquid cores” Invited Contribution. Leigh Ford, Farzad Atefi, Robert D. Singer and Peter J. Scammells* Eur. J. Org. Chem.2011, 942-950. “Grignard Reactions in Pyridinium and Phosphonium Ionic Liquids” Leigh Ford, Jitendra R. Harjani, Farzad Atefi, M. Teresa Garcia, Robert D. Singer, and Peter J. Scammells Green Chem. 2010 , 1783 – 1789 DOI: 10.1039/C0GC00082E “Further studies on the biodegradation of pyridinium ionic liquids” Gaik B. Kok, Cory C. Pye, Robert D. Singer, and Peter J. Scammells* J. Org. Chem. 2010, 75, 4806-4811“An Efficient Two-step Iron(0)-mediated N-Demethylation of N-Methyl Alkaloids” Jitendra R. Harjani, Theodore J. Abraham, Alwyn T. Gomez, M. Teresa Garcia, Robert D. Singer,* and Peter J. Scammells* Green Chem. 2010, 12, 650 - 655 ”Sonogashira Coupling Reactions in Biodegradable Ionic Liquids Derived from Nicotinic Acid” Farzad Atefi, M. Teresa Garcia, Robert D. Singer*, Peter J. Scammells*, Green Chem. , 2009, 11, 1595 – 1604. “Phosphonium ionic liquids: design, synthesis and evaluation of biodegradability”. Jitendra R. Harjani, Jeff Farrell, M. Teresa Garcia, Robert D. Singer*, and Peter J. Scammells*, Green Chem. 2009 , 11, 821 - 829 “Further Investigation of the Biodegradability of Imidazolium Ionic Liquids” Marangoni, Gerrard; Singer, Robert; Singh, Kulbir; Quinn, Jason J. Colloid Interface Sci. 335, (2009), 105 - 111 “Spontaneous Vesicle Formation with an Ionic Liquid Amphiphile” Jitendra R. Harjani,a Robert D. Singer,b M. Teresa Garciac and Peter J. Scammellsa,* Green Chemistry , 2009, 11, 83 - 90 “Biodegradable Pyridinium Ionic Liquids: Design, Synthesis and Evaluation” Naik, P. U., Trider, C.L., Farrell, J., Singer, R. D . I & EC ACS Symposium Series , Accepted February 20, 2009 “Ionic Liquid Complexes for Metal Extractions and Biphasic Catalysis” Prashant U. Naik, Greg McManus, Michael J. Zaworotko and Robert D. Singer* Dalton Trans. 2008, 4834 – 4836. “Salicylaldoxime and salen containing imidazolium ionic liquids for biphasic catalysis and metal extractions” Jitendra R. Harjani, Prashant Naik, Tomislav Frišcic,, Leonard R MacGillivray, and Robert D. Singer* Dalton Trans. 2008, 4595 – 4601. Inside Cover “Removal of Metal Ions from Aqueous Solutions Using Chelating Task-Specific Ionic Liquids” Miranda L. Cheney, Michael J. Zaworotko, Steven Beaton, and Robert D. Singer* J. Chem. Ed. 2008, 85, 1649 – 1651. “Cocrystal Controlled Solid-State Synthesis – C3S3: A Green Chemistry Experiment for Undergraduate Organic Chemistry” Entered on the Greener Education Materials for Chemists (GEMs) database, March 2009. Jitendra R. Harjani, Robert D. Singer, M. Teresa Garcia and Peter J. Scammells* Green Chemistry 2008, 10, 436. “The Design and Synthesis of Biodegradable Pyridinium Ionic Liquids” Teresa Lama, Robert D. Singer and William D. Lubell “Peptides of Life - Teaching Peptide Science and Art in Elementary School” Peptides for Youth, The Proceedings of the 20th American Peptide Symposium, Series: Advances in Experimental Medicine and Biology , Vol. 611, Del Valle, Susan; Escher, Emanuel; Lubell, William D. (Eds.) Springer, 2008. Prashant Naik and Robert D. Singer “Salicylaldoxime and salen containing ionic liquids for metal complexes” Provisional Patent filed in US Patent and Trademark Office (USPTO), February 28, 2008 application #: 61/032,103. Sandrine Bouquillon, Thomas Courrant, Darrell Dean, Nicholas Gathergood, Saibh Morrissey , Bruce Pegot , Peter J. Scammells, and Robert D. Singer Aust. J. Chem.. 2007, 60, 843-847. “Biodegradable Ionic Liquids: Selected Applications” Singer, Robert Douglas; Harjani, Jitendra “Imidazolium-containing amino carboxylate compounds and analogs for complexing metal ions, useful as ionic liquids, for extraction of metals from liquids, and their complexes as catalysts for air purification or organic reactions.” PCT Int. Appl. (2007), 62pp. CODEN: PIXXD2 WO 2007071028 A1 20070628 CAN 147:108436 AN 2007:702731. Sandrine Bouquillon, Thomas Courrant, Darrell Dean, Nicholas Gathergood, Saibh Morrissey , Bruce Pegot , Peter J. Scammells, and Robert D. Singer “Biodegradable Ionic Liquids: Selected Applications” Tetrahedron Submitted May, 2007. Miranda L. Cheney, Michael J. Zaworotko, and Robert D. Singer “Cocrystal Controlled Solid-State Synthesis – C3S3: A Green Chemistry Experiment for Undergraduate Organic Chemistry” J. Chem. Ed. Submitted May 22, 2007. Jitendra R. Harjani, Tomislav Frišcic , , Leonard R. MacGillivray and Robert D. Singer “Removal of Metal Ions from Aqueous Solutions Using a Chelating Ionic Liquid” Inorg. Chem. 2006 ; 45 (25); 10025-10027. Jitendra Harjani and Robert D. Singer “COMPOUNDS, Complexes AND uses thereof” PCT provisional patent application, 2006 PCT/CA2006/002060. Jitendra Harjani and Robert D. Singer “Task Specific Ionic Liquids Capable Containing an Ethylamine Diacetic Acid Moiety” US provisional application No. 60/752,880, filed on December 23, 2005 .

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