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研究领域

Synthesis of polynuclear homometallic 3d- and 4f-metal complexes Synthesis of polynuclear heterometallic 3d/3d′- and 3d/4f-metal complexes Multifunctional molecular magnetic materials High-spin molecules, single-molecule magnets and single-chain magnets Photoluminescent complexes Bioinorganic chemistry Medicinal inorganic chemisty

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P. S. Perlepe, L. Cunha-Silva, K. Gagnon,S. J. Teat,A. Escuer, Th. C. Stamatatos, “‘Ligands-with-Benefits’: Naphthalene-substituted Schiff bases fostering the formation of new NiII metal clusters with ferromagnetic and emissive properties, and undergoing exciting transformations”, accepted in Inorganic Chemistry. D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang, Th. C. Stamatatos, “Dodecanuclear 3d/4f-metal cluster compounds with a ‘Star of David’ topology and single-Molecule magnetism and magnetocaloric properties”, Chemical Communications, article in press. D. I. Alexandropoulos, E. E. Moushi, C. Papatriantafyllopoulou, C. M. Beavers, S. J. Teat, A. J. Tasiopoulos, G. Christou, Th. C. Stamatatos, “Cyanate groups in higher oxidation state metal cluster chemistry: Mixed-valence(II/III) Mn16 and Mn18 clusters”, Polyhedron, article in press. A. E. Thuijs, A. Marton, Th. C. Stamatatos, K. A. Abboud, G. Christou, “High nuclearity cerium-manganese clusters and their structural and magnetic properties: CeIV3MnIII7 and CeIV5MnIII11”, Polyhedron, 103, 288, 2016. E. C. Mazarakioti, L. Cunha-Silva,V. Bekiari, A. Escuer, Th. C. Stamatatos, “New structural topologies in 4­f-metal cluster chemistry from vertex-sharing butterfly units: {LnIII7} complexes exhibiting slow magnetization relaxation and ligand-centred emissions”, RSC Advances, 5, 92534, 2015, P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang, Th. C. Stamatatos, “‘All three-in-one’: ferromagnetism, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters”, Inorganic Chemistry Frontiers, 2, 945, 2015. D. Dermitzaki, C. P. Raptopoulou,V. Psycharis,A. Escuer, S. P. Perlepes, Th. C. Stamatatos, “Non-employed simple carboxylate ions in well-investigated areas of heterometallic carboxylate cluster chemistry: A new family of {CuII4LnIII8} complexes bearing tert-butylacetate bridging ligands”, Inorganic Chemistry, 54, 7555, 2015. P. Danelli, Z. G. Lada, C. P. Raptopoulou, V. Psycharis, Th. C. Stamatatos, S. P. Perlepes, “Doubly thiocyanato(S,N)-bridged dinuclear complexes of mercury(II) from the use of 2-pyridyl oximes as capping ligands”, Current Inorganic Chemistry, 5, 26, 2015. D. P. Giannopoulos, C. Wilson-Konderka, K. J. Gagnon,S. J. Teat, A. Escuer,C. Metallinos, Th. C. Stamatatos, “Synthesis and first use of pyridine-2,6-diylbis(pyrazine-2-ylmethanone) in metal cluster chemistry: A {MnIII3Na2} complex with an ideal trigonal bipyramidal geometry”, Dalton Transactions, 44, 4318, 2015. A. A. Alaimo,D. Takahashi, L. Cunha-Silva,G. Christou, Th. C. Stamatatos, “Emissive {MnIII4Ca} clusters with square pyramidal topologies: Synthetic, structural, and spectroscopic and physicochemical characterization”, Inorganic Chemistry, 54, 2137, 2015. M. Naimi, Th. Tsakiridis, Th. C. Stamatatos, D. I. Alexandropoulos, E. Tsiani, “Increased skeletal muscle glucose uptake by rosemary extract through AMPK activation”, Applied Physiology, Nutrition, and Metabolism, 40, 407, 2015. A. A. Athanasopoulou, M. Pilkington, C. P. Raptopoulou,A. Escuer, Th. C. Stamatatos, “Structural aesthetics in molecular nanoscience: