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研究领域

Organic/Inorganic Synthesis, Molecular Magnetism, Organic Conductors, Spin-Crossover Compounds, Transition Metal Cyanide Chemistry, Coordination Chemistry, Structural Chemistry, Supramolecular Chemistry, Tetrathiafulvalenes.

近期论文

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Phosphorus(V)porphyrin-manganese(II)terpyridine conjugates: synthesis, spectroscopy and photooxidation studies on a SnO2 surface, P.K. Poddutoori, G.N. Lin, M. Pilkington, F.D'Souza and A. van der Est, Inorg. Chem., 2016, accepted for publication. Encapsulation of a [Dy(OH2)8]2+ cation: magneto-optical and theoretical studies of a caged, emissive SMM, M. Al. Hareri, E.L. Gavey, J. Regier, Z. Ras Ali, L.D. Carlos, R.A.S. Ferreira and M. Pilkington, Chem. Commun., 2016, 52, 11335. (Front Cover) Structural insights into the coordination chemistry and reactivity of a 3,3'-bis-imine-2,2'-bipyridine ligand, R. Gumbau-Brisa, J.J. Hayward, J.D. Wallis, J.M. Rawson and M. Pilkington, Cryst.Eng.Comm., 2016, 18, 1892. (Front Cover) Employing Schiff-base macrocycles to probe the effect of ligand field on the relaxation dynamics of a family of Dy(III) SMM, E.L. Gavey and M. Pilkington, Polyhedron, 2016, 108, 122. (Invited Paper) Structural, magnetic and DFT studies on a charge transfer salt of a TTF-pyridyl-(1,5-diisopropyl)verdazyl diradical, cation, S. Venneri, J. Wilson, J.M. Rawson and M. Pilkington, ChemPlusChem. 2015, DOI: 10.1002/cplu.201500309. (Invited Cover) Probing the structural changes accompanying a spin crossover transition in a chiral [Fe(II)(N3O2)(CN)2] macrocycle by X-ray crystallography. R. T. Acha and M. Pilkington, Cryst. Eng. Comm. 2015, 17, 8897. (Invited Paper) Placing a crown on DyIII - a dual property LnIII complex displaying optical properties and SMM behaviour, E. L. Gavey, M. Al Hareri, J. Regier, L. D. Carlos, R. A. S. Ferreira, F. S. Razavi, J. M. Rawson and M. Pilkington, J. Mat. Chem. C. 2015, 3, 7738. Methods and compounds for enhancing contrast in magnetic resonance imaging (MRI) E.L. Gavey and M. Pilkington, U.S. Provisional Patent Application No. 62/174,752 filed on June 12, 2015. Molecular construction and photoinduced electron transfer studies of axially arranged supramolecular tetrathiafulvalene-aluminum(III)porphyrin-fullerene triads. P.K. Poddutoori, G. N. Lim, A. S. D. Sandanayaka, P. A. Karr, O. Ito, F. D’Souza, M. Pilkington and A. van der Est, Nanoscale, 2015, 7, 12151. A family of unsymmetrical hydroxyl-substituted BEDT-TTF donors: syntheses, structures and preliminary thin film studies. Q. Wang, M. Zecchini, J. D. Wallis, Y. L. Wu, J.M. Rawson and M. Pilkington, RSC Advances, 2015, 5, 40205. Stereochemistry for engineering spin crossover: structures and magnetic properties of a homochiral vs racemic [Fe(N3O2)(CN)2] complex.Q. Wang, S. Venneri, N. Zarrabi, H. Wang, C. Desplanches, J.-F. Letard, T. Seda and M. Pilkington, Dalton Trans., 2015, 44, 6711. Coordination complexes of 15-membered pentadentate aza, oxoaza and thiaaza Schiff base macrocycles. “old ccmplexes offer new attractions”. E. L. Gavey and M. Pilkington, Coord. Chem. Rev., 2015, 296, 125. Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles, E.R. Clark, J.J. Hayward, B.J. Leontowicz, M. Pilkington, and J. M. Rawson, Dalton Trans. 2015, 44, 2071. 3,3′-Di(pyrazinamoyl)-2,2′-bipyridine: Rational ligand design for the self-assembly of a 1-D coordination polymer, N.J. Hurley, J.M. Rawson and M. Pilkington, Dalton Trans. 2015, 44, 1866. Probing the reactivity of a 2,2′-bipyridyl-3,3′-bis-imine ligand by X-ray crystallography J. Wang, J. J. Hayward, R. Gumbau-Brisa, J. D. Wallis, H. Stoeckli-Evans and M. Pilkington, CrystEngComm., 2015, 17, 1159. Structural Aesthetics in Molecular Nanoscience: A Uniqjue Ni26 Cluster with a “Rabbit-Face’ Topology and a Discrete Ni18 ‘Molecular Chain’, A. A. Athanasopoulu, M. Pilkington, C. P. Raptopoulu, A. Escuer and T. C. Stamatatos, Chem. Commun., 2014, 95, 14908. (Front Cover) A Structural Investigation of Novel Thiophene-Functionalized BEDT-TTF Donors for Applications as Organic Field-Effect Transistors,, Q. Wang, J. D. Wallis, Y. Wu and M. Pilkington, Cryst. Eng. Comm., 2014, 16, 7268. Exploring the Coordination Chemistry of 3,3’-Di(picolinamoyl)-2,2’-bipyridine: One Ligand Multiple Nuclearities, N.J. Hurley, J. J. Hayward, J. M. Rawson, M. Murrie, and M. Pilkington, Inorg. Chem, 2014, 53, 8610. Synthesis and Characterisation of First Row Transition Metal Complexes of Functionalized 1,2,4-Benzothiadiazines, E.R. Clark, M. U. Anwar, B.L. Leontowicz, Y. Beldjoudi, J, J. Hayward, W. K, Chan, E.L. Gavey, M. Pilkington, E. Zysman-Colman and J. M. Rawson, Dalton Trans., 2014, 43, 12996. Transformation of a Ditopic Schiff-Base Nickel(II) Nitrate Complex into an Unsymmetrical Schiff Base Derivative by Partial Hydrolytic Degradation: Structural and Theoretical Studies, Q. Wang , Y. Liu , W. Gaoa, Z. Xua, Y. Lia, W. Lia, and M. Pilkington, Transition Metal Chemistry, 2014, 39, 613. The First 1-D Cyanide-Bridged Complex Assembled from a Covalently Tethered [Co(N3O2)Cl(OH2)]22+ Macrocyclic Building Block, R. T. Acha, E. L. Gavey, J. Wang, J. M. Rawson and M. Pilkington, Polyhedron, 2014, 76, 122. An Unusual Single Crystal-to-Single Crystal [2+2] Photocyclization Reaction of a TTF-Aryl-Nitrile Derivative, J. J. Hayward, R. Gumbau-Brisa, C. Clarke, A. Alberola, J. M. Rawson and M. Pilkington, Cryst. Eng. Comm., 2014, 16, 7268. (Invited Paper) Slow Relaxation in the first Penta Aza Dy(III) Macrocyclic Complex, E.L. Gavey, Y. Beldjoudi, J.M. Rawson, T. Stamatatos and M. Pilkington, Chem. Commun., 2014, 50, 374. Supramolecular Chains of High Nuclearity {MnIII25} Barrel-like Single Molecule Magnets, D.P. Giannopolous, A. Thuijs, M. Pilkington, W. Wernsdorfer, G. Christou, T. C. Stamatatos, Chem. Commun., 2014, 50, 779. (Front Cover) Emissive Molecular Nanomagnets: Introducing Optical Properties in Triangular Oximato MnIII3 SMMs from the Deliberate Replacement of Simple Carboxylate Ligands with their Fluorescent Analogues, D. I. Alexandropoulos,A.M. Mowson,M. Pilkington,V. Bekiari,G. Christou and T. C. Stamatatos, Dalton Trans., 2014, 43. 1965. (Front Cover)

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