A unique Ni26 cluster with a ‘rabbit-face’ topology and a discrete Ni18 ‘molecular chain’”, Chemical Communications, 50, 14942, 2014. B. Murphy, I. Snajdr, A. Machara, M. A. A. Endoma-Arias, Th. C. Stamatatos, D. P. Cox, T. Hudlicky, “Conversion of thebaine to oripavine and other useful intermediates for the semisynthesis of opiate-derived agents: Synthesis of hydromorphone”, Advanced Synthesis and Catalysis, 356, 2679, 2014. D. I. Alexandropoulos, L. Cunha-Silva, A. Escuer, Th. C. Stamatatos, “New classes of ferromagnetic materials with exclusively end-on azido bridges: From single-molecule magnets to 2D molecule-based magnets”, Chemistry - A European Journal, 20, 13860, 2014. P. S. Perlepe, A. A. Athanasopoulou, K. I. Alexopoulou, C. P. Raptopoulou,V. Psycharis,A. Escuer, S. P. Perlepes, Th. C. Stamatatos, “Structural and magnetic variations in tetranuclear NiII clusters: the effect of the reaction solvent and ligand substitution on the product identity”, Dalton Transactions, 43, 16605, 2014. D. Dermitzaki, C. P. Raptopoulou,V. Psycharis,A. Escuer, S. P. Perlepes, Th. C. Stamatatos, “Unexpected metal ion-assisted transformations leading to unexplored bridging ligands in NiII coordination chemistry: The case of PO3F2- group”, Dalton Transactions, 43, 14520, 2014. M. Charalambous, S. M. Zartilas, E. E. Moushi, C. Papatriantafyllopoulou, M. J. Manos, Th. C. Stamatatos, S. Mukherjee, V. Nastopoulos, G. Christou, A. J. Tasiopoulos, “Discrete and encapsulated molecular grids: Homometallic Mn15 and heterometallic Mn24Ni2 aggregates”, Chemical Communications, 50, 9090, 2014. R. Mirabdolbaghi, T. Dudding, Th. C. Stamatatos, “A class of phase-transfer catalyst with interionic strain: Insight into the bonding of disubstituted N- vs carbene-stabilized NI-centered cations”, Organic Letters, 16, 2790, 2014. E. C. Mazarakioti, K. M. Poole,L. Cunha-Silva,G. Christou, Th. C. Stamatatos, “A new family of Ln7 clusters with an ideal D3h metal-centered trigonal prismatic geometry, and SMM and photoluminescence behaviors”, Dalton Transactions, 43, 11456, 2014. D. I. Alexandropoulos, A. Fournet,L. Cunha-Silva, A. M. Mowson,V. Bekiari, G. Christou, Th. C. Stamatatos, “Fluorescent naphthalene diols as bridging ligands in LnIII cluster chemistry: Synthetic, structural, magnetic and photophysical characterization of LnIII8 ‘Christmas-stars’”, Inorganic Chemistry, 53, 5420, 2014. A. A. Athanasopoulou, C. P. Raptopoulou,A. Escuer, Th. C. Stamatatos, “Rare nuclearities in Ni(II) cluster chemistry: A Ni11 cage-like cluster from the initial use of N-salicylidene-2-amino-5-chlorobenzoic acid”, RSC Advances, 4, 12680, 2014. E. Gavey, Y. Beldjoudi, J. M. Rawson, Th. C. Stamatatos, M. Pilkington, “Slow relaxation in the first penta-aza Dy(III) macrocyclic complex”, Chemical Communications, 50, 3741, 2014. A. Escuer, J. Esteban, S. P. Perlepes, Th. C. Stamatatos, “The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry”, Coordination Chemistry Reviews, 275, 87, 2014. D. I. Alexandropoulos,L. Cunha-Silva,L. Pham, V. Bekiari, G. Christou, Th. C. Stamatatos, “Tetranuclear lanthanide(III) complexes with a zigzag topology from the use of pyridine-2,6-dimethanol: Synthetic, structural, spectroscopic, magnetic and photoluminescence studies”, Inorganic Chemistry, 53, 3220, 2014. D. P. Giannopoulos, A. Thuijs, W. Wernsdorfer, M. Pilkington, G. Christou, Th. C. Stamatatos, “Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets”, Chemical Communications, 50, 779, 2014.

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